Material Safety Data Sheet
EUCO # 452 EPOXY SYSTEM LV - 1 GAL UNIT
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
This is a kit that contains the following components:
EUCO 452/352 LV PART A
EUCO 452 LV/MV PART B
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Material Safety Data Sheet
EUCO 452/352 LV PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : EUCO 452/352 LV PART A
Product code : 002L 01
COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
White. Liquid. May cause slight irritation to the respiratory system. Leave area to breathe fresh air. Avoid
further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Slightly irritating.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause sensitization.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
May cause sensitization by contact. Prolonged or repeated exposure to epoxy resin can cause irritation to skin,
eyes, skin sensitization, temporary eye injury. Certain epoxy resins are reported to be mutagenic in some
laboratory tests. Fillers are encapsulated and not expected to be released from product under normal conditions
of use.
Target Organs: Skin, Eye, Ingestion
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Epichlorohydrin polymer 25068-38-6 > 60.0
Alkyl glycidyl ether 68609-96-1 7.0 - 13.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
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Material Safety Data Sheet
EUCO 452/352 LV PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash with water. If irritation, rash or other disorders develop, get medical attention
immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : > 200 掳 > 93 掳
F, C
Method : Setaflash Closed Cup
Lower explosion limit : 1.40 %(V) Solvent
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : This product is not expected to burn under normal conditions of use.
Hazardous combustion : Smoke, fumes.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : This product not expected to ignite under normal conditions of use.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Stop flow. Contain spill. Keep out of water courses. Absorb spill in sand, earth or other suitable material.
Transfer to appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Store in sealed containers in a dry, ventilated
warehouse location above freezing.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Not required under normal conditions of use.
Hand protection : Use suitable impervious rubber or vinyl gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.
Skin and body protection : Not required.
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Material Safety Data Sheet
EUCO 452/352 LV PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
Protective measures : Use professional judgment in the selection, care, and use.Other equipment
not normally required.
Engineering measures : General ventilation is sufficient.
Exposure Limits
No known components with exposure limits.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : White
Odor : Epoxy
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : > 500 掳 > 260 掳
F, C
Water solubility : Miscible
Specific Gravity : 1.16
% Volatile Weight : 0%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Acids and bases.Amines.Epoxy curing agents.
SECTION 11 - TOXICOLOGICAL INFORMATION
No Data Available
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Not regulated under RCRA. Dispose of in compliance with state and local regulations.
Do not incinerate.
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Material Safety Data Sheet
EUCO 452/352 LV PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : None present or none present in regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
0.0000 g/l
U.S. State Regulations:
Penn RTK Components : Epichlorohydrin polymer 25068-38-6
Alkyl glycidyl ether 68609-96-1
NJ RTK Components : Epichlorohydrin polymer 25068-38-6
Alkyl glycidyl ether 68609-96-1
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
None known.
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Material Safety Data Sheet
EUCO 452/352 LV PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 1 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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Material Safety Data Sheet
EUCO 452 LV/MV PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : EUCO 452 LV/MV PART B
Product code : 002L 01
COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585
Product use : Curative
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Liquid. Severely irritating to the respiratory tract. May cause chemical burns to the respiratory system.
May cause coughing and wheezing. May cause nausea, headaches, and dizziness. Move to fresh air. If
required, artificial respiration or administration of oxygen can be performed by trained personnel. Remove to
fresh air. Get immediate medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation Severely irritating to the respiratory tract. May cause chemical burns to the respiratory
:
system. May cause coughing and wheezing. May cause nausea, headaches, and
dizziness.
Eyes Vapors or liquid may cause tearing, blurred vision, severe irritation, and possible chemical
:
burns.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting. May cause chemical burns to
:
stomach, mouth, nose, and throat.
Skin May cause itching, reddening, inflammation. May cause severe burns, blistering and skin
:
damage. May cause sensitization resulting in irritation, itching and redness. May cause a
rash.
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
May cause sensitization by contact. Prolonged skin contact may cause irritation, burns or dermatitis. Repeated
overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless suitable
engineering controls and/or personal protective equipment are used. May aggravate persons sensitized to
amines Diethylenetriamine is a skin and eye irritant. Prolonged and repeated exposure can cause skin
sensitization, dermatitis, asthma. Fillers are encapsulated and not expected to be released from product under
normal conditions of use.
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Material Safety Data Sheet
EUCO 452 LV/MV PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Epoxy curing agent NJ TSRN# 51721300-5477P 40.0 - 70.0
Modified aliphatic amine NJ TSRN# 51721300-5810P 15.0 - 40.0
4-tert-Butylphenol 98-54-4 15.0 - 40.0
Bisphenol A 80-05-7 1.0 - 5.0
Tetraethylene pentamine 112-57-2 1.0 - 5.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Remove to fresh air. Get immediate medical
attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : > 200 掳 > 93 掳
F, C
Method : Setaflash Closed Cup
Lower explosion limit : 1.40 %(V) Solvent
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.Nitrogen
products oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
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Material Safety Data Sheet
EUCO 452 LV/MV PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear NIOSH/MSHA approved vapor respirator with appropriate cartridge
when the vapor concentration is expected to exceed exposure limits indicated
on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear chemical safety goggles and/or face shield to prevent eye contact. Do
not wear contact lenses. Do not touch eyes with contaminated body parts or
materials. Have eye washing facilities readily available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Inspect and replace equipment at regular intervals.Use professional judgment
in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
No known components with exposure limits.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : Gray
Odor : Amine
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
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Material Safety Data Sheet
EUCO 452 LV/MV PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : > 500 掳 > 260 掳
F, C
Water solubility : Negligible
Specific Gravity : 0.99
% Volatile Weight : 0%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.Epoxies.Isocyanates.Acids.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Bisphenol A, CAS-No.: 80-05-7
Acute oral toxicity (LD-50 oral) 3,300 mg/kg ( Rat )
Tetraethylene pentamine, CAS-No.: 112-57-2
Acute oral toxicity (LD-50 oral) 2,100 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 660 mg/kg ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Dispose of hazardous waste according to all local, state, federal and provincial
regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
CORROSIVE LIQUID, N.O.S. (Contains Diethylenetriamine), 8, UN1760, PG II
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
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Material Safety Data Sheet
EUCO 452 LV/MV PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
U.S. Federal Regulations:
SARA 313 Components : Bisphenol A 80-05-7
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Bisphenol A 80-05-7
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
0.0000 g/l
U.S. State Regulations:
MASS RTK Components : Bisphenol A 80-05-7
Tetraethylene pentamine 112-57-2
Penn RTK Components : Epoxy curing agent NJ TSRN# 51721300-5477P
Modified aliphatic amine NJ TSRN# 51721300-5810P
4-tert-Butylphenol 98-54-4
Bisphenol A 80-05-7
Tetraethylene pentamine 112-57-2
NJ RTK Components : Epoxy curing agent NJ TSRN# 51721300-5477P
Modified aliphatic amine NJ TSRN# 51721300-5810P
4-tert-Butylphenol 98-54-4
Bisphenol A 80-05-7
Tetraethylene pentamine 112-57-2
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
1333-86-4 Carbon Black
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
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Material Safety Data Sheet
EUCO 452 LV/MV PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 06/13/2005
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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