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MATERIAL SAFETY DATA SHEET
Duoprime庐 90
Section 01 - Chemical And Product And Company Information
Product Identifier 鈥︹?︹?︹?︹?︹?︹?︹??.... CITGO Duoprime庐 Oil 90
Product Use 鈥︹?︹?︹?︹?︹?︹?︹?︹?︹??...... Lubricant
Supplier Name鈥︹?︹?︹?︹?︹?︹?︹?︹??.鈥?.. ClearTech Industries Inc.
2302 Hanselman Avenue
Saskatoon, SK. Canada
S7L 5Z3
Prepared By................鈥︹?︹?︹?︹??..鈥?... ClearTech Industries Inc. Technical Department
Phone: (306)664-2522
Preparation Date.........鈥︹?︹?︹?︹??.鈥?... February 22, 2008
24-Hour Emergency Phone鈥︹?︹?︹??... 306-664-2522
Section 02 - Composition / Information on Ingredients
Hazardous Ingredients....鈥︹?︹?︹??..... White Mineral Oil 100%
Vitamin E (d-alpha tocopherol) < 0.1%
CAS Number...................鈥︹??.鈥︹??......White Mineral Oil 8042-47-5
Vitamin E (d-alpha tocopherol) 59-02-9
Synonym (s)...................鈥︹?︹?︹?︹??....White mineral oil
Section 03 - Hazard Identification
Inhalation...................鈥︹?︹?︹??.鈥?..... No significant adverse health effects are expected to occur upon short-term
exposure.
Skin Contact / Absorption鈥︹??.鈥?.... No significant irritation is expected to occur upon short-term exposure.
Eye Contact................鈥︹?︹?︹??.鈥?..... Mild eye irritation may result from contact with liquid, mist and/or vapor.
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Ingestion.....................鈥︹?︹?︹?︹?︹??.. No significant effects are expected if swallowed. Ingestion of product can
cause a laxative effect. Liquid entering into lungs can cause severe
damage.
Exposure Limits鈥︹?︹?︹?︹?︹?︹?︹??... ACGIH/TWA: 5mg/m3 (oil mist, mineral)
ACGIH/STEL: 10mg/m3 (oil mist, mineral)
OSHA/TWA: 5mg/m3 (oil mist, mineral)
Section 04 - First Aid Measures
Inhalation....................鈥︹?︹?︹?︹?︹??... Material not expected to cause any inhalation type disorders. In case of
overexposure, remove victim to fresh air.
Skin Contact / Absorption鈥︹?︹?︹??... Remove contaminated clothing. Wash affected area with soap and water.
Seek medical attention if irritation occurs or persists. Seek immediate
medical attention if material is injected under the skin, into muscle or
bloodstream.
Eye Contact..................鈥︹?︹?︹?︹??..... Flush immediately with water for at least 20 minutes. Forcibly hold eyelids
apart to ensure complete irrigation of eye tissue. Seek immediate medical
attention.
Ingestion......................鈥︹?︹?︹?︹?︹??.. Do not induce vomiting or give anything by mouth. If vomiting doesoccur,
place head below knees. Place victim on left sode with head down if
drowsy or unconscious. Seek immediate medical attention.
Additional Information.....鈥︹?︹?︹??.... This material does present a significant aspiration hazard. Aspiration may
produce chemical pneumonitis. Treatment may involve careful gastric
lavage if performed soon after ingestion or in patients who are comatose
or at risk of convulsing. Protect airway by placement in Trendelenburg and
left lateral decubitus position or by cuffed endotracheal intubation.
Intramuscular or subcutaneous injection requires prompt surgical
debridement.
Section 05 - Fire Fighting
Conditions of Flammability鈥︹?︹??..... Slightly combustible material (NFPA Class IIIB material).
Means of Extinction........鈥︹?︹?︹??...... Use foam, dry chemical, water fog or carbon dioxide.
Flash Point....鈥︹?︹?︹?︹?︹?︹?︹?︹?︹??... 177oC (open cup)
Auto-ignition Temperature鈥︹?︹?︹??.. 400oC
Upper Flammable Limit 鈥︹?︹?︹?︹??... Not available
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Lower Flammable Limit...鈥︹?︹??.鈥?.... Not available
Hazardous Combustible Products.... Carbon dioxide, carbon monoxide, fumes, smoke, unburned
hydrocarbons.
Special Fire Fighting Procedures...... Wear NIOSH-approved self-contained breathing apparatus and protective
clothing. This material can burn but will not readily ignite. Mists or sprays
may burn at temperatures below the flashpoint.
Explosion Hazards鈥︹?︹?︹?︹?︹?︹??..... Heated vapor can ignite with explosive force in enclosed spaces.
Section 06 - Accidental Release Measures
Leak / Spill................鈥?.鈥︹?︹?︹?︹??... Wear appropriate personal protective equipment if required. Ventilate area.
Stop or reduce leak if safe to do so. Prevent material from entering sewers
and waterways. Flush with water to remove any residue. For small spills,
absorb or cover material with dry earth, sand or other inert non-
combustible absorbent material and place into waste containers for
disposal. Large spills are to be contained for recovery or disposal. This
material will float on water.
Deactivating Materials...鈥︹?︹??.鈥?.... Not available
Section 07 - Handling and Storage
Handling Procedures.......鈥︹?︹?︹??.... Use proper equipment for lifting and transporting all containers. Use
sensible industrial hygiene and housekeeping practices. Wash thoroughly
after handling. Avoid all situations that could lead to harmful exposure. Do
not pressurize, cut, weld, braze solder, drill, grind or expose containers to
sparks, flames, heat or other potential ignition sources.
Storage Requirements......鈥︹??...鈥?... Keep container closed when product is not in use. Do not store at
temperatures above 48oC and with strong oxidizers. Keep away from
direct sunlight for long periods of time.
Section 08 - Personal Protection and Exposure Controls
Protective Equipment
Eyes.鈥︹?︹?︹?︹?︹?︹?︹?︹?︹??.鈥︹?︹??.... Chemical goggles, full-face shield, or a full-face respirator is to be worn at
all times when product is handled. Contact lenses should not be worn; they
may contribute to severe eye injury.
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Respiratory鈥︹?︹?︹?︹?︹?︹?︹?︹?︹??..... Respiratory protection is not anticipated under normal use conditions and
with adequate ventilation. If airborne concentrations above appropriate
workplace exposure levels are expected, a NIOSH-approved organic vapor
respirator with dust/mist prefilter should be used. Respirators should be
used in accordance with OSHA requirements (29 CFR 1910.134).
Gloves鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??...... Impervious gloves of chemically resistant material (neoprene, nitrile rubber
or PVC) should be worn at all times. Wash contaminated clothing and dry
thoroughly before reuse.
Clothing鈥︹?︹?︹?︹?︹?︹?︹?︹??..鈥︹??..... Body suits, aprons, and/or coveralls of chemical resistant material
(neoprene) should be worn at all times. Wash contaminated clothing and
dry thoroughly before reuse.
Footwear鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??...... Impervious boots of chemically resistant material should be worn at all
times.
Engineering Controls
Ventilation Requirements鈥︹?︹??....... Mechanical ventilation (dilution or local exhaust), process or personnel
enclosure and control of process conditions should be provided. Supply
sufficient replacement air to make up for air removed by exhaust systems.
Other鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??..... Keep an eye wash fountain and safety shower available and in close
proximity to work area.
Section 09 - Physical and Chemical Properties
Physical State.......鈥︹??....鈥︹?︹?︹??..... Liquid
Odor and Appearance鈥?..鈥︹?︹?︹??.... Odorless, colorless liquid
Odor Threshold....鈥︹?︹?︹?︹??............. Not applicable
Specific Gravity (Water=1)鈥︹?︹?︹??... 0.85
Vapor Pressure (mm Hg, 20oC)鈥?.鈥?.. < 0.1mm
Vapor Density (Air=1)..鈥︹?︹?︹?︹??..... > 1
Evaporation Rate........鈥︹??..鈥︹??.鈥?... Not available
Boiling Point...............鈥︹?︹?︹??.鈥?...... Not available
Freeze/Melting Point....鈥︹?︹?︹?︹??..... Not available
pH............................鈥︹?︹?︹?︹?︹??.鈥?... Not available
Water/Oil Distribution Coefficient..... Not available
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Bulk Density..............鈥︹?︹?︹?︹??.鈥?.... Not available
% Volatiles by Volume鈥︹?︹??..鈥︹??.... Not available
Solubility in Water...鈥︹?︹?︹?︹?︹??...... Insoluble in cold water
Molecular Formula......鈥︹?︹?︹??.鈥?..... Not available
Molecular Weight........鈥︹?︹?︹?︹??...... Not available
Section 10 - Stability and Reactivity
Stability.................鈥︹?︹?︹??....鈥︹?︹?︹?︹??.. Stable
Incompatibility..............鈥︹?︹?︹??..鈥︹?︹??.. Stong oxidizers
Hazardous Products of Decomposition... No other hazardous decomposition products were identified other
than ones listed in Section 5 of theis MSDS.
Polymerization...........鈥︹?︹?︹?︹??.鈥︹??.鈥?.. Not expected to occur
Section 11 - Toxicological Information
Irritancy.................鈥︹??..鈥︹?︹?︹??.鈥?.. Slightly irritating
Sensitization........鈥︹??.......鈥︹?︹?︹??.. Not available
Chronic/Acute Effects鈥︹??...鈥︹?︹??... Mineral oil mists from highly refined oils are reported to have low acute and
sub-acute toxicities in animals.
Synergistic Materials...鈥︹??....鈥︹??.... Not available
Animal Toxicity Data......鈥?..鈥︹?︹??... LD50(rat, oral)= >5000mg/kg
LD50(rabbit, dermal)= >2000mg/kg
Carcinogenicity......鈥︹??......鈥︹?︹??.... Long term studies of up to two years showed no carcinogenic effects have
been reported in any animal species tested.
Reproductive Toxicity..鈥?...鈥︹?︹??.... Not available
Teratogenicity..........鈥?.....鈥︹?︹?︹??.... Not available
Mutagenicity...........鈥︹??.....鈥︹?︹?︹??.. Lifetime mouse skin painting studies showed that white mineral oils are not
mutagenic.
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Section 12 - Ecological Information
Fish Toxicity..................鈥︹?︹?︹?︹??... Ecological effects have not been conducted on this product. If spilled
however, this product and any contaminated water or soil may be harmful
to human, animal and aquatic life. Coating action of petroleum products
can be harmful or fatal to aquatic life and waterfowl.
Biodegradability.............鈥︹?︹??.鈥?..... Not available
Environmental Effects鈥︹?︹?︹?︹?︹??.. An environmental analysis has not been conducted on this specific
product. Petroleum based oils will normally float on water. In stagnant or
slow flowing waterways, a layer of oil can cover a large surface are which
may result in limiting or eliminating natural atmospheric oxygen transport
into the water. Oxygen depletion in waterways may be enough to create
an anaerobic environment or cause a fish kill.
Section 13 - Disposal Consideration
Waste Disposal...........鈥?...鈥︹?︹?︹??... Dispose in accordance with all federal, provincial, and/or local regulations
including the Canadian Environmental Protection Act.
Section 14 - Transportation Information
TDG Classification
Class鈥︹?︹?︹?︹??..鈥︹?︹?︹?︹?︹??..鈥?..... Not regulated
Group...............鈥︹?︹?︹?︹??.......鈥︹??.... Not regulated
PIN Number.................鈥︹??..鈥︹?︹??.... Not regulated
Other鈥︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹?︹??...... Secure containers (full and/or empty) with suitable hold down devises
during shipment.
Section 15 - Regulatory Information
WHMIS Classification.......鈥︹?︹?︹??....Not a controlled product
NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE
HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS
CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.
NSF Certification.................................Product is registered as a H1 and 3H lubricant for use in and around food
processing areas under the jurisdiction of the USDA.
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Section 16 - Other Information
Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health
hazards and safety information contained herein as a guide and should take those precautions required in an
individual operation to instruct employees and develop work practice procedures for a safe work environment. The
information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of
handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages
incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and
regulations.
Attention: Receiver of the chemical goods / MSDS coordinator
As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution庐
initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward
the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will
send any available supplementary handling, health, and safety information to you at your request.
If you have any questions or concerns please call our customer service or technical service department.
ClearTech Industries Inc. - Locations
Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3
Phone: 306-664-2522
Fax: 306-665-6216
www.ClearTech.ca
Location Address Postal Code Phone Number Fax Number
Richmond, B.C. 12431 Horseshoe Way V7A 4X6 604-272-4000 604-272-4596
5516E - 40th St. S.E.
Calgary, AB. T2C 2A1 403-279-1096 403-236-0989
11750 - 180th Street
Edmonton, AB. T5S 1N7 780-452-6000 780-452-4600
Saskatoon, SK. 2302 Hanselman Avenue S7L 5Z3 306-933-0177 306-933-3282
Regina, SK. 555 Henderson Drive S42 5X2 306-721-7737 306-721-8611
Winnipeg, MB. 340 Saulteaux Crescent R3J 3T2 204-987-9777 204-987-9770
Mississauga, ON. 7480 Bath Road L4T 1L2 905-612-0566 905-612-0575
24 Hour Emergency Number - All Locations - 306-664-2522
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