046667
DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 8040
NIIN: 00N002122
Manufacturer's CAGE: 01PD6
Part No. Indicator: B
Part Number/Trade Name: LN-603 LIQUID NAILS, 0600301
===========================================================================
General Information
===========================================================================
Item Name:
Company's Name: MACCO ADHESIVES
Company's Street: 825 EUCLID AVE
Company's P. O. Box:
Company's City: CLEVELAND
Company's State: OH
Company's Country: US
Company's Zip Code: 44115
Company's Emerg Ph #: 800-634-0015
Company's Info Ph #: 216-344-8049
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code:
Safety Focal Point: N
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 002
Status: SMJ
Date MSDS Prepared: 10MAR95
Safety Data Review Date: 13OCT97
Supply Item Manager:
MSDS Preparer's Name:
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Other MSDS Number:
MSDS Serial Number: CFLMM
Specification Number:
Spec Type, Grade, Class:
Hazard Characteristic Code: NK
Unit Of Issue:
Unit Of Issue Container Qty:
Type Of Container:
Net Unit Weight:
Report for NIIN: 00N002122
NRC/State License Number:
Net Explosive Weight:
Net Propellant Weight-Ammo:
Coast Guard Ammunition Code:
===========================================================================
Ingredients/Identity Information
Page 1
046667
===========================================================================
Proprietary: NO
Ingredient: STYRENE POLYMER WITH 1,3-BUTADIENE; (BUTADIENE-STYRENE
POLYMER) (RUBBER)
Ingredient Sequence Number: 01
Percent: 1-5
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: WL6478000
CAS Number: 9003-55-8
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE)
Ingredient Sequence Number: 02
Percent: 5-10
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: FF9335000
CAS Number: 471-34-1
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: CLAY (KAOLIN); (KAOLIN)
Ingredient Sequence Number: 03
Percent: 30-40
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: GF1670500
CAS Number: 1332-58-7
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 2 MG/M3 TDUST
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: VM & P NAPHTHA
Ingredient Sequence Number: 04
Percent: 30-40
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 1003161VN
CAS Number: 64742-89-8
OSHA PEL: N/K (FP N)
Report for NIIN: 00N002122
ACGIH TLV: N/K (FP N)
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: SILICA, CRYSTALLINE - QUARTZ
Ingredient Sequence Number: 05
Percent: 0.1-1
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: VV7330000
CAS Number: 14808-60-7
Page 2
046667
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 0.1 MG/M3 RDUST
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: CYCLOHEXANE (SARA 313) (CERCLA)
Ingredient Sequence Number: 06
Percent: 1-5
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: GU6300000
CAS Number: 110-82-7
OSHA PEL: 300 PPM
ACGIH TLV: 300 PPM
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)
HEAVY NAPHTHENIC
Ingredient Sequence Number: 07
Percent: 5-10
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: PY8035001
CAS Number: 64742-52-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: STEAM-CRACKED, POLYMERS W/LIGHT STEAM-CRACKED PETROLEUM
NAPHTHA
Ingredient Sequence Number: 08
Percent: 10-20
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 1008542SP
CAS Number: 68410-16-2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Other Recommended Limit: N/K
-------------------------------------
Report for NIIN: 00N002122
Proprietary: NO
Ingredient: BUTADIENE, STYRENE, DIVINYLBENZENE POLYMER
Ingredient Sequence Number: 09
Percent: 5-10
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 1009628BS
CAS Number: 26471-45-4
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: SUPDAT:CONSIDERED LIMITED FOR CARCINOGENICITY. CRYSTALLINE
SILICA IS ALSO A KNOWN CAUSE OF SILICOSIS, A NON (ING 11)
Ingredient Sequence Number: 10
Page 3
046667
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 10:CANCEROUS LUNG DISEASE, NTP HAS CLASSIFIED CRYSTALLINE
SILICA A REASONABLY ANTIC HUMAN CARCINOGEN.
Ingredient Sequence Number: 11
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: FIRST AID PROC:INGEST:IF SWALLOWED, OBTAIN MEDICAL TREATMENT
IMMEDIATELY.
Ingredient Sequence Number: 12
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: SPILL PROC:SPILLS-SHUT OFF LEAK IF SAFE TO DO SO. DIKE &
Report for NIIN: 00N002122
CONTAIN SPILL. PUMP TO STORAGE/SALVAGE VESSELS. USE (ING 14)
Ingredient Sequence Number: 13
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 13:ABSORB TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATL
& RINSE WATER OUT OF SEWERS & WATER COURSES. (ING 15)
Ingredient Sequence Number: 14
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
Page 4
046667
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 14:SM SPILLS-USE ABSORBENT TO PICK UP RESIDUE & DISPOSE OF
PROPERLY.
Ingredient Sequence Number: 15
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: OTHER PREC:AVOIDED, USE APPROP RESP PROT AS DIRECTED UNDER
SPEC PROT INFO. EMPTY CNTNRS MAY CONTAIN HAZARDOUS (ING 17)
Ingredient Sequence Number: 16
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 16:RESIDUES. GROUND EQUIP WHEN TRANSFERRING TO PREVENT
ACCUMULATION OF STATIC CHARGE.
Report for NIIN: 00N002122
Ingredient Sequence Number: 17
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
===========================================================================
Physical/Chemical Characteristics
===========================================================================
Appearance And Odor: TAN PASTE.
Boiling Point: 179F,82C
Melting Point: N/K
Vapor Pressure (MM Hg/70 F): N/K
Vapor Density (Air=1): N/K
Specific Gravity: 1.125
Decomposition Temperature: N/K
Evaporation Rate And Ref: NOT KNOWN
Solubility In Water: NOT KNOWN
Percent Volatiles By Volume: 51.67
Viscosity:
pH: N/K
Radioactivity:
Form (Radioactive Matl):
Page 5
046667
Magnetism (Milligauss):
Corrosion Rate (IPY): N/K
Autoignition Temperature:
===========================================================================
Fire and Explosion Hazard Data
===========================================================================
Flash Point: 23.0F,-5.0C
Flash Point Method: SCC
Lower Explosive Limit: 1.2%
Upper Explosive Limit: 8.4%
Extinguishing Media: DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE.
Special Fire Fighting Proc: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PORTECT EXPOSED CONTAINERS.
Unusual Fire And Expl Hazrds: CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT/FIRE. VAPS MAY IGNITE EXPLOSIVELY @ AMBIENT TEMPS. VAPS ARE
HVR/AIR & MAY TRAVEL LONG DIST TO A (SUPDAT)
===========================================================================
Reactivity Data
===========================================================================
Stability: YES
Cond To Avoid (Stability): ELEVATED TEMPERATURES.
Materials To Avoid: CONT W/OXIDIZING AGENT, STORAGE NEAR ACIDS, SPARKS,
OPEN FLAME. IGNITION SOURCES.
Hazardous Decomp Products: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT.
Report for NIIN: 00N002122
===========================================================================
Health Hazard Data
===========================================================================
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: ACUTE:INHAL:IRRIT OF RESP TRACT. PRLNGD
INHAL MAY LEAD TO FATG, DIZZ &/OR LT HEAD, HDCH, NAUS, VOMIT, CNS DEPRESS,
RESP PROBS, LOSS OF CONSCIOUSNESS, DEATH. SKIN:IRRIT. PRLNGD/RPTD CONT CAN
CAUSE DERM, DEFAT. EYE:IRRIT. PRLNGD/RPTD CONT CAN CAUSE CONJ, TEARING OF
EYES, REDNESS. INGEST:MAY CAUSE LUNG (EFTS OF OVEREXP)
Carcinogenicity - NTP: YES
Carcinogenicity - IARC: YES
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: SILICA, CRYSTALLINE-QUARTZ:IARC MONO, VOL 68,
1997:GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994:ANTIC TO BE CARCIN.
Signs/Symptoms Of Overexp: HLTH HAZ:INFLAMM & DMG DUE TO ASPIR OF MATL
INTO LUNGS, HDCH, NAUS, VOMIT, DIARR, GI DISTURB, CNS DEPRESS. SUPP HLTH
INFO:OTHER EFTS OF OVEREXP MAY INCL TOX TO LUNGS. CONTAINS CRYSTALLINE
SILICA WHICH IS CONSIDERED HAZ BY INHAL, IARC HAS CLASSIFIED CRYSTALLINE
SILICA AS PROBABLY CARCIN FOR HUMANS (2A. THIS (SUPDAT)
Med Cond Aggravated By Exp: EYE, SKIN, RESPIRATORY DISORDERS.
Emergency/First Aid Proc: INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT
CONTINUED BRTHG. GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYG IF NEC.
GET MED HELP FOR ANY BRTHG DFCLTY. SKIN:FLUSH W/WATER, THEN WASH THORO W/
SOAP & WATER. REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE RE-USE. EYE:
FLUSH IMMED W/LG AMTS OF WATER, ESPECIALLY UNDER LIDS FOR @ LST 15 MINS. IF
IRRIT/OTHER EFTS PERSIST, OBTAIN MED TREATMENT. (ING 12)
===========================================================================
Precautions for Safe Handling and Use
===========================================================================
Page 6
046667
Steps If Matl Released/Spill: COMPLY W/ALL APPLIC HLTH & ENVIR REGS. ELIM
ALL SOURCES OF IGNIT. VENTILATE AREA W/EXPLO-PROOF EQUIP. USE NON-SPK
TOOLS. EVAC ALL UNNEC PERS. PLACE COLLECTED MATL IMPROPER CNTNR. COMPLETE
PERSONAL PROT EQUIP MUST BE USED DURING CLEANUP. LG (ING 13)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
STATE & LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
Precautions-Handling/Storing: STORE <80F. KEEP AWAY FROM HEAT, SPKS & OPEN
FLAME. USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF
CHILDREN.
Other Precautions: AVOID CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP CNTNRS
TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN
FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING/ABRADING(SANDING) PAINTED
SURFS. IF SUCH CNDTNS CANNOT BE (ING 16)
===========================================================================
Control Measures
===========================================================================
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW
APPLICABLE STANDARS. WHERE RESPIRTORY PROTECTION IS REQUIRED, USE ONLY
NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 VFR
1910.134.
Report for NIIN: 00N002122
Ventilation: PROVIDE DILUTION VENT/LOC EXHAUST TO PVNT BUILD-UP OF VAPS.
USE EXPLOSION-PROOF EQUIP. USE NON-SPARKING EQUIP.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING, APRON, BOOTS.
Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY
BEFORE EATING OR SMOKING.
Suppl. Safety & Health Data: EXPLO HAZ:SOURCE OF IGNIT & FLASH BACK. VAPS
CAN FORM EXPLOSIVE MIX IN AIR @ ELEVATED TEMPS. MAY DECOMPOSE UNDER FIRE
CNDTNS IN AIR @ ELEVATED TOX GASES. EFTS OF OVEREXP:CLASSIFICATION IS BASED
ON FINDINGS OF LAB ANIMAL STUDIES THAT WERE CONSIDERED SUFFICIENT & DATA
FROM EPIDEMIOLOGICAL STUDIES THAT WERE (ING 10)
===========================================================================
Transportation Data
===========================================================================
Transportation Action Code:
Transportation Focal Point:
Trans Data Review Date:
DOT PSN Code:
DOT Symbol:
DOT Proper Shipping Name:
DOT Class:
DOT ID Number:
DOT Pack Group:
DOT Label:
DOT/DoD Exemption Number:
IMO PSN Code:
IMO Proper Shipping Name:
IMO Regulations Page Number:
IMO UN Number:
IMO UN Class:
IMO Subsidiary Risk Label:
IATA PSN Code:
IATA UN ID Number:
IATA Proper Shipping Name:
IATA UN Class:
Page 7
046667
IATA Subsidiary Risk Class:
IATA Label:
AFI PSN Code:
AFI Symbols:
AFI Prop. Shipping Name:
AFI Class:
AFI ID Number:
AFI Pack Group:
AFI Label:
AFI Special Prov:
AFI Basic Pac Ref:
MMAC Code:
N.O.S. Shipping Name:
Additional Trans Data:
Report for NIIN: 00N002122
===========================================================================
Disposal Data
===========================================================================
Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Disposal Supplemental Data:
1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
2nd EPA Acute Hazard New:
3rd EPA Haz Wst Code New:
3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
===========================================================================
Label Data
===========================================================================
Label Required: YES
Technical Review Date: 13OCT97
Label Date: 13OCT97
MFR Label Number:
Label Status: G
Common Name: LN-603 LIQUID NAILS, 0600301
Chronic Hazard: YES
Signal Word: DANGER!
Acute Health Hazard-None:
Acute Health Hazard-Slight:
Acute Health Hazard-Moderate: X
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight: X
Contact Hazard-Moderate:
Contact Hazard-Severe:
Fire Hazard-None:
Fire Hazard-Slight:
Fire Hazard-Moderate:
Page 8
046667
Fire Hazard-Severe: X
Reactivity Hazard-None: X
Reactivity Hazard-Slight:
Reactivity Hazard-Moderate:
Reactivity Hazard-Severe:
Special Hazard Precautions: EXTREMELY FLAMMABLE. ACUTE: INHAL:IRRITATION
OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO FATIGUE, DIZZINESS
&/OR LT HEAD, HEADACHE, NAUSEA, VOMITING, CNS DEPRESSION, RESPIRATORY
PROBLEMS, LOSS OF CONSCIOUSNESS, DEATH. SKIN: IRRITATION. EYE: IRRITATION.
Report for NIIN: 00N002122
PROLONGED/REPEATED CONTACT CAN CAUSE CONJ, TEARING OF EYES, REDNESS.
INGEST: MAY CAUSE LUNG INFLAMMATION DUE TO ASPIRATION, NAUSEA, HEADACHE,
VOMITING, DIARRHEA, GI DISTURBANCES, CNS DEPRESSION. CHRONIC: CANCER
HAZARD. CONTAINS SILICA, CRYSTALLINE-QUARTZ, WHICH IS LISTED AS A HUMAN
LUNG CARCINOGEN (FP N). SKIN: DERMATITIS, DEFATTING. INHAL: SILICOSIS.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: MACCO ADHESIVES
Label Street: 825 EUCLID AVE
Label P.O. Box:
Label City: CLEVELAND
Label State: OH
Label Zip Code: 44115
Label Country: US
Label Emergency Number: 800-634-0015
Year Procured:
Page 9
|