113783
DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 6810
NIIN: 00N085038
Manufacturer's CAGE: 21076
Part No. Indicator: A
Part Number/Trade Name: O-PHOSPHORIC ACID 85%
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General Information
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Item Name:
Company's Name: SIGMA CHEMICAL CO
Company's Street:
Company's P. O. Box: 14508
Company's City: ST LOUIS
Company's State: MO
Company's Country: US
Company's Zip Code: 63178
Company's Emerg Ph #: 314-771-5765
Company's Info Ph #: 314-771-5765
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code: A
Safety Focal Point: N
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared: 27NOV92
Safety Data Review Date: 15APR98
Supply Item Manager:
MSDS Preparer's Name:
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Other MSDS Number:
MSDS Serial Number: CGVLV
Specification Number:
Spec Type, Grade, Class:
Hazard Characteristic Code:
Unit Of Issue:
Unit Of Issue Container Qty:
Type Of Container:
Net Unit Weight:
Report for NIIN: 00N085038
NRC/State License Number:
Net Explosive Weight:
Net Propellant Weight-Ammo:
Coast Guard Ammunition Code:
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Ingredients/Identity Information
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Proprietary: NO
Ingredient: PHOSPHORIC ACID (SARA 313) (CERCLA)
Ingredient Sequence Number: 01
Percent: 85
Ingredient Action Code: A
Ingredient Focal Point: N
NIOSH (RTECS) Number: TB6300000
CAS Number: 7664-38-2
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3;3 STEL
Other Recommended Limit: N/K
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Physical/Chemical Characteristics
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Appearance And Odor: COLORLESS LIQUID.
Boiling Point: N/K
Melting Point: N/K
Vapor Pressure (MM Hg/70 F): 2.2 @ 20C
Vapor Density (Air=1): 3.4
Specific Gravity: 1.685
Decomposition Temperature: N/K
Evaporation Rate And Ref: N/K
Solubility In Water: N/K
Percent Volatiles By Volume: N/K
Viscosity:
pH: N/K
Radioactivity:
Form (Radioactive Matl):
Magnetism (Milligauss):
Corrosion Rate (IPY): N/K
Autoignition Temperature:
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Fire and Explosion Hazard Data
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Flash Point: NONE
Flash Point Method: N/P
Lower Explosive Limit: N/K
Upper Explosive Limit: N/K
Extinguishing Media: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Special Fire Fighting Proc: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire And Expl Hazrds: EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Report for NIIN: 00N085038
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Reactivity Data
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Stability: YES
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG BASES. FINELY POWDERED METALS. FORMS A
DETONABLE MIXTURE W/NITROMETHANE.
Hazardous Decomp Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
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Health Hazard Data
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LD50-LC50 Mixture: LD50:(ORAL,RAT) 1530 MG/KG.
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Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: ACUTE:HARMFUL IF SWALLOWED, INHALED OR
ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF
MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN. INHALATION MAY
BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND EDEMA OF THE LARYNX AND
BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY (EFTS OF OVEREXP)
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: HLTH HAZ:EDEMA. SYMPTOMS OF EXPOSURE MAY
INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF
BREATH, HEADACHE, NAUSEA AND VOMITING. TARGET ORGAN DATA:BEHAVORIAL
(SOMNOLENCE); KIDNEY, URETER, BLADDER (HEMATURIA); SKIN AND APPENDAGES
(HAIR).
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT
LST 15 MINS. ASSURE ADEQ FLUSHING BY SEPARATING EYELIDS W/FINGERS. SKIN:
IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS WHILE REMOVING
CONTAM CLTHG & SHOES. WASH CONTAM CLTHG BEFORE REUSE. DISCARD CONTAM SHOES.
INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT,
GIVE OXYG. INGEST:WASH OUT MOUTH W/WATER PROVIDED (SUPDAT)
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Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: EVACUATE AREA. WEAR NIOSH APPROVED SCBA,
RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/DRY LIME OR SODA ASH, PICK UP,
KEEP IN CLOSED CONTAINER & HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH
SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent: DRY LIME OR SODA ASH.
Waste Disposal Method: DISP MUST BE I/A/W FED, STATE & LOC REGS (FP N).
FOR SM QTYS:CAUTIOUSLY ADD TO LG STIRRED EXCESS OF WATER. ADJUST PH TO
NEUT, SEPARATE ANY INSOL SOLIDS/LIQS & PACKAGE THEM FOR HAZ-WASTE DISP.
FLUSH AQ SOLN DOWN DRAIN W/PLENTY OF WATER. THE (SUPDAT)
Precautions-Handling/Storing: DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON
SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. HARMFUL LIQUID.
KEEP TIGHTLY CLOSED.
Report for NIIN: 00N085038
Other Precautions: STORE IN A COOL, DRY PLACE. CORROSIVE. CAUSES BURNS.
HARMFUL BY INHALATION, IN CONTACT W/SKIN & IF SWALLOWED.
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Control Measures
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Respiratory Protection: NIOSH APPROVED RESPIRATOR.
Ventilation: MECHANICAL EXHAUST REQUIRED.
Protective Gloves: HEAVY RUBBER GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA (FP N). WEAR SUITABLE PROTECTIVE CLOTHING.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. TAKE OFF
IMMEDIATELY ALL CONTAMINATED CLOTHING.
Suppl. Safety & Health Data: FIRST AID PROC:PERSON IS CONSCIOUS. CALL MD.
WASTE DISP METH:HYDROLYSIS & NEUTRALIZATION REACTIONS MAY GENERATE HEAT &
FUMES WHICH CAN BE CONTROLLED BY RATE OF ADDITION. EYE PROT:& FULL LENGTH
FACESHIELD (FP N).
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Transportation Data
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Transportation Action Code:
Transportation Focal Point:
Trans Data Review Date:
DOT PSN Code:
DOT Symbol:
DOT Proper Shipping Name:
DOT Class:
DOT ID Number:
DOT Pack Group:
DOT Label:
DOT/DoD Exemption Number:
IMO PSN Code:
IMO Proper Shipping Name:
IMO Regulations Page Number:
IMO UN Number:
IMO UN Class:
IMO Subsidiary Risk Label:
IATA PSN Code:
IATA UN ID Number:
IATA Proper Shipping Name:
IATA UN Class:
IATA Subsidiary Risk Class:
IATA Label:
AFI PSN Code:
AFI Symbols:
AFI Prop. Shipping Name:
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AFI ID Number:
AFI Pack Group:
AFI Label:
AFI Special Prov:
AFI Basic Pac Ref:
MMAC Code:
Report for NIIN: 00N085038
N.O.S. Shipping Name:
Additional Trans Data:
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Disposal Data
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Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Disposal Supplemental Data:
1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
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3rd EPA Haz Wst Code New:
3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
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Label Data
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Label Required: YES
Technical Review Date: 16APR98
Label Date: 15APR98
MFR Label Number:
Label Status: M
Common Name: O-PHOSPHORIC ACID 85%
Chronic Hazard: YES
Signal Word: DANGER!
Acute Health Hazard-None:
Acute Health Hazard-Slight:
Acute Health Hazard-Moderate: X
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight:
Contact Hazard-Moderate:
Contact Hazard-Severe: X
Fire Hazard-None: X
Fire Hazard-Slight:
Fire Hazard-Moderate:
Fire Hazard-Severe:
Reactivity Hazard-None: X
Reactivity Hazard-Slight:
Reactivity Hazard-Moderate:
Reactivity Hazard-Severe:
Special Hazard Precautions: ACUTE:HARMFUL IF SWALLOWED, INHALED OR
ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF
Report for NIIN: 00N085038
MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN. INHALATION MAY
BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND EDEMA OF THE LARYNX AND
BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. TARGET ORGAN DATA:
BEHAVIORAL (SOMNOLENCE); KIDNEY, URETER, BLADDER (HEMATURIA); SKIN AND
APPENDAGES (HAIR). CHRONIC:NONE LISTED BY MANUFACTURER.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: SIGMA CHEMICAL CO
Label Street:
Label P.O. Box: 14508
Label City: ST LOUIS
Label State: MO
Label Zip Code: 63178
Label Country: US
Label Emergency Number: 314-771-5765
Year Procured:
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