006799
DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 6810
NIIN: 00D020102
Manufacturer's CAGE: 63759
Part No. Indicator: A
Part Number/Trade Name: MALEIC ACID
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General Information
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Item Name:
Company's Name: WARDS NATURAL SCIENCE ESTABLISHMENT INC
Company's Street: 5100 W HENRIETTA RD
Company's P. O. Box: 92912
Company's City: ROCHESTER
Company's State: NY
Company's Country: US
Company's Zip Code: 14692
Company's Emerg Ph #: 716-226-6177 800-424-9300(CHEMTREC)
Company's Info Ph #: 716-334-4222 716-359-2502
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code:
Safety Focal Point: D
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SE
Date MSDS Prepared: 30SEP92
Safety Data Review Date: 07NOV96
Supply Item Manager: CX
MSDS Preparer's Name: ALEXANDER A. PICCIRILLI
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Other MSDS Number:
MSDS Serial Number: CBSWV
Specification Number: NONE
Spec Type, Grade, Class: NONE
Hazard Characteristic Code: T6
Unit Of Issue: NK
Unit Of Issue Container Qty: UNKNOWN
Type Of Container: UNKNOWN
Net Unit Weight: UNKNOWN
Report for NIIN: 00D020102
NRC/State License Number: N/R
Net Explosive Weight: N/R
Net Propellant Weight-Ammo: N/R
Coast Guard Ammunition Code: N/R
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Ingredients/Identity Information
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006799
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Proprietary: NO
Ingredient: MALEIC ACID (CERCLA)
Ingredient Sequence Number: 01
Percent: 100
Ingredient Action Code:
Ingredient Focal Point: D
NIOSH (RTECS) Number: OM9625000
CAS Number: 110-16-7
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
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Physical/Chemical Characteristics
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Appearance And Odor: WHITE CRYSTALLINE POWDER;FAINT ACIDULOUS ODOR.
Boiling Point: DECOMPOSES
Melting Point: 268F,131C
Vapor Pressure (MM Hg/70 F): NEGLIGIBLE
Vapor Density (Air=1): 4.0
Specific Gravity: 1.59
Decomposition Temperature: 275F,135C
Evaporation Rate And Ref: NON-VOLATILE
Solubility In Water: APPRECIABLE
Percent Volatiles By Volume: NIL
Viscosity: N/R
pH: N/R
Radioactivity: N/R
Form (Radioactive Matl):
Magnetism (Milligauss): N/P
Corrosion Rate (IPY): UNKNOWN
Autoignition Temperature: N/K
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Fire and Explosion Hazard Data
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Flash Point: NON-FLAMMABLE
Flash Point Method: N/P
Lower Explosive Limit: N/K
Upper Explosive Limit: N/K
Extinguishing Media: WATER SPRAY,DRY CHEMICAL(ABC),CARBON DIOXIDE,HALON,
STANDARD FOAM.
Special Fire Fighting Proc: USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire And Expl Hazrds: SUBLIMES AT 396F;EMITS FUMES UPON HEATING.
DECOMPOSITION FUMES MAY BE TOXIC.REACTS VIGOROUSLY WITH OXIDIZING AGENTS.
Report for NIIN: 00D020102
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Reactivity Data
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Stability: YES
Cond To Avoid (Stability): AT 230C,IT CONVERTS TO FUMARIC ACID AND
UNDERGOES PARTIAL CARBONIZATION AND FORMATION OF MALEIC ANHYDRIDE.
Materials To Avoid: STRONG OXIDIZERS,ALKALI METALS,STRONG BASES,AMINES.
SOLUTIONS OF MALEIC ACID MAY CORRODE METAL.
Hazardous Decomp Products: AT 230C,CONVERTS TO FUMARIC ACID AND UNDERGOES
PARTIAL CARBONIZATION AND FORMATION OF MALEIC ANHYDRIDE(READILY SUBLIMES)
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): N/R
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Health Hazard Data
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LD50-LC50 Mixture: ORAL LD50 (RAT) IS 708MG/KG
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: EYES:CORROSIVE.MAY CAUSE IRRITATION,POSSIBLE
CORNEAL EROSION.SKIN:MAY CAUSE IRRITATION AND DERMATITIS.INGEST:MODERATELY
TOXIC.MAY BE FATAL IF SWALLOWED.MAY CAUSE GI TRACT IRRITATION.MAY DAMAGE
MOUTH,ESOPHAGUS AND STOMACH.INHAL:MAY CAUSE RESPIRATORY IRRITATION.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE
IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Signs/Symptoms Of Overexp: INHAL:DIFFICULTY BREATHING,COUGHING.EYES:
REDNESS,PAIN.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP
AND WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.
INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.
GET MEDICAL ATTENTION.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED
MEDICAL ATTENTION.IF CONSCIOUS,GIVE 1-2 GLASSES OF WATER OR MILK.
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Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: RECOVER IF NOT CONTAMINATED.USE PROPER
RESPIRATORY AND PROTECTIVE EQUIPMENT.SWEEP OR VACUUM;DO NOT CREATE DUST;
PLACE IN AN APPROPRIATE CONTAINER FOR DISPOSAL.FLUSH SPILL AREA WITH WATER.
DO NOT POLLUTE WATERWAYS WITH RINSEATE.
Neutralizing Agent: NOT REPORTED.
Waste Disposal Method: DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.MAY BE INCINERATED.
Precautions-Handling/Storing: STORE IN A COOL,DRY,WELL-VENTILATED PLACE.
KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND
INCOMPATIBLE MATERIALS.
Other Precautions: AVOID SKIN AND EYE CONTACT.DO NOT INHALE VAPORS/MISTS.
Report for NIIN: 00D020102
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Control Measures
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Respiratory Protection: WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE A NIOSH/MSHA APPROVED RESPIRATOR FOR DUST.
Ventilation: LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Protective Gloves: RUBBER.
Eye Protection: CHEMICAL SAFETY GLASSES.
Other Protective Equipment: SMOCK,APRON.PROVIDE A LOCAL EYE WASH STATION
AND SAFETY SHOWER.
Work Hygienic Practices: EXECISE GOOD LABORATORY PRACTICES.WASH HANDS
AFTER USE AND BEFORE EATING.
Suppl. Safety & Health Data: NONE
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Transportation Data
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Transportation Action Code:
Transportation Focal Point: D
Trans Data Review Date: 98043
DOT PSN Code: QMK
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DOT Symbol:
DOT Proper Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
DOT Class: 6.1
DOT ID Number: UN2811
DOT Pack Group: III
DOT Label: KEEP AWAY FROM FOOD
DOT/DoD Exemption Number: N/R
IMO PSN Code: OTZ
IMO Proper Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. o
IMO Regulations Page Number: 6270-6
IMO UN Number: 2811
IMO UN Class: 6.1
IMO Subsidiary Risk Label: -
IATA PSN Code: YJJ
IATA UN ID Number: 2811
IATA Proper Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. *
IATA UN Class: 6.1
IATA Subsidiary Risk Class:
IATA Label: TOXIC
AFI PSN Code: YIF
AFI Symbols: *
AFI Prop. Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
AFI Class: 6.1
AFI ID Number: UN2811
AFI Pack Group: III
AFI Label:
AFI Special Prov: P5
AFI Basic Pac Ref: A10.6
MMAC Code: NR
N.O.S. Shipping Name: MALEIC ACID.
Additional Trans Data: NONE
Report for NIIN: 00D020102
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Disposal Data
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Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Disposal Supplemental Data:
1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
2nd EPA Acute Hazard New:
3rd EPA Haz Wst Code New:
3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
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Label Data
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Label Required: YES
Technical Review Date: 07NOV96
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Label Date:
MFR Label Number: UNKNOWN
Label Status: F
Common Name: MALEIC ACID
Chronic Hazard: N/P
Signal Word: WARNING!
Acute Health Hazard-None:
Acute Health Hazard-Slight:
Acute Health Hazard-Moderate: X
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight: X
Contact Hazard-Moderate:
Contact Hazard-Severe:
Fire Hazard-None:
Fire Hazard-Slight: X
Fire Hazard-Moderate:
Fire Hazard-Severe:
Reactivity Hazard-None: X
Reactivity Hazard-Slight:
Reactivity Hazard-Moderate:
Reactivity Hazard-Severe:
Special Hazard Precautions: EYES:CORROSIVE.MAY CAUSE IRRITATION,POSSIBLE
CORNEAL EROSION.SKIN:MAY CAUSE IRRITATION AND DERMATITIS.INGEST:MODERATELY
TOXIC.MAY BE FATAL IF SWALLOWED.MAY CAUSE GI TRACT IRRITATION.MAY DAMAGE
MOUTH,ESOPHAGUS AND STOMACH.INHAL:MAY CAUSE RESPIRATORY IRRITATION. FIRST
Report for NIIN: 00D020102
AID: SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH
WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR.
GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.GET MEDICAL ATTENTION.
INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF
CONSCIOUS,GIVE 1-2 GLASSES OF WATER OR MILK.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory:
Label Name: WARDS NATURAL SCIENCE ESTABLISHMENT INC
Label Street: 5100 W HENRIETTA RD
Label P.O. Box: 92912
Label City: ROCHESTER
Label State: NY
Label Zip Code: 14692
Label Country: US
Label Emergency Number: 716-226-6177 800-424-9300(CHEMTREC)
Year Procured: 1996
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