MATERIAL SAFETY DATA SHEET
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SECTION 1 鈥? PRODUCT AND SUPPLIER IDENTIFICATION
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PRODUCT: CLOVER GREEN GELCOAT
MSDS PREPARATION DATE: January 30, 2006
SUPPLIER: FIBERLAY, Inc.
ADDRESS: 24 S. Idaho St.
Seattle, WA 98134-1119
TELEPHONE: (206) 782-0660
EMERGENCY TELEPHONE NUMBER: (800) 424-9300 (CHEMTREC)
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SECTION 2 鈥? INGREDIENTS
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Component % (w/w) CAS Number Exposure Limits
Unsaturated Polyester Resin 20-40 Proprietary None Established
Styrene Monomer 33-37 100-42-5 OSHA PEL/TWA: 50 PPM (8 Hr
TWA)
OSHA PEL/Ceiling: Acceptable Max.
Peak: 600 PPM (5 Min in any 3 Hrs)
OSHA PEL/STEL: Acceptable
Concentration: 200 PPM (15 Min
TWA)
ACGIH TLV/TWA: 20 PPM (85
Mg/Cu.M.)
ACGIH TLV/STEL: 40 PPM (170
Mg/Cu.M.)
LD50, Oral: 4.37 gm/Kg (Rat)
LD50, Dermal: >5 gm/Kg (Rabbit)
IARC - Group 2B (Possible)
Talc (Hydrous Magnesium 0-20 014807-96-6 ACGIH TLV/TWA: 2 Mg/Cu.M.
Silicate) Respirable Dust
OSHA PEL/TWA: 2 Mg/Cu.M.
Respirable Dust
LD50, Oral: NOT AVAILABLE
LD50, Dermal: NOT AVAILABLE
LC50, Inhalation: NOT AVAILABLE
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Component % (w/w) CAS Number Exposure Limits
Calcium Carbonate 0-20 1317-65-3 OSHA PEL/TWA: 5.000 Mg/Cu.M.
Respirable Dust
OSHA PEL/TWA: 15.000 Mg/Cu.M.
Total Dust
OSHA VPEL/TWA: 5.000 Mg/Cu.M.
Respirable Dust
OSHA VPEL/TWA: 15.000 Mg/Cu.M.
Total Dust
ACGIH TLV/TWA: 10.000 Mg/Cu.M.
Quartz 0-1 14808-60-7 OSHA PEL/TWA: 10.000 Mg/Cu.M.
Respirable Dust
OSHA PEL/TWA: 30.000 Mg/Cu.M.
Total Dust
OSHA VPEL/TWA: 0.100 Mg/Cu.M.
Respirable Dust
ACGIH TLV/TWA: 0.050 Mg/Cu.M
Crystalline Free Silica 0-20 112945-52-5 None Established
Precipitated Silica Gel 鈥? 0-20 112926-00-8 OSHA PEL/TWA: 0.000 Mg/Cu.M.
Crystalline Free OSHA VPEL/TWA: 6.000 Mg/Cu.M.
ACGIH TLV/TWA: 10.000 Mg/Cu.M.
Methyl Methacrylate 4 80-62-6 ACGIH TLV/TWA: 100 PPM (410
Mg/Cu.M.)
OSHA PEL/TWA: 100 PPM (410
Mg/Cu.M.)
LD50, Oral: 7.9 gm/Kg (Rat)
LD50, Dermal: 35.5 gm/Kg (Rabbit)
LC50, Inhalation: >12,500 PPM/0.5 Hr
(Rat)
Red Iron Oxide Pigment 0 001332-37-2 OSHA PEL/TWA: 10 Mg/Cu. M.
ACGIH TLV/TWA: 5 Mg/Cu.M.
C.I. Pigment Yellow 42 (Iron 0 051274-00-1 OSHA PEL/TWA: 10 Mg/Cu. M.
Oxide) ACGIH TLV/TWA: 5 Mg/Cu.M.
Light Chrome Yellow Pigment 0-1 001344-37-2 OSHA PEL/TWA: 0.05 Mg/Cu.M. (Pb)
(C.I. Pigment Yellow 34 鈥? ACGIH TLV/TWA: 0.012 Mg/Cu.M.
Lead sulfochromate) (Cr)
Medium Chrome Yellow 0 001344-37-2 OSHA PEL/TWA: 0.05 Mg/Cu.M.( Pb)
Pigment (C.I. Pigment Yellow ACGIH TLV/TWA: 0.012 Mg/Cu.M.
34 鈥? Lead sulfochromate) (Cr)
Quinacridone Red Pigment 0 980-26-7 OSHA PEL/TWA: None Established
(C.I. Pigment Red 122) ACGIH TLV/TWA: None Established
Quinacridone Violet Pigment 0 1047-16-1 OSHA PEL/TWA: None Established
(C.I. Pigment Violet 19) ACGIH TLV/TWA: None Established
Moly Orange Pigment (C.I. 0 012656-85-8 OSHA PEL/TWA: 0.05 Mg/Cu.M.( Pb)
Pigment Red 104 鈥? Lead ACGIH TLV/TWA: 0.012 Mg/Cu.M.
molybdates/Lead (Cr)
chromate/Lead sulfate co-
precipitates)
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Phthalo Blue Pigment GS 0 00147-14-8 OSHA PEL/TWA: 1 Mg/Cu.M. (Cu)
(C.I. Pigment Blue 15) ACGIH TLV/TWA: 1 Mg/Cu.M. (Cu)
Phthalo Blue Pigment RS 0 00147-14-8 OSHA PEL/TWA: 1 Mg/Cu.M. (Cu)
(C.I. Pigment Blue 15) ACGIH TLV/TWA: 1 Mg/Cu.M. (Cu)
Phthalo Green Pigment RS 0-3 1328-53-6 OSHA PEL/TWA: 1 Mg/Cu.M. (Cu)
(C.I. Pigment Green 7) ACGIH TLV/TWA: 1 Mg/Cu.M. (Cu)
Carbon Black 0 001333-86-4 OSHA PEL/TWA: 3.5 Mg/Cu. M.
Titanium Dioxide 0-12 013463-67-7 ACGIH TLV/TWA: 10 Mg/Cu.M.
(Total Dust)
OSHA PEL/TWA: 15 Mg/Cu.M. (Total
Dust)
LD50, Oral: >7500 Mg/Kg (Rat)
LD50, Dermal: NOT AVAILABLE
LC50, Inhalation: NOT AVAILABLE
Aluminum Oxide 0-1 OSHA PEL/TWA: 15.000 Mg/Cu.M.
ACGIH TLV/TWA: 10.000 Mg/Cu.M.
Cobalt Compounds 0.1- 0.5 N/A None Established
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SECTION 3 - HAZARDS IDENTIFICATION
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EFFECTS OF EXCESSIVE OVEREXPOSURE. PRIMARY ROUTES OF ENTRY ARE:
EYE: CONTACT:
Irritation. Symptoms may include stinging, tearing, redness and discomfort.
SKIN CONTACT:
Irritation. Prolonged or repeated exposure may dry the skin. Symptoms may include redness,
burning, drying and cracking, skin burns and skin damage. Skin absorption is possible but
harmful effects are not expected from this route of exposure under normal conditions of
handling and use. Prolonged or repeated exposure to methyl methacrylate can cause skin
sensitization.
INHALATION:
Irritation to nose and throat. Extended or repeated exposure to concentrations above the
recommended exposure limits may cause brain or nervous system depression, with symptoms
such as dizziness, headache or nausea and if continued indefinitely, loss of consciousness,
liver and kidney damage. Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage.
INGESTION:
Single dose oral toxicity is low. Swallowing small amounts during normal handling is not
likely to cause harmful effects; swallowing large amounts may be harmful. This material can
enter the lungs during swallowing or vomiting and cause lung inflammation and/or damage.
May cause mouth, throat, esophagus and stomach irritation, nausea, vomiting and diarrhea.
GENERAL:
Lead and Lead compounds are cumulative poisons; blood levels can increase with repeated
exposure causing blood, kidney, liver, reproductive, developmental and nervous system
effects. Symptoms may include abdominal discomfort or pain, nausea, diarrhea, loss of
appetite, dizziness, lassitude, lack of coordination and insomnia.
Lead chromate is listed as a suspect human carcinogen by IARC (Group 2B). However,
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recent toxicity data indicate that Lead chromate pigments are non-carcinogenic or at least
show extremely low carcinogenic potential based on lung implantation studies on rats.
Furthermore, Lead chromate pigments do not show an increase in lung cancer rates according
to epidemiological studies of workers in factories that produce only Lead chromate pigments.
CHRONIC EFFECTS:
Repeated or prolonged exposure to styrene may cause nausea, loss of appetite, CNS
depression and general weakness.
MEDICAL CONDITIONS THAT MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT:
Preexisting eye, skin, liver, kidney and respiratory disorders.
TARGET ORGANS:
Overexposure to styrene has been suggested as a cause of the following effects in laboratory
animals, and may aggravate pre-existing disorders of these organs in humans: mild,
reversible kidney effects, effects on hearing, respiratory tract damage, testis damage, central
nervous system effects, mild effects on color vision or liver damage.
OTHER HEALTH HAZARDS: STYRENE MONOMER
The International Agency for Research on Cancer (IARC) has reclassified styrene as Group
2B "possibly carcinogenic to humans". This new classification is not based on new health
data relating to either humans or animals, but on a change in the IARC classification system.
The Styrene Information and Research Center does not agree with the reclassification and has
published the following statement. "Recently published studies tracing 50,000 workers
exposed to high occupational levels of styrene over a period of 45 years showed no
association between styrene and cancer, no increase in cancer among styrene
workers (as opposed to the average among all workers), and no increase in mortality related to
styrene." An increased incidence of lung tumors was observed in mice from a recent
inhalation study. The relevance of this finding is uncertain. Data from other long-term
animal studies and from epidemiology studies of workers exposed to styrene do not provide a
basis to conclude that styrene is carcinogenic. Lung effects have been observed in the mouse
following repeated exposure to styrene.
OTHER HEALTH HAZARDS: METHYL METHACRYLATE
Skin exposure to methyl methacrylate may cause irritation and/or a rash; it is also a potential
skin sensitizer. Prolonged or repeated overexposure at near lethal concentrations can
cause liver and kidney damage.
OTHER HEALTH HAZARDS: TALC
Talc, Hydrous Magnesium Silicate, contains crystalline silica at levels greater than 0.1% but
less than 1.0%. "IARC Monographs on the Evaluation of Carcinogenic Risks to Humans,
Supplement 7, 1987", concludes evidence for the carcinogenicity of crystalline silica to
humans, Class 2A. This classification was based on exposure to free silica dust and is not
expected to be relevant to trace amounts of crystalline silica dispersed in paints and plastics.
OTHER HEALTH HAZARDS: COBALT COMPOUNDS
The International Agency for Research on Cancer (IARC) has classified cobalt and cobalt
compounds as Group 2B carcinogens. Group 2B carcinogens are possibly carcinogenic to
humans. See IARC Monograph, Volume 52 for additional information.
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SECTION 4 鈥? FIRST AID MEASURES
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EYE CONTACT:
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush
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eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical
attention.
SKIN CONTACT:
Remove contaminated clothing. Flush exposed area with large amounts of water and then wash
thoroughly with soap and water. If skin is damaged, seek immediate medical attention. If skin is not
damaged and symptoms persist, seek medical attention. Launder clothing before reuse.
INHALATION:
If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist,
seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet;
seek immediate medical attention.
INGESTION:
Do not induce vomiting. This material is an aspiration hazard. If individual is drowsy or
unconscious, place on left side with the head down. Seek medical attention. If possible, do not leave
individual unattended.
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SECTION 5 鈥? FIRE AND EXPLOSION HAZARD DATA
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FLAMMABILITY CHARACTERISTICS:
Lowest Closed Cup Flashpoint: 82.0 degrees F
For Flash Points 73 to 100 deg. F.
OSHA Flammability Classification: Class IC
DOT Flammability Classification: Flammable Liquid
Lower Flammable Limit in Air: 1.1 % by volume
Upper Flammable Limit in Air: 12.5 % by volume
EXTINGUISHING MEDIA:
Use Foam, carbon dioxide, dry chemical. Use water spray/water fog for cooling.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
If polymerization takes place in a container, there is possibility of violent rupture of the container.
Vapors are uninhibited and may form polymers in vents or flame arrestors of storage tanks resulting
in stoppage of vents. Vapors may cause flash fire. Keep containers tightly closed and isolate from
heat, electrical equipment, sparks and flame. Never use welding or cutting torch on or near drum
(even empty) because product (even just residue) can ignite explosively.
SPECIAL FIRE FIGHTING PROCEDURES:
Full protective equipment including self-contained breathing apparatus should be used. Do not enter
fire area without proper protection. Fight fire from a safe distance/protected location.
Heat/impurities may increase temperature, build pressure and rupture closed containers spreading
fire, increasing risk of burns and injuries. Water spray may be ineffective due to low solubility.
Pressure relief system may plug with solids, increasing the risk of overpressure. If water is used, fog
nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and
possible auto-ignition or explosion when exposed to extreme heat. Notify authorities immediately if
liquid enters sewer or public waters.
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SECTION 6 鈥? ACCIDENTAL RELEASE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Eliminate all ignition sources such as flares, flames (including pilot lights), hot surfaces and any
electrical sparks. Avoid breathing vapors. Ventilate area. Stop spill at source. Prevent from
entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs,
notify authorities as required. Pump, vacuum or scoop spilled product into clean containers for
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disposal. Use non-sparking tools. Sand, floor absorbent or other inert absorbent may be used to
absorb material and aid in preventing the spread of the material. In case of a large spill, persons not
wearing protective equipment should be excluded from the area until cleanup has been completed.
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SECTION 7 鈥? HANDLING AND STORAGE
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PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Do not store above 100 deg. F. Store large quantities in buildings designed to comply with OSHA
1910.106. Keep away from heat, sparks and flame. Store containers closed and upright to prevent
leaks.
OTHER PRECAUTIONS:
Containers should be grounded and/or bonded when pouring. Emptied containers may retain
hazardous residue and explosive vapors. Keep away from heat, sparks and flames and direct
sunlight. Do not cut, puncture or weld on or near emptied containers. Follow all hazard precautions
given in this data sheet until container is thoroughly cleaned or destroyed. If this product is blended
with other components such as thinners, converter, colorants and catalysts prior to use, read all
warning labels. Any mixture of components will have hazards of all components. Follow all
precautions. If spraying this material, keep spray booths clean. Avoid buildup of spray dust or
overspray in booths or ducts. Do not take internally. Wash hands after using material and before
smoking or eating.
KEEP OUT OF REACH OF CHILDREN - FOR INDUSTRIAL USE ONLY!
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SECTION 8 鈥? EXPOSURE CONTROLS, PERSONAL PROTECTION
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RESPIRATORY PROTECTION:
Do not breathe or ingest vapors, spray mist or dust while applying, sanding, grinding, or sawing
cured product. Wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during
application and other use of this product until vapors, mists and dusts are exhausted, unless air
monitoring demonstrates vapor, mist and dust levels are below applicable limits. Half-face, air
purifying, organic vapor cartridge respirator can be used up to 400 PPM exposure. A full-face, air
purifying, organic vapor cartridge respirator can be used up to 1000 PPM for short-term periods
depending on respirator cartridge use efficiency. Higher concentrations would require full-face,
positive pressure, supplied air or self-contained breathing apparatus. Follow respirator
manufacturer鈥檚 directions for respirator use. Observe OSHA Standard 29 CFR 1910.134.
VENTILATION:
Provide general clean air dilution or local exhaust ventilation in volume and pattern to keep the air
contaminant concentration below the lower explosion limit and below current applicable exposure
limits in the mixing, application and curing areas; and to remove decomposition product during
welding and flame cutting on surfaces coated with this product. In confined areas, use only with
forced ventilation adequate to keep vapor concentration below 20% of lower explosion limits. Refer
to OSHA Standards 29 CFR 1910.94, 1910.107, 1910.108.
NOTE: Heavy solvent vapors should be removed from lower levels of the work area and all ignition sources
(non-explosion-proof motors, etc.) should be eliminated.
PROTECTIVE GLOVES:
Use solvent impermeable gloves such as polyethylene, natural rubber, neoprene, buna-N or nitrile to
avoid contact with product.
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EYE PROTECTION:
Do not get in eyes. Use safety eyewear with splash guards or side shields, chemical goggles or face
shields that meet OSHA regulations.
OTHER PROTECTIVE EQUIPMENT:
Avoid contact with skin. Use protective clothing. Prevent contact with contaminated clothing.
Wash contaminated clothing, including shoes, before reuse.
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SECTION 9 鈥? PHYSICAL AND CHEMICAL PROPERTIES
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Low = 214.0 掳F High = 295.0 掳F
Boiling Range:
Freezing Point: N/A
29.000 mm/Hg @ 68 掳F
Vapor Pressure:
Vapor Density: 3.60
Specific Gravity: 1.22-1.29 (10.2 to 10.8 LB/GL 鈥? Calculated)
Evaporation Rate: 3.000 (n-Butyl Acetate = 1)
%Volatile by Weight: 33-37
%Volatile by Volume: 48-55
Physical State: LIQUID
Appearance: GREEN
Odor: MODERATE AROMATIC
pH: N/A
Water Solubility: INSOLUBLE
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SECTION 10 鈥? STABILITY AND REACTIVITY
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STABILITY:
This product is stable under normal conditions
HAZARDOUS POLYMERIZATION:
Is not expected but may occur.
CONDITIONS TO AVOID:
Elevated temperatures, heat, sparks, open flame and other ignition sources. Improper addition of
promoter and/or catalyst. Avoid direct contact of MEKP catalyst with accelerator. If an accelerator
such as cobalt drier is to be added, mix this accelerator with base material before adding catalyst.
INCOMPATABILITY (MATERIALS TO AVOID):
Oxidizers, peroxides, strong acids, other oxidizing agents, organic metal soaps, aluminum chloride
and vinyl polymers.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion can produce fumes containing organic acids, carbon dioxide,
carbon monoxide, other toxic gases and acrid smoke.
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SECTION 11 鈥? TOXICOLOGICAL INFORMATION
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GELCOAT PRODUCT TOXICOLOGICAL INFORMATION:
EYE EFFECTS:
No Data
SKIN EFFECTS:
No Data
INHALATION EFFECTS:
No Data
Page 7 of 9
ORAL (INGESTION) EFFECTS:
No Data
INDIVIDUAL INGREDIENT TOXICOLOGICAL INFORMATION: SEE SECTION 2
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SECTION 12 鈥? ECOLOGICAL INFORMATION
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ENVIRONMENTAL FATE:
Styrene and Methyl Methacrylate are classified as Hazardous Air Pollutants (HAP). Both react when
the product cures and only a portion is lost as Volatile Organic Compounds (VOC). The VOC
quantity listed in SECTION 9 is a total theoretical loss value. Under typical conditions, only half this
amount might be lost to the atmosphere. The loss will vary due to temperature, humidity, film
thickness, air movement, spray equipment, techniques, catalyzation, gel and cure rates, etc. If precise
values are needed, it is suggested that on-site testing be conducted.
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SECTION 13 鈥? DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL;
Whatever cannot be saved for recovery or re-use should be handled as hazardous waste in accordance
with 40 CFR Part 261.21(a)(1) and classified as a D001 Ignitable Waste. Processing, use or
contamination of this product may change the waste management options. State and local disposal
regulations may differ from federal disposal regulations. Dispose of in accordance with local, state
and federal regulations. Incinerate in an approved facility.
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SECTION 14 鈥? TRANSPORT INFORMATION
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DOT Shipping Name: Resin Solution
DOT Hazard Class: 3
DOT Identification Number UN1866
DOT Packaging Group: III
DOT Label Flammable Liquid
DOT Placard: UN1866 Placard is required if container volume
exceeds 119 gallons.
RQ 鈥? Styrene 1000 LBS
RQ 鈥? Methyl Methacrylate 1000 LBS
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SECTION 15 鈥? REGULATORY INFORMATION
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FEDERAL REGULATIONS:
TSCA (Toxic Substances Control Act) 鈥? United States 鈥? The intentional ingredients of this product
are listed.
CLEAN AIR ACT SECTION 112:
This product contains the following components listed as Hazardous Air Pollutants:
LEAD COMPOUNDS CAS# N/A Percent by Weight: 3.000
CHROMIUM COMPOUNDS CAS# N/A Percent by Weight: 3.000
METHYL METHACRYLATE CAS# 000080-62-6 Percent by Weight: 4.0000
STYRENE MONOMER CAS# 000100-42-5 Percent by Weight: 33-37
SARA TITLE III:
SARA 302 Components 鈥? 40 CFR 355 Appendix A - None
SARA 311/312 Hazard Class 鈥? 40 CFR 370.2
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Immediate (X) Delayed (X) Fire (X) Reactive (X)
Sudden Release of Pressure ( )
SARA 313 INFORMATION:
This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part
372:
METHYL METHACRYLATE CAS# 000080-62-6 Percent by Weight: 4.0000
STYRENE MONOMER CAS# 000100-42-5 Percent by Weight: 33-37
COPPER COMPOUNDS CAS# N/A Percent by Weight: 3.000
LEAD COMPOUNDS CAS# N/A Percent by Weight: 1.000
CHROMIUM COMPOUNDS CAS# N/A Percent by Weight: 1.000
CERCLA RQ 鈥? 40 CFR 302.4(a)
Styrene 1000 LBS
Methyl Methacrylate 1000 LBS
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 INFORMATION:
WARNING - This product contains a chemical(s) known to the State of California to cause cancer
and/or birth defects.
Styrene may contain up to 2 PPM of benzene as a contaminant. Styrene can react in the presence of
air to form styrene oxide. Benzene and styrene oxide are chemicals known to the state of California
to cause cancer and/or birth defects.
This product contains the following substances known to the State of California to cause cancer:
C.I. Pigment Yellow 34 (Lead sulfochromate)
This product contains the following substances known to the State of California to cause adverse
reproductive effects:
C.I. Pigment Yellow 34 (Lead sulfochromate)
CANADIAN WHMIS CLASSIFICATION: B2/D1A/F
HAP CONTENT:
The HAP content and VOC content of this product are not necessarily the same. The HAP content
can be determined by adding together any styrene, methyl methacrylate, Lead and Chromium
compounds (listed in this section under Clean Air Act Section 112). The result is the HAP content in
weight percent.
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SECTION 16 鈥? OTHER INFORMATION
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NFPA RATINGS:
Health: 2 Flammability: 3 Reactivity: 1
NPCA HMIS INFORMATION:
Health: 2 Flammability: 3 Reactivity: 1 Personal Protective Equipment: I
PREPARATION DATE: January 30, 2006
PREPARED BY: David L. Ellsworth
REVISIONS: None
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The information contained herein is information received from our raw material suppliers and other sources
and is believed to be reliable and accurate. This data or information is not to be taken as a warranty for
which FIBERLAY, INC. assumes legal responsibility.
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