Material Safety Data Sheet
MSDS ID NO.: 0260MAR019
Revision date: 09/12/2005
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon Synfuel Binder - Oil Emulsion
Synonyms: Oil Emulsion Synfuel Binder; SB-CS; SB-RS; SB-6; Synfuel Binder Oil Emulsion
Chemical Family: Petroleum Hydrocarbon
Formula: Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information: 419-421-3070
Emergency telephone number: 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Synfuel Binder - Oil Emulsion is a complex mixture of residual fuel oil and/or catalytic cracked slurry oil and anionic
emulsifiers. Emulsion quality varies depending on source of No. 6 oil and/or slurry oil and source of water.
Product information
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon Synfuel Binder - Oil Mixture 100
Emulsion
Component Information
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Residuum, Vacuum 64741-56-6 0-40
Anionic Emulsifier Mixture 0.1-4
No. 6 Fuel Oil 68553-00-4 0-100
Middle Distillate Fuel 64741-44-2 10-30
Catalytic Cracked Clarified Oil 64741-62-4 0-100
Water 7732-18-5 5-60
Sulfur Compounds Mixture 1-3
Hydrogen Sulfide 7783-06-4 0-0.01 = 10 ppm TWA = 10 ppm TWA
= 15 ppm STEL = 14 mg/m鲁 TWA
= 15 ppm STEL
= 21 mg/m鲁 STEL
Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
3. HAZARDS IDENTIFICATION
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 1 of 11
Emulsion
EMERGENCY OVERVIEW
THIS PRODUCT IS A BROWN TO BLACK VISCOUS COLORED LIQUID. THIS PRODUCT IS NOT A COMBUSTIBLE
LIQUID PER THE OSHA HAZARD COMMUNICATION STANDARD, BUT WILL IGNITE AND BURN AT
TEMPERATURES EXCEEDING THE FLASH POINT. PRODUCT MAY CAUSE THERMAL BURNS FROM ELEVATED
HANDLING AND STORAGE TEMPERATURES. LONG-TERM SKIN EXPOSURE TO COMPONENTS OF THIS
PRODUCT HAS CAUSED CANCER IN LABORATORY ANIMALS AND HUMANS. REPEATED SKIN CONTACT TO
SOME COMPONENTS OF THIS PRODUCT HAVE PRODUCED SYSTEMIC TOXICITY (INCLUDING LIVER DAMAGE)
IN LABORATORY ANIMALS. WHEN HEATED THIS MATERIAL MAY VENT TOXIC LEVELS OF HYDROGEN SULFIDE
(H2S) VAPORS THAT ACCUMULATE IN THE VAPOR SPACES OF STORAGE AND TRANSPORT COMPARTMENTS.
H2S VAPORS CAN CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION AND ASPHYXIATION.
OSHA WARNING LABEL:
DANGER!
CONTACT WITH HEATED MATERIAL MAY CAUSE SEVERE BURNS.
LONG-TERM SKIN EXPOSURE TO COMPONENTS OF THIS PRODUCT HAS CAUSED SKIN CANCER IN
LABORATORY ANIMALS AND HUMANS.
REPEATED SKIN CONTACT TO SOME COMPONENTS IN THIS PRODUCT HAS PRODUCED SYSTEMIC TOXICITY
(INCLUDING LIVER DAMAGE) IN LABORATORY ANIMALS.
MAY VENT HARMFUL CONCENTRATIONS OF HYDROGEN SULFIDE (H2S) GAS WHICH CAN CAUSE
RESPIRATORY IRRITATION AND ASPHYXIATION.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation: Exposure to vapor or mist may cause pulmonary irritation, dizziness, nausea and
loss of consciousness. Significant concentrations of hydrogen sulfide gas can be
present in the vapor space of storage tanks and bulk transport compartments (See
Sections 7, 8 & 11).
Ingestion: Product would be expected to have a low order of acute toxicity. Significant ingestion
of some components of this product may cause liver damage.
Skin contact: Direct skin contact can cause chemical as well as thermal burns. Prolonged and
repeated liquid contact can cause defatting and drying of the skin and can lead to
irritation and/or dermatitis. Components of this product may cause skin sensitization.
Components of this product can cause liver damage if absorbed through the skin.
Eye contact: Hot product causes severe burns. Liquid or vapor contact may result in slight eye
irritation.
Carcinogenic Evaluation:
Product information
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon Synfuel Binder - Oil NE
Emulsion
Mixture
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 2 of 11
Emulsion
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is inadequate evidence for the carcinogenicity of diesel fuel/fuel oil in humans. IARC
determined that there was limited evidence for the carcinogenicity of marine diesel
fuel in animals. Distillate (light) diesel fuels were not classifiable as to their
carcinogenicity to humans (Group 3A).
The International Agency for Research on Cancer (IARC) has determined that there
is sufficient evidence for the carcinogenicity of residual (heavy) fuel oil in animals.
The International Agency for Research on Cancer (IARC) has determined there is
sufficient evidence for the carcinogenicity of catalytically cracked clarified oils
(carbonblack feedstock) in experimental animals.
Component Information
Notes: The International Agency for Research on Cancer (IARC) and the National
Toxicology Program (NTP) have concluded that certain polycyclic aromatic
hydrocarbons, i.e. (benzo(a)pyrene, benz(a)anthracene, benzo(a)phenanthrene,
indeno(1,2,3-cd)pyrene, benzo(j)fluoranthene, benzo(j,k,fluorine,
benzo(g,h,i)perylene, and 5-methylchrysene are probably carcinogenic to humans
(Group 2A and B).
4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician.
Skin contact: Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
Ingestion: Ingestion not likely. If swallowed, do not induce vomiting and do not give liquids.
Immediately call a physician.
Eye contact: Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
Medical conditions aggravated by Preexisting skin conditions, respiratory disorders, and impaired liver function may be
exposure: aggravated by exposure to components of this product.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
Specific hazards: This product is not a combustible liquid per the OSHA
Hazard Communication Standard, but will ignite and burn at
temperatures exceeding the flash point. For additional fire
related information, see NFPA 30 or the North American
Emergency Response Guide 128.
Special protective equipment for firefighters: Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Use water spray to cool exposed surfaces
from as far a distance as possible. Keep run-off water out of
sewers and water sources.
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 3 of 11
Emulsion
Flash point: >200 F
Autoignition temperature: No data available.
Flammable limits in air - lower (%): No data available.
Flammable limits in air - upper (%): No data available.
NFPA rating: HMIS classification:
Health: 2 Health: 2
Flammability: 1 Flammability: 1
Reactivity: 1 Reactivity: 1
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Notify local health and pollution control agencies, if
appropriate. Contain liquid with sand or soil. Recover and return product to source.
7. HANDLING AND STORAGE
Handling:
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Do not cut, drill, grind or weld on
empty containers since they may contain explosive residues. This product may flash if product temperature is >140 F.
Do not mix with cationic emulsions.
Harmful concentrations of hydrogen sulfide (H2S) gas can accumulate in excavations and low-lying areas as well as the
vapor space of storage and bulk transport compartments. Stay upwind and vent open hatches before unloading.
Avoid skin contact. Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap
and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures: Local or general exhaust required in an enclosed area or when there is inadequate
ventilation.
Respiratory protection: Not required under normal conditions and adequate ventilation. Use atmosphere
supplying respirators in the event of oxygen deficiency, when material produces
vapors that exceed permissible limits or when excessive vapors are generated. Self-
contained breathing apparatus should be used for fire fighting.
Skin and body protection: Impermeable gloves (e.g., nitrile, viton, tyvek/saranex 23) to prevent skin contact.
Eye protection: Goggles and faceshield when handling hot material.
Hygiene measures: Use mechanical ventilation equipment that is explosion-proof. Chemical resistant
apron or other protective clothing may be needed to avoid skin contact. Long sleeves
and pants as necessary to prevent skin contact.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Black Viscous Liquid
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 4 of 11
Emulsion
Physical state (Solid/Liquid/Gas): Liquid
Substance type (Pure/Mixture): Pure
Color: Black
Odor: Hydrocarbon
Molecular weight: Not determined.
pH: Neutral
Boiling point/range (5-95%): No data available.
Melting point/range: Not determined.
Decomposition temperature: Not applicable.
Specific gravity: Not determined
Density: No data available.
Bulk density: No data available.
Vapor density: No data available.
Vapor pressure: Not determined.
Evaporation rate: No data available.
Solubility: Not determined
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): No data available.
VOC content(%): No data available.
Viscosity: No data available.
10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.
Polymerization: Will not occur.
Hazardous decomposition products: Combustion produces carbon monoxide, aldehydes,
aromatic and other hydrocarbons.
Materials to avoid: Strong oxidizing agents such as chlorates, nitrates,
peroxides, cationic emulsions.
Conditions to avoid: Sources of heat or ignition. Do not mix with cationic
emulsions.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information
Name CAS Number Inhalation: Dermal: Oral:
Marathon Synfuel Binder - Oil Mixture No data available No data available No data available
Emulsion
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 5 of 11
Emulsion
Summary of health effect data on synfuel components:
This product contains diesel fuel (middle distillate) at a level of >1.0% Lifetime skin painting studies in animals with
similar distillate fuels have produced weak to moderate carcinogenic activity following prolonged and repeated exposure.
Similar middle distillates, when tested at nonirritating dose levels, did not show any significant carcinogenic activity
indicating that this tumorigenic response is likely related to chronic irritation and not to dose. Repeated dermal application
has produced severe irritation and systemic toxicity in subacute toxicity studies. Some components of this product, have
been shown to produce a species specific, sex hormonal dependent kidney lesion in male rats from repeated oral or
inhalation exposure. Subsequent research has shown that the kidney damage develops via the formation of a alpha-2碌-
globulin, a mechanism unique to the male rat. Humans do not form alpha-2碌-globulin, therefore, the kidney effects
resulting from this mechanism are not relevant in humans.
This product may contain No. 6 fuel oil at a level of >1.0%. Lifetime skin painting studies in animals with products similar
to Heavy catalytic cracked distillate, No. 6 fuel oil and/or its components have produced tumors in animals following
prolonged and repeated skin contact. Repeated dermal application has produced severe irritation and systemic toxicity in
subacute toxicity studies. Some components of this product were found to be positive in some mutagenicity tests while
negative in others. The exact relationship between these results and human health is not known.
Catalytic cracked clarified oil (CCCO) may be present in concentrations up to 100% in this product. Lifetime skin painting
studies in animals with CCCO have produced tumors in animals following prolonged and repeated skin contact.
Repeated dermal application of CCCO (30 mg/kg/day for 13 weeks) in rats resulted in anemia, liver degeneration and
injury to bone marrow and lymphoid tissues. 100% mortality was observed at 2,000 mg/kg/day within three weeks.
Repeated dermal application (30 mg/kg/day) of CCCO to pregnant rats during gestation produced maternal and fetal
toxicity, some deaths and systemic toxicity (liver, thymus and blood). The number of viable offspring decreased at doses
of 30 mg/kg/day and above. Many of the developmental effects (anomalies, resorptions and growth inhibition) were
observed at doses which produced maternal toxicity. In a separate developmental study CCCO produced decreases in
body weights and food consumption at doses from 10-250 mg/kg/day. Although fertility and reproductive function were
not affected, the no observable adverse effect level for CCCO administered dermally was 1 mg/kg/day.
Hydrogen sulfide gas (H2S) is toxic by inhalation. Prolonged breathing of 50-100 ppm H2S vapors can produce eye and
respiratory tract irritation. Higher concentrations (250-600 ppm) for 15-30 minutes can produce headache, dizziness,
nervousness, nausea and pulmonary edema or bronchial pneumonia. Concentrations of >1000 ppm will cause immediate
unconsciousness and death through respiratory paralysis. Rats and mice exposed to 80 ppm H2S, 6 hrs/day, 5
days/week for 10 weeks, did not produce any toxicity except for irritation of nasal passages. H2S did not affect
reproduction and development (birth defects or neurotoxicity) in rats exposed to concentrations of 75-80 ppm or 150 ppm
H2S, respectively. Over the years a number of acute cases of H2S poisonings have been reported. Complete and rapid
recovery is the general rule. However, if the exposure was sufficiently intense and sustained causing cerebral hypoxia
(lack of oxygen to the brain), neurologic effects such as amnesia, intention tremors or brain damage are possible.
This product contains polynuclear aromatic hydrocarbons (PAC) at a level of >0.1%. Some PACs that have been
identified in this product such as benzo(a)pyrene, benz(a)anthracene and indeno(1,2,3-cd)pyrene have been shown to be
carcinogenic in experimental animals. An increased risk of cancer has been observed in workers employed in the
aluminum production, coal gasification, coal-tar pitch, coke production and iron and steel industries that had been
occupationally exposed to polynuclear aromatic hydrocarbons. Since these kinds of PACs have been measured at high
levels in air samples taken in these industries, The International Agency for Research on Cancer (IARC) has concluded
that these PACs are probably carcinogenic to humans.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects: Product can be toxic to fish and aquatic life. The 24 hour TLM of the water soluble
fraction of bunker C fuel oil is 3-6 ppm in marine and estuarine crustaceans and fish.
13. DISPOSAL CONSIDERATIONS
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 6 of 11
Emulsion
Cleanup Considerations: This product as produced is not specifically listed as an EPA
RCRA hazardous waste according to federal regulations (40
CFR 261). However, when discarded or disposed of, it may
meet the criteria of an "characteristic" hazardous waste. This
material could become a hazardous waste if mixed or
contaminated with a hazardous waste or other substance(s).
It is the responsibility of the user to determine if disposal
material is hazardous according to federal, state and local
regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information: This material when transported via US commerce is NOT REGULATED by DOT
regulations.
DOT reportable quantity (lbs): Not applicable.
TDG (Canada):
Regulated substances: Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Residuum, Vacuum NA
Anionic Emulsifier NA
No. 6 Fuel Oil NA
Middle Distillate Fuel NA
Catalytic Cracked Clarified Oil NA
Water NA
Sulfur Compounds NA
Hydrogen Sulfide hydrogen sulfide
SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 7 of 11
Emulsion
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Residuum, Vacuum NA
Anionic Emulsifier NA
No. 6 Fuel Oil NA
Middle Distillate Fuel NA
Catalytic Cracked Clarified Oil NA
Water NA
Sulfur Compounds NA
Hydrogen Sulfide = 100 lb final RQ
= 45.4 kg final RQ
SARA Section 311/312: The following EPA hazard categories apply to this product:
Acute Health Hazard
Chronic Health Hazard
SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
Residuum, Vacuum None
Anionic Emulsifier None
No. 6 Fuel Oil None
Middle Distillate Fuel None
Catalytic Cracked Clarified Oil None
Water None
Sulfur Compounds None
Hydrogen Sulfide None
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Residuum, Vacuum
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Anionic Emulsifier
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 8 of 11
Emulsion
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
No. 6 Fuel Oil
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Middle Distillate Fuel
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 2452
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Catalytic Cracked Clarified Oil
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 9 of 11
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Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Water
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Sulfur Compounds
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Hydrogen Sulfide
MSDS ID NO.: 0260MAR019 Product name: Marathon Synfuel Binder - Oil Page 10 of 11
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Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 1017
Pennsylvania Right-To-Know: environmental hazard
Massachusetts Right-To Know: Extraordinarily hazardous
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Toxic, Flammable
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous extraordinarily hazardous
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: flammable - fourth degree
New Jersey - Environmental Hazardous SN 1017
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - = 100 lbs Air RQ
List of Hazardous Substances: = 100 lbs Land/Water RQ
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or the Non Domestic Substance List (NDSL).
Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure:
Water Uncontrolled product according to WHMIS classification
criteria.
Hydrogen Sulfide A; B1; D1A; D2B 1% (English Item 851, French Item 1550)
16. OTHER INFORMATION
Additional Information: The pronounced and easily-recognized rotten egg odor of hydrogen sulfide gas
(H2S) can be detected at concentrations as low as 0.003-0.13 ppm. Since higher
H2S concentrations (100-200 ppm) cause olfactory fatigue and other hydrocarbon
odors can "mask" H2S, the sense of smell cannot be used as a reliable indicator of
H2S exposure.
Prepared by: Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
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