Material Safety Data Sheet
MSDS ID NO.: 0148MAR019
Revision date: 07/25/2006
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon Road Oil Asphalt
Synonym: E-2 Road Oil; Road Oil E-2; E-3 Road Oil; Road Oil E-3; E-4 Road Oil; Road Oil E-4
Chemical Family: Asphalt
Formula: Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information: 419-421-3070
Emergency telephone number: 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Road Oil Asphalt is a petroleum asphalt mixed with varying proportions of No. 2 fuel oil, No. 6 fuel oil and/or Heavy
catalytic cracked distillate. Composition varies depending on source of final product. May contain minor amounts of
sulfur, nitrogen and oxygen containing compounds.
Product information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon Road Oil Asphalt Mixture 100
Component Information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
No. 6 Fuel Oil 68553-00-4 0-100
Asphalt 8052-42-4 0-100 =0.5 mg/m鲁 TWA
(inhalable fraction, as
benzene-soluble
aerosol)
Distillate, Catalytic Cracked Heavy 64741-61-3 0-48
No. 2 Fuel Oil 64741-44-2 0-24
Sulfur Compounds Mixture 0-3
Hydrogen Sulfide 7783-06-4 0-0.5 = 10 ppm TWA = 10 ppm TWA
= 15 ppm STEL = 14 mg/m鲁 TWA
= 15 ppm STEL
= 21 mg/m鲁 STEL
Naphthalene 91-20-3 0.01-0.12 Skin - potential = 10 ppm TWA
= 50 mg/m3 TWA
significant contribution
to overall exposure by = 15 ppm STEL
= 75 mg/m3 STEL
the cutaneous route
= 10 ppm TWA
= 15 ppm STEL
Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 1 of 11
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
ROAD OILS ARE DARK BROWN TO BLACK VISCOUS LIQUIDS. WHEN HEATED THIS MATERIAL MAY VENT
TOXIC LEVELS OF HYDROGEN SULFIDE (H2S) VAPORS THAT ACCUMULATE IN THE VAPOR SPACES OF
STORAGE AND TRANSPORT COMPARTMENTS. H2S VAPORS CAN CAUSE EYE, SKIN, AND RESPIRATORY
TRACT IRRITATION AND ASPHYXIATION. AVOID SKIN CONTACT. LONG TERM SKIN EXPOSURE TO
COMPONENTS OF THIS PRODUCT HAS CAUSED CANCER IN LABORATORY ANIMALS. THIS PRODUCT IS NOT A
COMBUSTIBLE LIQUID PER THE OSHA HAZARD COMMUNICATION STANDARD, BUT WILL IGNITE AND BURN AT
TEMPERATURES EXCEEDING THE FLASH POINT.
OSHA WARNING LABEL:
DANGER!
MAY VENT HARMFUL CONCENTRATIONS OF HYDROGEN SULFIDE (H2S) GAS WHICH CAN CAUSE
RESPIRATORY IRRITATION AND ASPHYXIATION.
LONG-TERM SKIN EXPOSURE TO COMPONENTS OF THIS PRODUCT HAS CAUSED CANCER IN LABORATORY
ANIMALS.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation: Vapors and fumes can cause respiratory and nasal irritation. Significant
concentrations of hydrogen sulfide gas can be present in the vapor space of storage
tanks and bulk transport compartments (See Sections 7, 8 & 11).
Ingestion: Product would be expected to have a low order of acute toxicity.
Skin contact: Prolonged and repeated liquid contact can cause dermatitis, folliculitis or oil acne.
Eye contact: Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon Road Oil Asphalt NE
Mixture
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is sufficient evidence for the carcinogenicity of extracts of steam-refined bitumens
(asphalts), air-refined bitumens and pooled mixtures of steam- and air-refined
bitumens in experimental animals. IARC has determined that there is inadequate
evidence that bitumens alone are carcinogenic to humans.
Component Information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Asphalt Supplement 7, 1987; A4 - Not Classifiable as a
8052-42-4 Monograph 35, 1985; Human Carcinogen (as
(extracts of steam and air benzene-soluble aerosol)
refined bitumens)
Distillate, Catalytic Cracked Heavy Monograph 45, 1989;
64741-61-3 (Listed under
``Occupational expsosures
in petroleum refining``)
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 2 of 11
Naphthalene Monograph 82, 2002 Reasonably Anticipated To A4 - Not Classifiable as a Present
91-20-3 Be A Carcinogen Human Carcinogen
Listed
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is inadequate evidence for the carcinogenicity of diesel fuel/fuel oil in humans. IARC
determined that there was limited evidence for the carcinogenicity of marine diesel
fuel in animals. Distillate (light) diesel fuels were not classifiable as to their
carcinogeniicty to humans (Group 3A)
The International Agency for Research on Cancer (IARC) has also determined that
there is sufficient evidence for the carcinogenicity in experimental animals of light
and heavy vacuum distillates, of light and heavy catalytically cracked distillates and
of cracked residues (catalytically cracked clarified oil) derived from the refining of
crude oil.
The International Agency for Research on Cancer (IARC) has determined that there
is sufficient evidence for the carcinogenicity of residual (heavy) fuel oil in animals.
The International Agency for Research on Cancer (IARC) and the Environmental
Protection Agency (EPA) have determined that naphthalene could be a possible
human carcinogen.
4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact: Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
Ingestion: Ingestion not likely. If large amounts are swallowed, immediately call a physician.
Eye contact: Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
Medical conditions aggravated Preexisting skin, eye and respiratory disorders may be aggravated by exposure to
by exposure: components of this product.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
Specific hazards: This product is not a combustible liquid per the OSHA
Hazard Communication Standard, but will ignite and burn at
temperatures exceeding the flash point.
Special protective equipment for firefighters: Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Keep run-off water out of sewers and
water sources.
Flash point: >200 F
Autoignition temperature: No data available.
Flammable limits in air - lower (%): 1.0
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 3 of 11
Flammable limits in air - upper (%): 6.0
NFPA rating: HMIS classification:
Health: 1 Health: 1
Flammability: 1 Flammability: 1
Reactivity: 1 Reactivity: 1
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Notify local health and pollution control agencies, if
appropriate. Contain liquid with sand or soil. Recover and return product to source.
7. HANDLING AND STORAGE
Handling:
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition.
Significant concentrations of hydrogen sulfide (H2S) gas can be generated and accumulate in storage tanks and bulk
transport compartments which may require additional precautions and procedures during loading/unloading. When
opening covers and outlet caps on storage tanks, use face shield and gloves to avoid possible injury from pressurized
product. Stay upwind and vent open hatches before unloading. Keep heating coils and flues in storage tanks, trucks and
kettles covered with product (8"). Do not overheat.
Avoid skin contact. Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap
and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures: Local or general exhaust required in an enclosed area or when there is inadequate
ventilation.
Respiratory protection: Not required under normal conditions and adequate ventilation. When H2S vapors
exceed permissible limits, i.e., in confined spaces or bulk transport
loading/unloading, a positive-pressure atmosphere supplying respirator is
recommended. Self-contained breathing apparatus should be used for fire fighting.
Skin and body protection: Impermeable gloves to prevent skin contact.
Eye protection: Goggles and faceshield when handling hot material.
Hygiene measures: Chemical resistant apron or other protective clothing may be needed to avoid skin
contact. Use mechanical ventilation equipment that is explosion-proof.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Black Viscous Liquid
Physical state (Solid/Liquid/Gas): Liquid
Substance type (Pure/Mixture): Mixture
Color: Black
Odor: Hydrocarbon
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 4 of 11
Molecular weight: Not determined.
pH: Neutral
Boiling point/range (5-95%): No data available.
Melting point/range: Not determined.
Decomposition temperature: Not applicable.
Specific gravity: Not determined
Density: 7.3-8.3 lbs/gal
Bulk density: No data available.
Vapor density: No data available.
Vapor pressure: 1 mm Hg @ 160 F
Evaporation rate: No data available.
Solubility: Negligible
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): No data available.
VOC content(%): No data available.
Viscosity: No data available.
10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.
Polymerization: Will not occur.
Hazardous decomposition products: Combustion produces toxic oxides of sulfur, carbon
monoxide, sulfur dioxide, hydrogen sulfide and
hydrocarbons.
Materials to avoid: Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid: Excessive heat, sources of igition and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name CAS Number Inhalation: Dermal: Oral:
Marathon Road Oil Asphalt Mixture No data available No data available No data available
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 5 of 11
Some epidemiologic studies conducted on workers exposed to asphalt fume have shown no increased incidence of
cancer while other studies have reported a slightly increased incidence of lung, other respiratory tract or gastrointestinal
cancers. In those studies in which elevated cancer incidences were reported, concurrent or previous exposure to coal-tar
products have been documented. therefore, it cannot be concluded that cancer incidence is related to exposure to
asphalt fume.
Although early studies have some technical shortcomings, long term inhalation exposures to asphalt aerosols or fumes
did not produce evidence of carcinogenicity even though chronic inflammatory changes similar to those produced by
nonspecific respiratory irritants were observed. Inhalation of 150 mg/m3 asphalt fume (particulate + vapor) 6 hours/day, 5
days/week for 13 weeks, did not produce toxicity except for reduced body weight and irritation in nasal passages in
exposed rats.
Laboratory animals administered subcutaneous or intramuscular injections of asphalt preparations or repeated skin
applications of hot (212 F) undiluted asphalt have occasionally produced a low incidence of skin tumors at the site of
application. These findings are of questionable validity since repeated tissue trauma (and/or burns) at the application site
can induce tumors. Solvent dilutions of different types of asphalts have been tested in chronic skin painting studies. Some
of the studies have reported a low incidence of skin tumors. The use of diluents may enhance bioavailability or metabolic
activation of chemicals in the mixture in a fashion not representative of occupational exposure. Skin painting studies in
mice have been conducted using condensates from fumes generated at temperatures >450 F diluted in solvent. Asphalt
fume condensate preparations have produced skin tumors. Experimental conditions (temperature and dose) were grossly
exaggerated over that likely to occur in humans.
Extracts of whole asphalts tested in a modified Ames assay gave negative or slightly positive findings (mutagenicity index
<1.5). Fume condensates derived from heating asphalts to high temperatures (>450 F) were moderately active (MI 4-9).
Fumes generated from coal tar pitch were >1000 times more active. Asphalt fume samples collected under actual field
conditions did not show any significant mutagenic activity.
Summary of health effect data on asphalt components:
This product can contain a toxicologically significant concentration of hydrogen sulfide (H2S). Hydrogen sulfide gas (H2S)
is toxic by inhalation. Prolonged breathing of 50-100 ppm H2S vapors can produce eye and respiratory tract irritation.
Higher concentrations (250-600 ppm) for 15-30 minutes can produce headache, dizziness, nervousness, nausea and
pulmonary edema or bronchial pneumonia. Concentrations of >1000 ppm will cause immediate unconsciousness and
death through respiratory paralysis. Rats and mice exposed to 80 ppm H2S, 6 hrs/day, 5 days/week for 10 weeks, did not
produce any toxicity except for irritation of nasal passages. H2S did not affect reproduction and development (birth
defects or neurotoxicity) in rats exposed to concentrations of 75-80 ppm or 150 ppm H2S, respectively. Over the years a
number of acute cases of H2S poisonings have been reported. Complete and rapid recovery is the general rule.
However, if the exposure was sufficiently intense and sustained causing cerebral hypoxia (lack of oxygen to the brain),
neurologic effects such as amnesia, intention tremors or brain damage are possible.
This product may contain No. 2 fuel oil at a level of >1.0%. Lifetime skin painting studies in animals with similar middle
distillate fuel oils and gas oils have produced tumors following prolonged and repeated skin contact. Some middle
distillates and/or light gas oils, when tested at nonirritating dose levels, did not show any significant carcinogenic activity
indicating that this tumorigenic response may be related to chronic irritation and not to dose.
Lifetime skin painting studies in animals with products similar to Heavy catalytic cracked distillate, No. 6 fuel oil and/or its
components have produced tumors in animals following prolonged and repeated skin contact. Repeated dermal
application has produced severe irritation and systemic toxicity in subacute toxicity studies. The product contains Heavy
catalytic cracked distillate or No. 6 fuel oil at a level of >1.0% Repeated dermal application has produced severe irritation
and systemic toxicity in subacute toxicity studies. Some components of this product, i.e., paraffins and olefins, have been
shown to produce a species specific sex hormonal dependent kidney lesion in male rats from repeated oral or inhalation
exposure. Subsequent research has shown that the kidney damage develops via the formation of alpha-2u-globulin, a
mechanism unique to the male rat. Humans do not form alpha-2u-globulin, therefore, the kidney effects resulting from
this mechanism are not relevant in humans. Some components were found to be positive in a few mutagenicity tests
while negative in the majority of others. The exact relationship between these results and human health is not known.
This product may contain >0.1% naphthalene. Exposure to naphthalene at 30 ppm for two years caused lung tumors in
female mice. Male mice with the same exposure did not develop tumors. Exposure to 10-60 ppm naphthalene for 2 years
caused tumors in the tissue lining of the nose and respiratory tract in male and female rats. Oral administration of 133-
267 mg/kg/day of naphthalene in mice for up to 90 days did not produce mortality, systemic toxicity, adversely affect
organ or body weight or produce changes in blood. Repeated oral administration of naphthalene produced an anemia in
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 6 of 11
dogs. Repeated intraperitoneal doses of naphthalene produced lung damage in mice. Repeated high doses of
naphthalene has caused the formation of cataracts and retinotoxicity in the eyes of rats and rabbits due to accumulation
of 1,2-naphthoquinone, a toxic metabolite. Effects in human eyes is uncertain and not well documented. Pregnant rats
administered intraperitoneal doses of naphthalene during gestation gave birth to offspring that had delayed heart and
bone development. Pregnant mice given near lethal doses of naphthalene showed no significant maternal toxicity and a
reduction in the number of pups per litter, but no gross abnormalities in offspring. Suppressed spermatogenesis and
progeny development have been reported in mice, rats and guinea pigs after exposure to high concentrations of
naphthalene in their drinking water. Certain groups or individuals, i.e., infants, Semites, Arabs, Asians and Blacks, with a
certain blood enzyme deficiency (glucose-6-phosphate dehydrogenase) are particularly susceptible to hemolytic agents
and can rapidly develop hemolytic anemia and systemic poisoning from ingestion or inhalation of naphthalene.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects: This product does not concentrate or accumulate in the food chain. This product is
not expected to cause any acute or chronic toxicity to aquatic organisms due to its
extremely low water solubility.
13. DISPOSAL CONSIDERATIONS
Cleanup Considerations: This product as produced is not specifically listed as an EPA
RCRA hazardous waste according to federal regulations (40
CFR 261). This material could become a hazardous waste if
mixed or contaminated with a hazardous waste or other
substance(s). It is the responsibility of the user to
determine if disposal material is hazardous according to
federal, state and local regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information: This material when transported via US commerce would be regulated by DOT
Regulations.
Comments: (Hot Petroleum Asphalt) This material must not be transported when
heated at or above its flash point.
Proper shipping name: Elevated Temperature Liquid, N.O.S.
UN/Identification No: UN 3257
Hazard Class: 9
Packing group: III
DOT reportable quantity (lbs): Not applicable.
TDG (Canada):
Proper shipping name: Elevated Temperature Liquid, N.O.S.
UN/Identification No: UN 3257
Hazard Class: 9
Packing group: III
Regulated substances: Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 7 of 11
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
No. 6 Fuel Oil NA
Asphalt NA
Distillate, Catalytic Cracked Heavy NA
No. 2 Fuel Oil NA
Sulfur Compounds NA
Hydrogen Sulfide hydrogen sulfide
Naphthalene NA
SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
No. 6 Fuel Oil NA
Asphalt NA
Distillate, Catalytic Cracked Heavy NA
No. 2 Fuel Oil NA
Sulfur Compounds NA
Hydrogen Sulfide = 100 lb final RQ
= 45.4 kg final RQ
Naphthalene = 0.454 kg final RQ
= 1 lb final RQ
= 100 lb final RQ
= 45.4 kg final RQ
SARA Section 311/312: The following EPA hazard categories apply to this product:
Acute Health Hazard
Chronic Health Hazard
SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
No. 6 Fuel Oil None
Asphalt None
Distillate, Catalytic Cracked Heavy None
No. 2 Fuel Oil None
Sulfur Compounds None
Hydrogen Sulfide None
Naphthalene = 0.1 % de minimis concentration
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
No. 6 Fuel Oil
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 8 of 11
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Asphalt
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 0170
Pennsylvania Right-To-Know: [present]
Massachusetts Right-To Know: Present
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Toxic, Flammable
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Distillate, Catalytic Cracked Heavy
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
No. 2 Fuel Oil
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 9 of 11
New Jersey Right-To-Know: sn 2452
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Sulfur Compounds
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Hydrogen Sulfide
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 1017
Pennsylvania Right-To-Know: environmental hazard
Massachusetts Right-To Know: Extraordinarily hazardous
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Toxic, Flammable
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous extraordinarily hazardous
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: flammable - fourth degree
New Jersey - Environmental Hazardous SN 1017
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - = 100 lbs Air RQ
List of Hazardous Substances: = 100 lbs Land/Water RQ
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 10 of 11
Naphthalene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure:
Hydrogen Sulfide A; B1; D1A; D2B 1% (English Item 851, French Item 1550)
Naphthalene B4, D2A 1%
16. OTHER INFORMATION
Additional Information: No data available.
Prepared by: Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0148MAR019 Product name: Marathon Road Oil Asphalt Page 11 of 11
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