Material Safety Data Sheet
EUCO # 452-P EPOXY SYSTEM GEL -1 GL MTO
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
This is a kit that contains the following components:
EUCO 452 GEL P PART A
EUCO 452 GEL P PART B
1/14 002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : EUCO 452 GEL P PART A
Product code : 002P 01
COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Liquid solution. Vapor may irritate respiratory tract. May cause nausea, headaches, and dizziness.
Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation Vapor may irritate respiratory tract. May cause nausea, headaches, and dizziness.
:
Eyes Direct contact may cause mild irritation. May cause temporary injury.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient
evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the
TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis
may result from breathing free silica. Prolonged or repeated exposure to epoxy resin can cause irritation to skin,
eyes, skin sensitization, temporary eye injury. Certain epoxy resins are reported to be mutagenic in some
laboratory tests. Fillers are encapsulated and not expected to be released from product under normal conditions
of use.
Target Organs: Skin, Eye, Ingestion, Lung
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Epichlorohydrin polymer 25068-38-6 40.0 - 70.0
Clay 1332-58-7 15.0 - 40.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 10.0 - 30.0
Siloxanes and Silicones 67762-90-7 1.0 - 5.0
3/14 800000050111
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
Water 7732-18-5 1.0 - 5.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : > 200 掳 > 93 掳
F, C
Method : Setaflash Closed Cup
Lower explosion limit : 1.4 %(V) Solvent
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.
products
Protective equipment for : Water may be used to cool containers to minimize pressure build-
firefighters up.Use accepted fire fighting techniques. Wear full firefighting
protective clothing, including self-contained breathing apparatus
(SCBA).
Fire and explosion conditions : Closed container, may burst when exposed to extreme heat.Empty
containers may contain ignitable vapors.Vapor concentrations in
enclosed areas may ignite explosively.Vapors may travel to sources of
ignition and flashback.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Store under dry warehouse conditions away from heat and all ignition sources. Store in a cool, well ventilated
area. Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed
when not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use
4/14 800000050111
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
flame near container. Change soiled work clothes frequently. Clean hands thoroughly after handling.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Chemical splash goggles.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use general ventilation and/ or local exhaust to reduce the airborne
contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Clay 1332-58-7 ACGIH TWA: 2 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Crystalline Silica (Quartz)/ 14808-60-7 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
Silica Sand OSHA TWA: 0.1 mg/m3 Respirable.
OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid solution
Color : Gray
Odor : Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : > 500 掳 > 260 掳
F, C
5/14 800000050111
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
Water solubility : Negligible
Specific Gravity : 1.075
% Volatile Weight : 1%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Epoxy curing agents.Amines and oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
No Data Available
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Recycle or dispose of in compliance with local, provincial and federal regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : None present or none present in regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
OSHA Status: Considered : Irritant
6/14 800000050111
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
0 g/l
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Penn RTK Components : Epichlorohydrin polymer 25068-38-6
Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
NJ RTK Components : Epichlorohydrin polymer 25068-38-6
Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Siloxanes and Silicones 67762-90-7
Water 7732-18-5
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
7/14 800000050111
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART A
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
8/14 800000050111
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : EUCO 452 GEL P PART B
Product code : 002P 01
COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland, OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S. only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585
Product use : Curative
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Gray. Liquid solution. May cause slight irritation to the respiratory system. Leave area to breathe fresh air.
Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Vapors or liquid may cause tearing, blurred vision, severe irritation, and possible chemical
:
burns.
Ingestion May cause irritation to the mouth, throat and stomach. May cause chemical burns to
:
stomach, mouth, nose, and throat.
Skin May cause moderate irritation. May cause sensitization resulting in irritation, itching and
:
redness.
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Prolonged and repeated overexposure to amines may cause liver and kidney damage based on animal studies.
Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient
evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the
TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis
may result from breathing free silica. Diethylenetriamine is a skin and eye irritant. Prolonged and repeated
exposure can cause skin sensitization, dermatitis, asthma. Fillers are encapsulated and not expected to be
released from product under normal conditions of use.
Target Organs: Skin, Eye, Lung
SECTION 3 - PRODUCT COMPOSITION
9/14 800000050112
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
Chemical Name CAS-No. Weight %
Epoxy curing agent NJ TSRN# 51721300-5477P 40.0 - 70.0
Clay 1332-58-7 30.0 - 60.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 10.0 - 30.0
Siloxanes and Silicones 67762-90-7 3.0 - 7.0
Bisphenol A 80-05-7 1.0 - 5.0
Tetraethylene pentamine 112-57-2 1.0 - 5.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : > 200 掳 > 93 掳
F, C
Method : Setaflash Closed Cup
Lower explosion limit : 1.4 %(V) Solvent
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide, carbon dioxide, and nitrogen oxides.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Stop flow. Contain spill. Keep out of water courses. Absorb spill in sand, earth or other suitable material.
Transfer to appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
Store under normal warehouse conditions in sealed containers. Keep container closed when not in use. Vapor
may migrate to sources of ignition. Do not smoke, weld, generate sparks, or use flame near container. Change
10/14 800000050112
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
soiled work clothes frequently. Clean hands thoroughly after handling. Prevent inhalation of vapor, ingestion,
and contact with skin eyes and clothing. Keep container closed when not in use. Precautions also apply to
emptied containers. Handle in compliance with common hygienic practices. Clean hands thoroughly after
handling.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Use full engineering controls before relying on personal protective
equipment.Wear NIOSH/MSHA approved vapor respirator with appropriate
cartridge when the vapor concentration is expected to exceed exposure limits
indicated on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Protect hands with impervious gloves.
Eye protection : Wear chemical safety goggles and/or face shield to prevent eye contact. Do
not wear contact lenses. Do not touch eyes with contaminated body parts or
materials. Have eye washing facilities readily available.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Clay 1332-58-7 ACGIH TWA: 2 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Crystalline Silica (Quartz)/ 14808-60-7 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
Silica Sand OSHA TWA: 0.1 mg/m3 Respirable.
OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid solution
Color : Gray
Odor : Amine
pH : Not available.
Vapour pressure : Not available.
Vapor density : Not available.
Melting point/range : Not available.
11/14 800000050112
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
Freezing point : Not available.
Boiling point/range : > 500 掳 > 260 掳
F, C
Water solubility : Not available.
Specific Gravity : 1.075
% Volatile Weight : 1%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Acids.
Stability : Stable under normal conditions. Avoid welding arcs, flames or other high
temperature sources.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Bisphenol A, CAS-No.: 80-05-7
Acute oral toxicity (LD-50 oral) 3,300 mg/kg ( Rat )
Tetraethylene pentamine, CAS-No.: 112-57-2
Acute oral toxicity (LD-50 oral) 2,100 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 660 mg/kg ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
CORROSIVE LIQUID, N.O.S. (Contains Diethylenetriamine), 8, UN1760, PG II
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
12/14 800000050112
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Bisphenol A 80-05-7
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Bisphenol A 80-05-7
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
0 g/l
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Bisphenol A 80-05-7
Tetraethylene pentamine 112-57-2
Penn RTK Components : Epoxy curing agent NJ TSRN# 51721300-5477P
Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Siloxanes and Silicones 67762-90-7
Bisphenol A 80-05-7
Tetraethylene pentamine 112-57-2
NJ RTK Components : Epoxy curing agent NJ TSRN# 51721300-5477P
Clay 1332-58-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Siloxanes and Silicones 67762-90-7
Bisphenol A 80-05-7
Tetraethylene pentamine 112-57-2
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
1333-86-4 Carbon Black
13/14 800000050112
002P 01
Material Safety Data Sheet
EUCO 452 GEL P PART B
Version 1 Print Date 07/12/2007
REVISION DATE: 11/07/2005
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 3 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
14/14 800000050112
002P 01
|