Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
Revision Date: 01/29/2007
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
SUSPEND庐 SC INSECTICIDE
Product Name
102000003167
MSDS Number
432-763
EPA Registration No.
Bayer Environmental Science
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day)
For Product Information call: 1-800-331-2867
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
Deltamethrin 52918-63-5 4.75
1,2-Propanediol 57-55-6 15.20
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Caution! Hazard to humans and domestic animals. Harmful if inhaled. Do not
Emergency Overview
breathe vapours or spray mist. Contact with product may result in transient
tingling and reddening of the skin. Remove and wash contaminated clothing
before re-use.
liquid suspension
Physical State
none
Odor
white
Appearance
Inhalation, Skin contact
Routes of Exposure
Immediate Effects
Contact with product may result in transient tingling and reddening of the skin.
Skin
Harmful if inhaled. Do not breathe vapours or spray mist.
Inhalation
Page 1 of 8 Bayer Environmental Science
A Business Group of Bayer
CropScience
Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
Extremely toxic to fish and aquatic invertebrates.
Potential Environmental
Effect
SECTION 4. FIRST AID MEASURES
When possible, have the product container or label with you when calling a
General
poison control center or doctor or going for treatment.
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Eye
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a physician or poison control center immediately.
Take off contaminated clothing and shoes immediately. Wash off immediately
Skin
with plenty of water for at least 15 minutes. Call a physician or poison control
center immediately.
Call a physician or poison control center immediately. Rinse out mouth and give
Ingestion
water in small sips to drink. DO NOT induce vomiting unless directed to do so by
a physician or poison control center. Never give anything by mouth to an
unconscious person. Do not leave victim unattended.
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration, preferably mouth-to-mouth if possible. Call a physician or
poison control center immediately.
Notes to Physician
There is no specific antidote. Appropriate supportive and symptomatic treatment
Treatment
as indicated by the patient's condition is recommended.
SECTION 5. FIRE FIGHTING MEASURES
not applicable
Flash point
Carbon dioxide (CO2), Dry chemical, Foam, Water
Suitable Extinguishing
Media
Fight fire from upwind position. Evacuate personnel to safe areas. Cool closed
Fire Fighting
containers/ tanks exposed to fire with water spray. Do not allow run-off from fire
Instructions
fighting to enter drains or water courses.
Firefighters should wear NIOSH approved self-contained breathing apparatus
and full protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
Keep unauthorized people away. Avoid contact with spilled product or
Personal Precautions
contaminated surfaces. In case of spill, leak or emergency, use a NIOSH
approved chemical cartridge-type respirator.
Dike area to prevent runoff. Collect and transfer the product into a properly
Methods for Cleaning Up
labelled and tightly closed container. Soak up with inert absorbent material (e.g.
sand, silica gel, acid binder, universal binder, sawdust). Decontaminate tools and
equipment following cleanup.
Isolate area. Contaminated soil may have to be removed and disposed.
Additional Advice
SECTION 7. HANDLING AND STORAGE
Avoid contact with skin, eyes and clothing. Handle and open container in a
Handling Procedures
manner as to prevent spillage. Smoking, eating and drinking should be
prohibited in the application area.
Store in original container. Do not contaminate water, food, or feed by storage or
Storing Procedures
disposal. Store in a cool, dry place and in such a manner as to prevent cross
contamination with other pesticides, fertilizers, food, and feed.
Handle in accordance with good industrial hygiene and safety practice.
Work/Hygienic
Recommendations for exposure control/personal protection are intended for the
Procedures
manufacture, formulation and packaging of the product.
Wash hands thoroughly with soap and water after handling and before eating,
drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.
Remove and wash contaminated clothing before re-use.
no data available
Min/Max Storage
Temperatures
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Train employees in safe use of the product. Eye wash facility and safety shower
General Protection
should be available. Follow all label instructions.
Maintain exposure levels below the exposure limit through the use of general
Engineering Controls
and local exhaust ventilation.
Chemical resistant goggles must be worn.
Eye/Face Protection
Chemical-resistant gloves made of waterproof material such as neoprene, butyl
Hand Protection
rubber, barrier laminate or nitrile rubber.
When respirators are required, select NIOSH approved equipment based on
Respiratory Protection
actual or potential airborne concentrations and in accordance with the
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
appropriate regulatory standards and/or industry recommendations.
Exposure Limits
Pyrogenic (fumed) 112945-52-5 Z3 TWA 20 millions of particles per
amorphous silica cubic foot of air
Z3 TWA 0.8 mg/m3
Remarks The value is calculated from
a specified equation using a
value of 100%. Values lower
than 100% will give higher
exposure limits. See
regulation for specific
equation.
1,2-Propanediol 57-55-6 WEEL TWA 10 mg/m3
Form of exposure Aerosol.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
white
Appearance
liquid suspension
Physical State
none
Odor
6.6 suspension in water
pH
<= 7.0 (100 %) at 20 掳C
1.05 at 20 掳C
Specific Gravity
approx. 1.053 g/cm鲁 at 20 掳C
Density
no data available
Boiling Point
no data available
Melting / Freezing Point
immiscible
Water solubility
no data available
Minimum Ignition Energy
165 mPa.s at 20 掳C
Viscosity
SECTION 10. STABILITY AND REACTIVITY
Stable under normal conditions.
Chemical Stability
Strong oxidizing agents
Incompatibility
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
strong reducing agents
Thermal decomposition can lead to release of:
Hazardous
Carbon monoxide
Decomposition Products
Carbon dioxide (CO2)
SECTION 11. TOXICOLOGICAL INFORMATION
Only acute toxicity studies have been conducted on this product as formulated. The non-acute information
pertaines to the active ingredient, deltamethrin technical.
male/female combined rat: LD50: > 15,000 mg/kg
Acute Oral Toxicity
male/female combined rabbit: LD50: > 10,000 mg/kg
Acute Dermal Toxicity
male/female combined rat: LC50: > 1.02 mg/l
Acute Inhalation Toxicity
Exposure time: 4 h
Determined in the form of a respirable aerosol.
(actual)
male/female combined rat: > 4.08 mg/l
Exposure time: 1 h
Determined in the form of a respirable aerosol.
Extrapolated from the 4 hr LC50.
(actual)
rabbit: No skin irritation.
Skin Irritation
rabbit: No eye irritation.
Eye Irritation
guinea pig: Non-sensitizing.
Sensitization
Deltamethrin caused neurobehavioral effects (e.g., tremors) in chronic toxicity
Chronic Toxicity
studies in rats and dogs.
Assessment Carcinogenicity
Deltamethrin was not carcinogenic in lifetime feeding studies in rats and mice.
ACGIH
None.
NTP
None.
IARC
Deltamethrin 52918-63-5 Overall evaluation: 3
OSHA
None.
REPRODUCTION: Deltamethrin was not a reproductive toxicant in multi-
Reproductive &
generation reproduction studies in rats.
Developmental Toxicity
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
DEVELOPMENTAL TOXICITY: Deltamethrin was not a primary developmental
toxicant in developmental toxicity studies in rats and rabbits. Developmental
effects (e.g., delayed ossifications) were observed in rabbits at the high-dose but
were considered secondary to maternal toxicity.
Deltamethrin caused neurobehavioral effects (e.g., tremors) without correlating
Neurotoxicity
neuropathological changes in acute and subchronic neurotoxicity screening
studies in rats.
Deltamethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo
Mutagenicity
tests.
SECTION 12. ECOLOGICAL INFORMATION
Oncorhynchus mykiss (rainbow trout)
Toxicity to Fish
LC50: 0.00026 mg/l
Exposure time: 96 h
Bluegill sunfish
LC50: 0.00017 mg/l
Exposure time: 96 h
Eastern Oyster
Acute Toxicity to Aquatic
LC50: 0.0082 mg/l
Invertebrates
Exposure time: 96 h
Mysidopsis bahia (mysid shrimp)
LC50: 0.000001 mg/l
Exposure time: 96 h
Bobwhite quail
Toxicity to other
LD50: > 2,250 mg/kg
organisms
Bobwhite quail
LC50: > 5,620 ppm
Mallard duck
LC50: 8,039 ppm
Half life: 55 - 65 h
Stability in water
pH: 9.0
Bluegill sunfish BCF: 189 - 3,930
Bioaccumulation
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
Do not discharge effluent containing this product into lakes, streams, ponds,
Environmental
estuaries, oceans or other water unless in accordance with the requirements of a
Precautions
National Pollutant Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. For guidance,
contact your State Water Board or Regional Office of the EPA. Retain and
dispose of contaminated wash water.
SECTION 13. DISPOSAL CONSIDERATIONS
Do not contaminate water, food, or feed by disposal. Dispose in accordance with
General Disposal
all local, state/provincial and federal regulations.
Guidance
Follow advice on product label and/or leaflet. If these wastes cannot be disposed
of by use according to label instructions, contact your State Pesticide or
Environmental Control Agency, or the Hazardous Waste representative at the
nearest EPA Regional Office for guidance.
Triple rinse containers. Puncture container to avoid re-use. Dispose of empty
Container Disposal
container in a sanitary landfill or by incineration, or, if allowed by State/Provincial
and local authorities, by burning. If burned, stay out of smoke.
SECTION 14. TRANSPORT INFORMATION
PROPER SHIPPING NAME: Not DOT regulated
NOTE: For transport purposes (49 CFR Part 173.132), the calculated 1-Hour LC50 (Rat) is: 4.08 mg/l.
SECTION 15. REGULATORY INFORMATION
432-763
EPA Registration No.
US Federal Regulations
TSCA list
1,2-Propanediol 57-55-6
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III - Section 302 - Notification and Information
None.
SARA Title III - Section 313 - Toxic Chemical Release Reporting
None.
US States Regulatory Reporting
CA Prop65
This product does not contain any substances known to the State of California to cause cancer.
This product does not contain any substances known to the State of California to cause reproductive
harm.
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Bayer Environmental Science
Material Safety Data Sheet MSDS Number: 102000003167
MSDS Version 2.2
SUSPEND庐 SC INSECTICIDE
US State Right-To-Know Ingredients
1,2-Propanediol 57-55-6 MN, RI
Canadian Regulations
Canadian Domestic Substance List
1,2-Propanediol 57-55-6
Environmental
CERCLA
None.
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
International Regulations
European Inventory of Existing Commercial Substances (EINECS)
Deltamethrin 52918-63-5
1,2-Propanediol 57-55-6
SECTION 16. OTHER INFORMATION
NFPA 704 (National Fire Protection Association):
Health - 1 Flammability - 0 Reactivity - 0 Others - none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
Reason to Revise: Updated for general editorial purposes.
Revision Date: 01/29/2007
This information is provided in good faith but without express or implied warranty. The customer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer.
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