Material Safety Data Sheet
MSDS ID NO.: 0223MAR019
Revision date: 09/12/2005
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon 100 HF Solvent Neutral Oil
Synonyms: Neutral Oil 100; SNO 100; Solvent Neutral Oil 100; 100 Solvent Neutral Oil
Chemical Family: Solvent Neutral Oil
Formula: Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information: 419-421-3070
Emergency telephone number: 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Solvent Neutral Oil is a complex mixture of hydrocarbons obtained by removal of normal paraffins from a petroleum
fraction by solvent crystallization. It consists predominantly of hydrocarbons having carbon numbers predominantly in the
range of C20-C50.
Product information
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon 100 HF Solvent Neutral Oil 64742-65-0 100
Component Information
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Petroleum Distillates, Solvent 64742-65-0 100 Mineral Oil Mist
Dewaxed Heavy Paraffinic (MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
SOLVENT NEUTRAL OIL IS A NON-VOLATILE AND NON-COMBUSTIBLE AMBER LIQUID PER THE OSHA HAZARD
COMMUNICATION STANDARD, BUT WILL IGNITE AND BURN AT TEMPERATURES EXCEEDING THE FLASH
POINT.
OSHA WARNING LABEL:
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THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE ANY HAZARD WARNING LABEL UNDER
THE OSHA HAZARD COMMUNICATION STANDARD.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Principle routes of exposure: Skin
Inhalation: Exposure to vapors or mists of this product may cause pulmonary irritation, dizziness
and nausea. Prolonged overexposure to vapors or mists may produce chemical
pneumonitis.
Ingestion: Product would be expected to have a low order of acute toxicity.
Skin contact: Prolonged or repeated liquid contact can cause dermatitis, folliculitis or oil acne.
Eye contact: Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon 100 HF Solvent Neutral Oil NE
64742-65-0
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is no evidence that severely solvent-refined oils are carcinogenic to experimental
animals.
Component Information
4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact: Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
If product is accidentally injected into or under the skin, regardless of wound size or
initial absence of symptoms, the individual should be evaluated immediately by a
physician as a surgical emergency.
Ingestion: Not expected to be acutely toxic. If large amounts are swallowed, immediately call a
physician.
Eye contact: Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
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Notes to physician: High velocity injection under the skin may result in serious injury. If left untreated the
affected area is subject to infection, disfigurement, lack of blood circulation and may
require amputation. When dispensed by high pressure equipment this material can
easily penetrate the skin and leave a bloodless puncture wound. Material injected
into a finger can be deposited into the palm of the hand. Within 24-48 hours the
patient may experience swelling, discoloration, and throbbing pain in the affected
area. Immediate treatment by a surgical specialist is recommended.
Medical conditions aggravated by No data available.
exposure:
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
Specific hazards: This product is not a combustible liquid per the OSHA
Hazard Communication Standard, but will ignite and burn at
temperatures exceeding the flash point.
Special protective equipment for firefighters: Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Use water spray to cool exposed surfaces
from as far a distance as possible. Keep run-off water out of
sewers and water sources.
Flash point: >380 F
Autoignition temperature: No data available.
Flammable limits in air - lower (%): No data available.
Flammable limits in air - upper (%): No data available.
NFPA rating: HMIS classification:
Health: 1 Health: 1
Flammability: 1 Flammability: 1
Reactivity: 1 Reactivity: 1
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Eliminate all ignition sources. Advise authorities and National Response Center (800-
424-8802) if substance has entered a watercourse or sewer. Notify local health and
pollution control agencies, if appropriate. Contain liquid with sand or soil. Recover
and return product to source. Use suitable absorbent materials such as vermiculite,
sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
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Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Do not cut, drill, grind or weld on
empty containers since they may contain explosive residues.
Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures: Local or general exhaust required when using at elevated temperatures that
generate vapors or mists.
Respiratory protection: Not required under normal conditions and adequate ventilation. Approved organic
vapor chemical cartridge or supplied air respirators should be worn when significant
vapors are generated. Observe respirator protection factor criteria cited in ANSI
Z88.2. Self-contained breathing apparatus should be used for fire fighting.
Skin and body protection: Use chemical resistant gloves such as neoprene, nitrile, or PVA to prevent prolonged
or repeated skin contact.
Eye protection: No special eye protection is normally required.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Amber Liquid
Physical state (Solid/Liquid/Gas): Liquid
Substance type (Pure/Mixture): Mixture
Color: Amber
Odor: Slight Hydrocarbon
Molecular weight: C.A. 390
pH: Neutral
Boiling point/range (5-95%): >425 F
Melting point/range: 0 F pour point, ASTM D97
Decomposition temperature: Not applicable.
Specific gravity: 0.85-0.87
Density: 7.1-7.3 lbs/gal @ 60 F
Bulk density: No data available.
Vapor density: >1
Vapor pressure: <1 mm Hg @ 100 F
Evaporation rate: Negligible
Solubility: Not determined
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): >4
VOC content(%): 0
Viscosity: 100-115 SUS @ 100 F
10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.
Polymerization: Will not occur.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, aldehydes and
hydrocarbons.
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Materials to avoid: Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid: Heat and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information
Name CAS Number Inhalation: Dermal: Oral:
Marathon 100 HF Solvent Neutral Oil 64742-65-0 >2-4 mg/l [Rat] >2 ml/kg [Rabbit] >5 gm/kg [Rat]
Chronic skin painting studies with severely solvent refined neutral oils did not produce evidence of skin cancer in mice.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects: Water accomated fractions (WAF) of highly refined base oils did not produce acute
toxicity in fish (100-1000 mg/l), fresh water algae (500 mg/l) or daphnia (10,000 mg/l)
in 48-96 hour LC50 studies.
13. DISPOSAL CONSIDERATIONS
Cleanup Considerations: This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information: This material when transported via US commerce is NOT REGULATED by DOT
regulations.
DOT reportable quantity (lbs): Not applicable.
TDG (Canada):
Regulated substances: Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined not to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
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SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Petroleum Distillates, Solvent NA
Dewaxed Heavy Paraffinic
SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Petroleum Distillates, Solvent NA
Dewaxed Heavy Paraffinic
SARA Section 311/312: The following EPA hazard categories apply to this product:
None
SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
Petroleum Distillates, Solvent None
Dewaxed Heavy Paraffinic
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Petroleum Distillates, Solvent Dewaxed Heavy Paraffinic
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or the Non Domestic Substance List (NDSL).
16. OTHER INFORMATION
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Additional Information: No data available.
Prepared by: Craig M. Parker Manager, Toxicology And Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
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