Material Safety Data Sheet
MSDS ID NO.: 0261MAR019
Revision date: 10/16/2007
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon ED75/ED85
Synonym: E-75; E75; E-85; E85; E-80; E80; Ethanol/Gasoline Fuel Blend; Fuel Ethanol
ED75/ED85
Chemical Family: Gasoline/Ethanol
Formula: Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information: 419-421-3070
Emergency telephone number: 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
ED75/ED 85 is a mixture of ethyl alcohol and gasoline that is approved for use in an automobile spark ignition engine.
Can contain small amounts of dye and other additives (>0.02%) which are not considered hazardous at the
concentrations used.
Product information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon ED75/ED85 Mixture 100 =1000 ppm TWA =1000 ppm STL
Component Information:
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 1 of 15
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Ethyl Alcohol 64-17-5 75-85 = 1000 ppm TWA =1000 ppm TWA
1900 mg/m3 TWA
Gasoline 81690-81-5 15-25 =300 ppm TWA;
=500 ppm STEL
Saturated Hydrocarbons Mixture 8.3-21
Aromatic Hydrocarbons Mixture 1.5-10
Unsaturated Hydrocarbons Mixture 0.2-3.8
Toluene 108-88-3 0.2-3.8 = 20 ppm TWA = 100 ppm TWA
= 375 mg/m3 TWA
= 150 ppm STEL
= 560 mg/m3 STEL
Xylene 1330-20-7 0.3-2.5 = 100 ppm TWA = 100 ppm TWA
= 435 mg/m3 TWA
= 150 ppm STEL
= 150 ppm STEL
= 655 mg/m3 STEL
= 125 mg/m3 TWA
1,2,4-Trimethylbenzene 95-63-6 0.2-1.3 = 25 ppm TWA
= 25 ppm TWA
Benzene 71-43-2 0.1-0.9 Skin - potential = 25 ppm Ceiling OSHA Exposure Limit
significant contribution = 10 ppm TWA as specified in
to overall exposure by = 50 ppm STEL 1910.1028:
the cutaneous route =1.0 ppm TWA
= 0.5 ppm TWA = 5 ppm STEL
= 2.5 ppm STEL = 0.5 ppm Action
Level
= 180 mg/m3 TWA
Hexane 110-54-3 0.-0.75 Skin - potential
significant contribution = 1800 mg/m3 TWA
to overall exposure by = 50 ppm TWA
the cutaneous route = 500 ppm TWA
= 50 ppm TWA = 1000 ppm STEL
= 3600 mg/m3 STEL
= 500 ppm TWA
= 1000 ppm STEL
Ethyl Benzene 100-41-4 0.1-0.5 = 100 ppm TWA = 100 ppm TWA
= 435 mg/m3 TWA
= 125 ppm STEL
= 125 ppm STEL
= 545 mg/m3 STEL
Naphthalene 91-20-3 0-0.13 Skin - potential = 10 ppm TWA
significant contribution = 50 mg/m3 TWA
to overall exposure by = 15 ppm STEL
= 75 mg/m3 STEL
the cutaneous route
= 10 ppm TWA
= 15 ppm STEL
Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
THIS PRODUCT IS A CLEAR, COLORLESS LIQUID WITH A STRONG HYDROCARBON ODOR. IT IS A VOLATILE
AND EXTREMELY FLAMMABLE LIQUID THAT MAY CAUSE FLASH FIRES. KEEP AWAY FROM HEAT, SPARKS
AND OPEN FLAME. THIS PRODUCT CONTAINS BENZENE WHICH MAY CAUSE CANCER OR BE TOXIC TO
BLOOD-FORMING ORGANS. CONTAINS MATERIAL THAT HAS CAUSED CANCER BASED ON ANIMAL DATA.
NEVER SIPHON THIS PRODUCT BY MOUTH. IF SWALLOWED, THIS PRODUCT MAY GET SUCKED INTO THE
LUNGS (ASPIRATED) AND CAUSE LUNG DAMAGE OR EVEN DEATH.
OSHA WARNING LABEL:
DANGER!
EXTREMELY FLAMMABLE.
ASPIRATION (INADVERTENT SUCTION) OF LIQUID INTO THE LUNGS CAN PRODUCE CHEMICAL PNEUMONIA
OR EVEN DEATH.
CONTAINS BENZENE WHICH MAY CAUSE CANCER OR BE TOXIC TO BLOOD-FORMING ORGANS.
CONTAINS MATERIAL THAT HAS CAUSED CANCER BASED ON ANIMAL DATA.
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 2 of 15
CONSUMER WARNING LABEL:
HEALTH AND SAFETY WARNING STATEMENT:
EXTREMELY FLAMMABLE, VAPORS MAY EXPLODE.
HARMFUL OR FATAL IF SWALLOWED.
LONG TERM EXPOSURE TO VAPORS HAS CAUSED CANCER IN LABORATORY ANIMALS.
KEEP FACE AWAY FROM NOZZLE WHILE FILLING.
KEEP NOZZLE AWAY FROM EYES AND SKIN.
NEVER SIPHON BY MOUTH.
DON'T OVERFILL TANK.
FOR USE AS A MOTOR FUEL ONLY.
STATIC ELECTRICITY, SPARK EXPLOSION, ELECTRONIC DEVICES WARNING:
DO NOT GET BACK IN YOUR VEHICLE WHILE REFUELING.
RE-ENTRY COULD CAUSE STATIC ELECTRICITY BUILD UP.
USE APPROVED CONTAINER.
PUT CONTAINER ON GROUND (NEVER ON OR IN A VEHICLE).
KEEP NOZZLE IN CONTACT WITH CONTAINER.
KEEP CELLULAR PHONES OR OTHER DEVICES IN YOUR VEHICLE DURING REFUELING.
Inhalation: Prolonged breathing of high ethanol vapor concentrations can produce headache,
dizziness, nausea, incoordination and impaired vision. Excessive overexposure can
cause central nervous system depression, loss of consciousness, liver damage and
death resulting from respiratory failure.
Exposure to vapor concentrations of gasoline exceeding 1,000 ppm can cause
respiratory irritation, headache, dizziness, nausea and loss of coordination. Higher
concentrations may cause loss of consciousness, cardiac sensitization, coma and
death resulting from respiratory failure.
Intentional overexposure to high concentrations of product vapors (such as huffing)
can cause nervous system and brain damage, convulsions and sudden death from
cardiac arrest.
Ingestion: Liquid ingestion can cause inebriation, headache, incoordination, gastrointestinal
pain, nausea, and vomiting leading to central nervous system depression. Aspiration
(inadvertent suction) of liquid into the lungs must be avoided as even small quantities
in the lungs can produce chemical pneumonitis, pulmonary edema/hemorrhage and
even death.
Skin contact: Prolonged and repeated liquid contact can cause defatting and drying of the skin and
can lead to irritation and/or dermatitis.
Eye contact: Liquid may cause mild to severe irritation. Splash contact or high vapor
concentrations can produce an immediate burning and stinging sensation.
Carcinogenic Evaluation:
Product information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon ED75/ED85 NE
Mixture
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 3 of 15
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is inadequate evidence for the carcinogenicity of gasoline in humans. IARC
determined that limited evidence of carcinogenicity in animals exists. IARC`s overall
evaluation of gasoline, in spite of limited carcinogenicity evidence, has resulted in the
IARC designation of gasoline as possibly carcinogenic to humans (Group 2B)
because gasoline contains benzene.
IARC has determined that there is inadequate evidence for the carcinogenicity of
gasoline engine exhaust in humans or animals. However, IARC`s overall evaluation
on gasoline engine exhaust, in spite of the absence of carcinogenicity data, has
resulted in the IARC designation of gasoline engine exhaust as possibly carcinogenic
to humans (Group 2B) because of the presence of certain engine exhaust
components.
The International Agency for Research on Cancer (IARC) has determined that there
is sufficient evidence for the carcinogenicity of alcoholic beverages (ethanol) in
humans (Group 1).
Component Information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Ethyl Alcohol A2-Possible Human Known Carcinogen A4 - Not Classifiable as a Present
64-17-5 Carcinogen Listed Human Carcinogen
Toluene Listed A4 - Not Classifiable as a
108-88-3 Human Carcinogen
Xylene Listed A4 - Not Classifiable as a
1330-20-7 Human Carcinogen
Benzene Supplement 7 [1987], Known Carcinogen A1 - Confirmed Human Present
71-43-2 Monograph 29 [1982] Listed Carcinogen
Ethyl Benzene Monograph 77 [2000] Listed A3 - Confirmed animal Present
100-41-4 carcinogen with unknown
relevance to humans
Naphthalene Monograph 82 [2002] Reasonably Anticipated To A4 - Not Classifiable as a Present
91-20-3 Be A Carcinogen Human Carcinogen
Listed
Notes: The International Agency for Research on Cancer (IARC), the National Toxicology
Program (NTP), and OSHA have determined that there is sufficient evidence for the
carcinogenicity of benzene in humans (Group 1A).
The International Agency for Research on Cancer (IARC) has concluded that ethyl
benzene is possibly carcinogenic to humans (Group 2B).
The International Agency for Research on Cancer (IARC) and the Environmental
Protection Agency (EPA) have determined that naphthalene could be a possible
human carcinogen.
4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact: Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
Ingestion: If swallowed, do not induce vomiting and do not give liquids. Immediately call a
physician.
Eye contact: Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 4 of 15
Medical conditions aggravated Pre-existing eye, skin, respiratory, liver and/or kidney disorders may be aggravated
by exposure: by exposure to components of this product.
Pre-existing eye, skin, respiratory disorders and impaired liver function may be
aggravated by overexposure to ethanol. Persons on disulfiram (antabuse) therapy
should be aware that the ethyl alcohol in the product is hazardous to them just as is
alcohol from any source. Disulfiram reactions (vomiting, headache and even
collapse) may follow ingestion of small amounts of alcohol.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
Specific hazards: This product has been determined to be a flammable liquid
per the OSHA Hazard Communication Standard, and should
be handled accordingly. Vapors may travel along the
ground or be moved by ventilation and ignited by many
sources such as pilot lights, sparks, electric motors, static
discharge, or other ignition sources at locations distant from
material handling. Flashback can occur along vapor trail.
For additional fire related information, see NFPA 30 or the
North American Emergency Response Guide 128.
Special protective equipment for firefighters: Avoid using straight water streams. Water may be
ineffective in extinguishing low flash point fires, but can be
used to cool exposed surfaces. Avoid excessive water spray
application. Water spray and foam (AFFF/ATC) must be
applied carefully to avoid frothing and from as far a distance
as possible. Keep run-off water out of sewers and water
sources.
Flash point: -50 to 55 F
Autoignition temperature: C.A. 495 F
Flammable limits in air - lower (%): 1.4 (Gasoline)
Flammable limits in air - upper (%): 19.0 (Ethanol)
NFPA rating: HMIS classification:
Health: 1 Health: 1
Flammability: 3 Flammability: 3
Reactivity: 0 Reactivity: 0
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Eliminate all ignition sources. Advise authorities and National Response Center (800-
424-8802) if the product has entered a water course or sewer. Notify local health
and pollution control agencies, if appropriate. Contain liquid with sand or soil.
Recover and return free product to proper containers. Use suitable absorbent
materials such as vermiculite, sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 5 of 15
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Do not cut, drill, grind or weld on
empty containers since they may contain explosive residues. Avoid skin contact. Exercise good personal hygiene
including removal of soiled clothing and prompt washing with soap and water.
For use as a motor fuel only. Product should never be used as a solvent due to its flammable and potentially toxic
properties. Siphoning by mouth can result in lung aspiration which can be harmful or fatal.
Portable containers of 12 gallons (45 liters) or less should never be filled while they are in or on a motor vehicle or marine
craft. Static electric discharge can ignite fuel vapors when filling non-grounded containers or vehicles on trailers.
Containers should be placed on the ground. The nozzle spout must be kept in contact with the container before and
during the entire filling operation. Use only approved containers. A buildup of static electricity can occur upon re-entry
into a vehicle during fueling especially in cold or dry climate conditions. The charge is generated by the action of
dissimilar fabrics (i.e., clothing and upholstery) rubbing across each other as a person enters/exits the vehicle. A flash fire
can result from this discharge if sufficient flammable vapors are present. Therefore, do not get back in your vehicle while
refueling. Cellular phones and other electronic devices may have the potential to emit electrical charges (sparks). Sparks
in potentially explosive atmospheres (including fueling areas such as gas stations) could cause an explosion if sufficient
flammable vapors are present. Therefore, turn off cellular phones and other electronic devices when working in
potentially explosive atmospheres or keep devices inside your vehicle during refueling.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures: Local or general exhaust required in an enclosed area or when there is inadequate
ventilation.
Respiratory protection: Approved organic vapor chemical cartridge or supplied air respirators should be worn
for exposures to any components exceeding the TLV or STEL. Observe respirator
protection factor criteria cited in ANSI Z88.2. Self-contained breathing apparatus
should be used for fire fighting.
Skin and body protection: Use nitrile rubber, viton or PVA gloves for repeated or prolonged skin exposure.
Eye protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields.
Hygiene measures: No special protective clothing is normally required. Select protective clothing
depending on industrial operations. Use mechanical ventilation equipment that is
explosion-proof.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Clear Liquid
Physical state (Solid/Liquid/Gas): Liquid
Substance type (Pure/Mixture): Mixture
Color: Clear or Colored
Odor: Hydrocarbon
Molecular weight: Not determined.
pH: Neutral
Boiling point/range (5-95%): 90-437 F
Melting point/range: Not determined.
Decomposition temperature: Not applicable.
Specific gravity: 0.70-0.77
Density: 5.9-6.3 lbs/gal
Bulk density: No data available.
Vapor density: No data available.
Vapor pressure: 43-776 mm Hg @ 100 F
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 6 of 15
Evaporation rate: No data available.
Solubility: Appreciable
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): No data available.
VOC content(%): 100%
Viscosity: No data available.
10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.
Polymerization: Will not occur.
Hazardous decomposition products: Combustion produces carbon monoxide, aldehydes,
aromatic and other hydrocarbons.
Materials to avoid: Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid: Excessive heat, sources of ignition and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name CAS Number Inhalation: Dermal: Oral:
Marathon ED75/ED85 Mixture No data available No data available No data available
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 7 of 15
Lifetime inhalation studies with full vaporized gasoline (67, 292 and 2,056 ppm) produced kidney damage and kidney
tumors in male rats but not in female rats or male and female mice. Female mice developed a slightly higher incidence of
liver tumors compared to controls at the highest exposure level. Results from separate studies with compounds
producing similar effects, i.e., 1,4-dichlorobenzene and perchloroethylene, have shown that the kidney damage and
kidney tumors develop via the formation of alpha-2u-globulin, a mechanism unique to the male rat. Humans do not form
alpha-2u-globulin, therefore, tumors resulting from this mechanism are not relevant in humans. The biologic significance
of the mouse liver tumor response with regard to human health risk is questionable.
This product may contain ethanol or ethyl alcohol at a concentration of >0.1% Intentional abuse, misuse or other massive
exposure to ethanol may result in multiple organ damage and/or death. Chronic ingestion of large amounts of ethanol
can cause cancer and damage to the liver, kidney, heart, brain, nervous system and stomach. Ethyl alcohol ingestion
during pregnancy can adversely affect the unborn child. Studies in laboratory animals involving prolonged and repeated
exposures have resulted in such effects as embryotoxicity, immunotoxicity and teratogenicity. Mutagenic effects have
been reported in both in vitro and in vivo systems but usually at high dosages.
Summary of health effect information on gasoline engine exhaust:
Chronic inhalation studies of gasoline engine exhaust in mice, rats and hamsters did not produce any carcinogenic
effects. Condensates/extracts of gasoline engine exhaust produced an increase in tumors compared to controls when
testing by skin painting, subcutaneous injection, intratracheal instillation or implantation into the lungs. Combustion of
gasoline produces gases and particulates which include carbon monoxide, carbon dioxide, oxides of nitrogen and/or
sulfur and hydrocarbons. Significant exposure to carbon monoxide vapors decreases the oxygen carrying capacity of the
blood and may cause tissue hypoxia via formation of carboxyhemoglobin. Overexposure to CO can cause headache,
nausea, nervous system depression, coma and death.
Summary of Health Effect Data on ED75/ED85 Components.
This product contains benzene at a level of >0.1%. Repeated or prolonged exposure to benzene at concentrations in
excess of the TLV may cause serious injury to blood-forming organs. Significant chronic exposure to benzene vapor has
been reported to produce various blood disorders ranging from anemia to certain forms of leukemia (cancer) in man.
Benzene produced tumors in rats and mice in lifetime chronic toxicity studies, but the response has not been consistent
across species, strain, sex or route of exposure. Animal studies on benzene have demonstrated immune toxicity,
chromosomal aberrations, testicular effects and alterations in reproductive cycles and embryo/fetotoxicity, but not
teratogenicity.
This product contains >0.1% ethyl benzene (EB). Rats and mice exposed to 750 ppm EB for 6 hours/day, 5 days/week
for two years developed kidney tumors in male and female rats and lung tumors in male mice and liver tumor in female
mice.
This product contains >0.1% naphthalene. Exposure to naphthalene at 30 ppm for two years caused lung tumors in
female mice. Male mice with the same exposure did not develop tumors. Exposure to 10-60 ppm naphthalene for 2 years
caused tumors in the tissue lining of the nose and respiratory tract in male and female rats. Oral administration of 133-
267 mg/kg/day of naphthalene in mice for up to 90 days did not produce mortality, systemic toxicity, adversely affect
organ or body weight or produce changes in blood. Repeated oral administration of naphthalene produced an anemia in
dogs. Repeated intraperitoneal doses of naphthalene produced lung damage in mice. Repeated high doses of
naphthalene has caused the formation of cataracts and retinotoxicity in the eyes of rats and rabbits due to accumulation
of 1,2-naphthoquinone, a toxic metabolite. Effects in human eyes is uncertain and not well documented. Pregnant rats
administered intraperitoneal doses of naphthalene during gestation gave birth to offspring that had delayed heart and
bone development. Pregnant mice given near lethal doses of naphthalene showed no significant maternal toxicity and a
reduction in the number of pups per litter, but no gross abnormalities in offspring. Suppressed spermatogenesis and
progeny development have been reported in mice, rats and guinea pigs after exposure to high concentrations of
naphthalene in their drinking water. Certain groups or individuals, i.e., infants, Semites, Arabs, Asians and Blacks, with a
certain blood enzyme deficiency (glucose-6-phosphate dehydrogenase) are particularly susceptible to hemolytic agents
and can rapidly develop hemolytic anemia and systemic poisoning from ingestion or inhalation of naphthalene.
This product may contain hexane at a level of >1.0%. Studies in laboratory animals have produced systemic toxicity in
blood, spleen and lungs. Fetotoxicity has been observed at hexane concentrations that produced maternal toxicity.
Long term exposure to high concentrations of hexane has been shown to cause testicular effects and nervous system
damage.
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 8 of 15
12. ECOLOGICAL INFORMATION
Ecotoxicity effects: Product can cause fouling of shoreline and may be harmful to aquatic life in low
concentrations. This product does not concentrate or accumulate in the food chain.
The aquatic toxicity of gasoline is as follows:
FreshwaterToxicity:
LD50 is 8 ppm at 96 hours in bluegill.
TLM is 90 ppm at 24 hours in juvenile shad.
SaltwaterToxicity:
LC50 is 2 ppm at 96 hours in mullet.
LD50 is 1.5 ppm at 96 hours in grass shrimp.
LC50 is 2 ppm at 96 hours in menhaden.
TLM is 91 ppm at 24 hours in juvenile shad.
13. DISPOSAL CONSIDERATIONS
Cleanup Considerations: This product as produced is not specifically listed as an EPA
RCRA hazardous waste according to federal regulations (40
CFR 261). However, when discarded or disposed of, it may
meet the criteria of an "characteristic" hazardous waste. This
product could also contain benzene at >0.5 ppm and could
exhibit the characteristics of "toxicity" as determined by the
toxicity characteristic leaching procedure (TCLP). This
material could become a hazardous waste if mixed or
contaminated with a hazardous waste or other substance(s).
It is the responsibility of the user to determine if disposal
material is hazardous according to federal, state and local
regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information: This material when transported via US commerce would be regulated by DOT
Regulations.
Proper shipping name: Alcohols, N.O.S.
UN/Identification No: UN 1987
Hazard Class: 3
Packing group: II
DOT reportable quantity (lbs): Not applicable.
TDG (Canada):
Proper shipping name: Alcohols, N.O.S.
UN/Identification No: UN 1987
Hazard Class: 3
Packing group: II
Regulated substances: Not applicable.
15. REGULATORY INFORMATION
US Federal Regulatory
Information:
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 9 of 15
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Ethyl Alcohol NA
Gasoline NA
Saturated Hydrocarbons NA
Aromatic Hydrocarbons NA
Unsaturated Hydrocarbons NA
Toluene NA
Xylene NA
1,2,4-Trimethylbenzene NA
Benzene NA
Hexane NA
Ethyl Benzene NA
Naphthalene NA
SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Ethyl Alcohol NA
Gasoline NA
Saturated Hydrocarbons NA
Aromatic Hydrocarbons NA
Unsaturated Hydrocarbons NA
Toluene = 0.454 kg final RQ
= 1 lb final RQ
= 1000 lb final RQ
= 454 kg final RQ
Xylene = 100 lb final RQ
= 45.4 kg final RQ
1,2,4-Trimethylbenzene NA
Benzene = 10 lb final RQ
= 4.54 kg final RQ
Hexane = 2270 kg final RQ
= 5000 lb final RQ
Ethyl Benzene = 1000 lb final RQ
= 454 kg final RQ
Naphthalene = 0.454 kg final RQ
= 1 lb final RQ
= 100 lb final RQ
= 45.4 kg final RQ
SARA Section 311/312: The following EPA hazard categories apply to this product:
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 10 of 15
Name CERCLA/SARA 313 Emission reporting:
Ethyl Alcohol None
Gasoline None
Saturated Hydrocarbons None
Aromatic Hydrocarbons None
Unsaturated Hydrocarbons None
Toluene = 1.0 % de minimis concentration
Xylene = 1.0 % de minimis concentration
1,2,4-Trimethylbenzene = 1.0 % de minimis concentration
Benzene = 0.1 % de minimis concentration
Hexane = 1.0 % de minimis concentration
Ethyl Benzene = 0.1 % de minimis concentration
Naphthalene = 0.1 % de minimis concentration
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Ethyl Alcohol
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Gasoline
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Saturated Hydrocarbons
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 11 of 15
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Aromatic Hydrocarbons
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Unsaturated Hydrocarbons
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 12 of 15
Toluene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Listed
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Xylene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Listed
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
1,2,4-Trimethylbenzene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Listed
Substances List:
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 13 of 15
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Benzene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Listed
Massachusetts Extraordinarily Hazardous carcinogen; extraordinarily hazardous
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Listed
Substances:
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Hexane
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Ethyl Benzene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 14 of 15
New Jersey - Special Hazardous Substances: Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Naphthalene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure:
Ethyl Alcohol 0.1 %
Toluene B2, D2A, D2B 1%
Xylene B2, D2A, D2B
1,2,4-Trimethylbenzene B3 0.1 %
Benzene B2, D2A, D2B 0.1 %
Hexane B2, D2A 1%
Ethyl Benzene B2, D2A, D2B 0.1 %
Naphthalene B4, D2A 1%
16. OTHER INFORMATION
Additional Information: No data available.
Prepared by: Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0261MAR019 Product name: Marathon ED75/ED85 Page 15 of 15
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