PAGE 1 of 4 Duraglas
U S Chemical & Plastics, Inc For Chemical Emergency
Alco Industries Companies
600 Nova Drive SE CHEMTREC: 1-800-424-9300
Massillon, OH 44646 CANUTEC: 1-613-996-6666
PH 330-830-6000 - FAX 330-830-6005 (For Canada call collect)
===============================================================================
SECTION I - IDENTIFICATION OF PRODUCT
===============================================================================
PRODUCT NAME: DURAGLAS
PRODUCT CODE: (24059), 24030, 24035, 24036
SYNONYM/CROSS REFERENCE: Polyester Paste Filler
SCHEDULE B NUMBER: 3214.10.0000-4
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SECTION II - HAZARDOUS INGREDIENTS
=====================================================================
INGREDIENTS WGT% CAS # TLV/PEL
Styrene 15-20% 100-42-5 ACGIH TLV 50 ppm
STEL 100 ppm
OSHA PEL 100 ppm
CPEL 200 ppm
(See Health Hazard Info)
ACGIH TWA 2 mg/m3
Non-Fibrous Talc 40-50% 14807-96-6
OSHA TLV 20 mppcf
OSHA PEL 15 mg/m3
Castor Oil Derivative 1-5 % 8001-78-3
ACGIH PEL 15 mg/m3
Fiberglass (Milled) 0-5 % 65997-17-3
ACGIH PEL 15 mg/m3
Calcium Metasilicate 5-15% 13983-17-0
ACGIH TWA 10 mg/m3
Calcium Carbonate 5-15% 1317-65-3
471-34-1
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SECTION III - PHYSICAL DATA
=====================================================================
APPEARANCE: Green Paste, fibrous texture
SPECIFIC GRAVITY: 1.65
VAPOR PRESSURE (mmHG): N/Av
BOILING POINT: N/Av
VAPOR DENSITY: Heavier than air
EVAPORATION RATE (Ethyl Ether = 1): Slower than Ethyl Ether
VOLATILES BY WEIGHT: 13-20%
SOLUBILITY IN WATER: Not Soluble
VOC: Grams/Litre = less exempts 242
loss upon curing approx 2.0 g/l
Page 1 of 4 Tubed Cream Hardener
CATALYST SYSTEMS
U S Chemical & Plastics , Inc
Alco Industries Companies
PO Box 88 CHEMTREC: 1-800-424-9300
2290 Zimmerman Rd SE CANUTEC: 1-613-996-6666
Gnadenhutten, OH 44629 (For Canada call collect)
PH: 740-254-4311
==================================================================
SECTION I - IDENTIFICATION OF PRODUCT
=======================================================
PRODUCT NAME: CREAM HARDENER (TUBED)
PRODUCT CODE: 27640/White, 27641/Red, 27642/Green, 27643/Blue,
27645/Raspberry, 28050/Black
additional product codes on page 4
SYNONYM/CROSS REFERENCE: Polyester Cream Hardener/Polyester Catalyst,
Benzoyl Peroxide Paste
SCHEDULE B NUMBER: 3815.90.0000-0
==================================================================
SECTION II - HAZARDOUS INGREDIENTS
=======================================================
INGREDIENTS WGT% CAS # TLV/PEL
Benzoyl Peroxide 47.5-50.0 94-36-0 Combustible when dry:
TLV 5 mg/m3 *
* Refer to 29 CFR 1910.1000, subpart Z.
Also see TLV for Chemical Substances and Physical Agents in the Work Environment (ACGIH)
==================================================================
SECTION III - PHYSICAL DATA
=======================================================
APPEARANCE: Red, White, Blue, Green or Raspberry Paste
SPECIFIC GRAVITY: 1.20
VAPOR PRESSURE (mmHG): N/E
BOILING POINT: Decomposes
VAPOR DENSITY: (Air = 1) >
EVAPORATION RATE (Ethyl Ether = 1): <1
VOLATILES BY WEIGHT: 10-20%
SOLUBILITY IN WATER: Insoluble
VOC: Grams/Litre = Nil
Lbs/Gallon = Nil
===========================================================
SECTION IV - FIRE AND EXPLOSION DATA
===========================================================
FLASH POINT: 184 F/ 84 C Seta Flash Closed cup
LOWER FLAMMABLE LIMIT %: N/E
UPPER FLAMMABLE LIMIT %: N/E
FIRE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers with water
spray. Firefighter should wear OSHA/NIOSH approved self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARD: Closed containers exposed to high temperatures, such as fire
conditions may rupture.
Page 2 of 4 Tubed Cream Hardener
==================================================================
SECTION V - HEALTH HAZARD/TOXICOLOGICAL PROPERTIES
==================================================================
OVEREXPOSURE EFFECTS:
ACUTE EFFECTS:
EYES: Contact with eyes can cause irritation, redness, tearing, blurred vision, and/or swelling.
SKIN: Contact with skin can cause irritation, (minor itching, burning and/or redness), Dermatitis,
defatting may be readily absorbed thru the skin.
INHALATION: Inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness,
fatigue, nausea, headache, possible unconsciousness and/or asphyxiation. Aspiration of material
into lungs may result in chemical pneumonitis which can be fatal.
INGESTION: Ingestion can cause gastrointestinal irritation, nausea, vomiting, diarrhea.
CHRONIC EFFECTS:
Overexposure to this material has apparently been known to cause the following effects in lab
animals: skin damage and appendages.
CARCINOGEN: YES _____ NO __X__
TERATOGEN: YES _____ NO ___X
MUTAGEN: YES _____ NO ___X_
Benzoyl Peroxide has caused tumorogenic effects in laboratory animals.
PRIMARY ROUTES OF EXPOSURE: skin, inhalation
FIRST AID:
INHALATION: If inhaled, remove victim from exposure to a well-ventilated area. Make them
comfortably warm, but not hot. Use oxygen or artificial respiration as required. Consult a physician.
SKIN: For skin contact, wash promptly with soap and excess water.
EYES: For eye contact, flush promptly with excess water for at least fifteen minutes. Consult a
physician.
INGESTION: If ingested, do not induce vomiting. Give victim a glass of water. Call a physician
immediately.
==================================================================
SECTION V I - REACTIVITY DATA
==================================================================
STABILITY: Stable
CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge.
INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalis, oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide and Carbon.
HAZARDOUS POLYMERIZATION: Will not occur.
==================================================================
SECTION VII - SPILL AND DISPOSAL PROCEDURE
==================================================================
SPILLS, LEAK OR RELEASE: Ventilate area. Remove all possible sources of ignition. Avoid prolonged
breathing of vapor. Contain spill with inert absorbent.
WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations.
Page 3 of 4 Tubed Cream Hardener
==================================================================
SECTION VIII - PROTECTION INFORMATION
==================================================================
RESPIRATORY PROTECTION: If component TLV limits are exceeded, use NIOSH/MSHA approved
respirator to remove vapors. Use an air-supplied respirator if necessary.
VENTILATION: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended
levels. Explosion-proof ventilation may be necessary.
PROTECTIVE GLOVES: To prevent prolonged exposure use rubber gloves; solvents may be absorbed
through the skin
EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields.
OTHER PROTECTIVE EQUIPMENT: Wear protective clothing as required to prevent skin contact.
==================================================================
SECTION IX - HANDLING AND STORAGE PRECAUTIONS
==================================================================
STORAGE AND HANDLING: Use with adequate ventilation. Avoid contact with eyes and skin. Avoid
breathing vapors. Do not store the product above 100F/38C. Do not flame, cut, braze weld or melt empty
containers. Keep the product away from heat, open flame, and other sources of ignition. Avoid contact with
strong acids, alkalis and oxidizers.
==================================================================
SECTION X - ADDITIONAL INFORMATION
==================================================================
SHIPPING INFORMATION: Please comply with DOT regulations in USA
HMIS RATING: Health 2 4 = Extreme
Fire 2 3 = High
Reactivity 2 2 = Moderate
1 = Slight
0 = Insignificant
Personal Protection - See Section VIII
CALIFORNIA PROPOSITION 65:
Trace amounts of some chemicals known to the State of California to cause cancer, birth
defects or other reproductive harm may be present in this product.
SECTION 313 SUPPLIER NOTIFICATION:
This product contains the following toxic chemicals subject to the reporting requirements of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR 372:
CHEMICAL NAME CAS % BY WGT
Benzoyl Peroxide 94-36-0 47.5-50.0%
THIS INFORMATION MUST BE INCLUDED IN ALL MSDS鈥檚 THAT ARE COPIED AND DISTRIBUTED FOR THIS CHEMICAL
Page 4 of 4 Tubed Cream Hardener
=======================================================================
ABBREVIATIONS
====================================================
IARC = International Agency for Research on Cancer
ACGIH = American Conference of Governmental Industrial Hygienists
NIOSH = National Institute of Occupational Safety and Health
TLV = Threshold Limit Value
PEL = Permissible Emission Level
DOT = Department of Transportation
NTP = National Toxicology Program
N/AV = Not Available
N/AP = Not Applicable
N/E = Not Established
N/D = Not Determined
NOTE: ADDITIONAL PART NUMBERS:
Bulk Red 27641
27007, 27020, 27170, 27010, 27110, 27020, 27120
Bulk Blue 27643
27012, 27022, 27112, 27160, 27122, 28159
Bulk White 27647
27014, 27114, 27024, 27124, 27080
Bulk Raspberry 27645
27029, 27030, 27032, 27034, 27196, 27633
Bulk Black 28050
27042
PREPARED BY: CATALYST SYSTEMS, INC
U S Chemical & Plastics, Inc
Alco Industries Companies
PO Box 88
2290 Zimmerman Rd SE
Gnadenhutten, OH 44629
TELEPHONE NBR 740-254-4311
FAX NBR 740-254-9400
PREPARED ON September 18, 2002
SUPERSEDES July 16, 2002
REASON FOR UPDATE Format
The information in the Material Safety Data Sheet has been compiled from our experience and from data
presented in various technical publications. It is the user鈥檚 responsibility to determine the suitability of
this information for the adoption of the safety precautions as may be necessary. We reserve the right to
revise Material Safety Data Sheets from time to time as new technical information becomes available.
The user has the responsibility to contact the Company to make sure that the MSDS is the latest one
issued.
PAGE 2 of 4 Duraglas
==============================================================================
SECTION IV - FIRE AND EXPLOSION DATA
=================================================================================
FLASH POINT: 89 F/ 31.7 C Seta Flash Closed cup
LOWER FLAMMABLE LIMIT %: N/E
UPPER FLAMMABLE LIMIT %: N/E
FIRE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers with water
spray. Firefighter should wear OSHA/NIOSH approved self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARD: Closed containers exposed to high temperatures, such as fire
conditions may rupture.
=================================================================================
SECTION V - HEALTH HAZARD/TOXICOLOGICAL PROPERTIES
=================================================================================
OVEREXPOSURE EFFECTS:
ACUTE EFFECTS:
EYES: Contact with eyes can cause irritation, redness, tearing, blurred vision, and/or swelling.
SKIN: Contact with skin can cause irritation, (minor itching, burning and/or redness), Dermatitis,
defatting may be readily absorbed thru the skin.
INHALATION: Inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness,
fatigue, nausea, headache, possible unconsciousness and/or asphyxiation. Aspiration of material into
lungs may result in chemical pneumonitis which can be fatal.
INGESTION: Ingestion can cause gastrointestinal irritation, nausea, vomiting, diarrhea.
CHRONIC EFFECTS:
Overexposure to this material has apparently been known to cause the following effects in lab animals:
eye, skin, lung, and central nervous system damage.
CARCINOGEN: YES _____ NO ___X_
TERATOGEN: YES _____ NO ___X_
MUTAGEN: YES _____ NO ___X_
STYRENE CARCINOGINICITY
Styrene is listed by IARC to be a possible carcinogen. Styrene studies have shown that Styrene causes cancer in
certain laboratory animals. However, there is insufficient evidence to conclude that Styrene is a human carcinogen.
PRIMARY ROUTES OF EXPOSURE: skin, inhalation, eyes
FIRST AID:
INHALATION: If inhaled, remove victim from exposure to a well-ventilated area. Make them
conformably warm, but not hot. Use oxygen or artificial respiration as required. Consult a physician.
SKIN: For skin contact, wash promptly with soap and excess water.
EYES: For eye contact, flush promptly with excess water for at least fifteen minutes. Consult a
physician.
INGESTION: If ingested, do not induce vomiting. Give victim a glass of water. Call a physician
immediately.
PAGE 3 of 4 Duraglas
=================================================================================
SECTION V I - REACTIVITY DATA
=================================================================================
STABILITY: Stable
CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge.
INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalis, oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide and Carbon.
HAZARDOUS POLYMERIZATION: Will not occur.
================================================================================
SECTION VII - SPILL AND DISPOSAL PROCEDURE
=================================================================================
SPILLS, LEAK OR RELEASE: Ventilate area. Remove all possible sources of ignition. Avoid prolonged
breathing of vapor. Contain spill with inert absorbent.
WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations.
MARINE POLLUTANT: Contains ten percent or more of a marine pollutant
================================================================================
SECTION VIII - PROTECTION INFORMATION
=================================================================================
RESPIRATORY PROTECTION: If component TLV limits are exceeded, use NIOSH/MSHA approved
respirator to remove vapors. Use an air-supplied respirator if necessary.
VENTILATION: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended levels.
Explosion-proof ventilation may be necessary.
PROTECTIVE GLOVES: To prevent prolonged exposure use rubber gloves; solvents may be absorbed through
the skin
EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields.
OTHER PROTECTIVE EQUIPMENT: Wear protective clothing as required to prevent skin contact.
=================================================================================
SECTION IX - HANDLING AND STORAGE PRECAUTIONS
=================================================================================
STORAGE AND HANDLING: Use with adequate ventilation. Avoid contact with eyes and skin. Avoid
breathing vapors. Do not store the product above 100F/38C. Do not flame, cut, braze weld or melt empty
containers. Keep the product away from heat, open flame, and other sources of ignition. Avoid contact with strong
acids, alkalis and oxidizers.
=================================================================================
SECTION X - ADDITIONAL INFORMATION
=================================================================================
SHIPPING INFORMATION: Please comply with DOT regulations in USA
HMIS RATING: Health 2 4 = Extreme
Fire 3 3 = High
Reactivity 1 2 = Moderate
1 = Slight
0 = Insignificant
Personal Protection - See Section VIII
=================================================================================
PAGE 4 of 4 Duraglas
CALIFORNIA PROPOSITION 65:
Trace amounts of some chemicals known to the State of California to cause cancer, birth defects
or other reproductive harm may be present in this product.
SECTION 313 SUPPLIER NOTIFICATION:
This product contains the following toxic chemicals subject to the reporting requirements of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR 372:
CHEMICAL NAME CAS % BY WGT
Styrene 100-42-5 15-20%
THIS INFORMATION MUST BE INCLUDED IN ALL MSDSs THAT ARE COPIED AND DISTRIBUTED FOR THIS CHEMICAL
=======================================================================================
ABBREVIATIONS
==================================================================
IARC = International Agency for Research on Cancer
ACGIH = American Conference of Governmental Industrial Hygienists
NIOSH = National Institute of Occupational Safety and Health
TLV = Threshold Limit Value
PEL = Permissible Emission Level
DOT = Department of Transportation
NTP = National Toxicology Program
N/AV = Not Available
N/AP = Not Applicable
N/E = Not Established
N/D = Not Determined
PREPARED BY: U S CHEMICAL & PLASTICS, INC
An Alco Industries Company
600 NOVA DRIVE SE
MASSILLON, OH 44646
TELEPHONE NBR 330-830-6000
FAX NBR 330-830-6005
PREPARED ON September 21, 2001
SUPERSEDES January 23, 2001
The information in the Material Safety Data Sheet has been compiled from our experience and from data
presented in various technical publications. It is the user鈥檚 responsibility to determine the suitability of this
information for the adoption of the safety precautions as may be necessary. We reserve the right to revise
Material Safety Data Sheets from time to time as new technical information becomes available. The user has
the responsibility to contact the Company to make sure that the MSDS is the latest one issued.
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