MATERIAL SAFETY DATA SHEET
47 VE PRIMER WHITE Page : 1
PRODUCT NAME: 47 VE PRIMER WHITE BMIS CODES: H F R P
PRODUCT CODE: 1794-005 23 2H
D.O.T. PROPER SHIPPING NAME: RESIN SOLUTION, 3, UN1866, PGII
SECTION I - MANUFACTURER IDENTIFICATION --------___------
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MANUFACTURER'S NAME: DURA TECHNOLOGIES, INC.
ADDRESS : 2720 SOUTH WILLOW AVE.
BLOOMINGTON, CA 92316
EMERGENCY PHONE : 800-424-9300 DATE PRINTED : 01/20/99
INFORMATION PHONE : 909-877-8477 NAME OF PREPARER : Richard Stewart
------____ SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION ---------
VAPOR PRESSURE WRIGHT
REPORTABLE COMPONENTS CAS NUMBER rmHg@TEMP PERCENT
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* STYRENE 4.5 7
100-42-5 70
OSHA TWA: 50 PPM ;ACGIH TWA 50 PPM
CERCLA RQ: 1000 LBS ;DOT RQ: 3336 LBS
78-93-3 70 68 5
METHYL ETHYL KETONE
l
OSHA PEL: 200 PPM, ;ACGIH TLV: 200 PPM
ORAL LD50 (RAT) = 2.7-5.6 g/kg ;DERMAL LD50 5-13 g/Kg (RABBIT)
DOT RQ: 5000 LBS
HEXANE 110-54-3 140 68
ACGIH TLV: 300
TOLUENE 42 77
108-88-3
ACGIH TLV: 100
ISOPROPYL ALCOHOL 67-63-O 33 77
OSHA & ACGIH TWA: 400 PPM ;OSHA & ACGIH STEL: 500 PPM
DIMETHYL BENZENE (XYLENE) 1330-20-7 5.1 68
: OSHA PEL 100 PPM
ACGIH TLV: lOOPPM,
* Indicates toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.
NOTE: A ZERO IN THE WEIGHT PERCENT COLUMN INDICATES THAT THERE IS LESS THAN ONE-HALF OF ONE PERCENT PRESENT.
WARNING ! THERE ARE CERTIAN HEALTH HAZARDS INVOLVED WITH HANDLING AND STORING THIS MATERIAL. PLEASE READ AND FOLLOW THE SAFTY
RECOMMENDATIONS PUT FORWARD ON THIS MSDS.
III - PHYSICAL/CHEMICAL CHARACTERISTICS ------------
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--------------- SECTION
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1.32
BOILING RANGE: 151 deg F - 295 deg F SPECIFIC GRAVITY (H20=1):
EVAPORATION RATE: SLOWER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
COATING VOC: 1.22 lb/g1
MATERIAL V.O.C.: 1.22 lb/g1
SOLUBILITY IN WATER: negligible
APPEARANCE AND ODOR: VINYL ESTER COATING WITH CHARACTERISTIC STYRENE ODOR
SECTION IV - FIRE AND EXPLOSION HAZARD DATA --------------
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METHOD USED: TCC
FLASH POINT: 20 DEG F
UPPER: 12.7
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1
EXTINGUISHING MEDIA: FOAM, C02, DRY CHEMICAL, WATER FOG
SPECIAL FIREFIGHTING PROCEDURES
Wear full protective equipment including SELF-CONTAINED BREATHING APPARATUS. If water is used, fog nozzles are preferable. Water may
Water spray may be ineffective. WARNING: Burning liquid
be used to cool containers to prevent pressure build-up or autoignition.
chemicals are usually lighter than water and will float spreading flames as the water flows from the site of the fire fighting
efforts. WARNING!: Stay away from hot drums due to explosion hazard.
UNUSUAL FIRE AND EXPLOSION HAZARDS
there is the possibility of violent rupture of
At high temperatures this material may self polymerize. If polymerization occurs,
sealed containers. Styrene vapors are uninhibited and may form polymers in the vents or flame arrestors of storage tanks rendering
them useless. These vents should be inspected frequently for blockage. Vapors may cause flash fires. Keep storage containers tightly
closed and isolated from heat, electrical equipment, sparks and flames.
MATERIAL SAFETY DATA SHEET
47 VE PRIMER WHITE Page: 2
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_______--_---___-____--_ REACTIVITY __----_-----_----------
SECTION V -
STABILITY: STABLE
CONDITIONS TO AVOID
AVOID HEAT, Sparks or open flames. Never allow the PROMOTER/ACCELERATOR to come in direct contact with the CATALYST (When mixed in
an undiluted form, cobalt and peroxide will react violently and cause an explosion). Do not use plastic or non-conducting containers
to store and handle flammable liquids. These containers can not be properly grounded and static charge may build up in the flammable
liquid.
INCOMPATIBILITY (MATERIALS TO AVOID)
Avoid contact with strong acids, oxidizers (bleaches), and strong bases (caustic soda).
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
If ignited this product will release carbon dioxide, carbon monoxide, and some organic acids. Do not breath fumes.
HAZARDOUS POLYMERIZATION: MAY OCCUR
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a--.7---------------- SECTION VI - HEALTH HAZARD DATA _____-____--____--____-
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
The excessive inhalation of vapors may cause nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, and headaches.
The symptoms of inhalation exposure are very simuliar to common complaints caused by colds and other minor medical problems and must
be monitored scrupulously to detect the appearance of overexposure.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
EYE CONTACT: This material can be irritating to the eyes. The symptoms of this are tearing, redness, and discomfort. SKIN CONTACT:
This material may cause severe skin irritation. Symptons include redness, burning drying and cracking.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Exposure by skin contact can cause severe skin irritation. Prolonged or repeated exposure may induce redness, burning, and cracking
of the skin. Skin absorption is possible but no adverse effects are expected from this route of exposure under normal conditions of
handling and use.
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Swallowing can cause gastrointestinal irritation, nausea, vomitting and diarrhea. Aspiration of the liquid material can cause
pneumonitis which can be FATAL. Care should be taken that such aspiration DOES NOT OCCUR SHOULD THE VICTIM VOMIT.
HE ALTH HAZARDS (ACUTE AND CHRONIC)
Reports have associated repeated or prolonged occupational exposure to solvents with permanent brain and nervous system damage,and
liver or kidney atrophy. Intentional misuse by concentrating and inhaling the vapors can be fatal. This material has not been tested
as a whole for health effects. WARNING! Although all intentional PROP 65 chemicals will be listed, THERE MAY BE DETECTABLE LEVELS OF
UNINTENTIONAL CHEMICALS WHICH ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE HARM PRESENT
IN THIS PRODUCT.
TARGET ORGAN INFORMATION:
Overexposure to this material has been suggested as a cause of the following effects in laboratory animals, and may aggravate pre-
existing disorders of these organs in humans: mild, reversible kidney effects, effects on hearing respiratory tract damage, testis
damage, and liver damage. Overexposure to this material has been suggested as a cause of the following effects in humans and may
respiratory tract damage.
aggravate pre-existing disorders of these organs: central nervous system effects, effects on hearing,
OSHA REGULATED: No
CARCINOGENICITY: NTP CARCINOGEN: No IARC MONOGRAPHS: No
PROPOSITION 65: WARNING: BENZENE IS AN IMPURITY IN THIS PRODUCT
STYRENE AT LEVELS LESS THAN ONE TENTH OF ONE PERCENT.
CONTAINS BENZENE WHICH IS A CHEMICAL KNOWN BY THE STATE OF CALIFORNIA TO CAUSE CANCER. WARNING: THIS PRODUCT CONTAINS TOLUBNE A
CHEMICAL KNOWN BY THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
WARNING! The International Agency for Research on Cnacer states that styrene is 'possibly carcinogenic to humans' (Group 2B) based on
'inadequate evidence' in humans, 'limited evidence' in animals, and other 'relevant data'.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Respiratory problems such as asthma; Skin disorders such as dermatitus; eye disorders or overly sensitive eyes.
EMERGENCY AND FIRST AID PROCEDURES
ANY OVEREXPOSURE MOVE VICTIM To FRESH AIR AND SEEK MEDICAL AID. EYE CONTACT: Immediatly flush eyes with warm Clean Water. If
FOR
symptoms persists seek medical attention. SKIN CONTACT: Immediatly flush contaminated skin with water using mild soap if necessary.
Remove all contaminated clothing and do not reuse clothes until thoroughly clean. INHALATION OVEREXPOSURE: Where breathing has
stopped give artificial respiration. If breathing is difficult have qualified persons give medical oxygen. INGESTION: Give victim
aspiration of this material may occur during
water to dilute chemical. NEVER induce vomiting in an unconscious or convulsing victim.
vomiting and can lead to lung damage or death. Seek immediate medical help
MATERIAL SAFETY DATA SHEET
47 VE PRIMER WHITE Page: 3
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---------_- SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ------------
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Evacuate personnel, remove sources of ignition, provide ventilation, equip cleanup crew with safty equipment, contain the spill with
dikes, then use an absorbant or vacumn equipment to remove material. Store waste in a sealed container. Use only nonsparking tools
during clean up. Do not allow this material to flow into the environment. If the spill exceeds the reportable quantity notify EPA
and DOT officials.
WASTE DISPOSAL METHOD
Dispose of in accordance with Local, State and Federal regualtions. Closed containers may explode if incenerated and all wastes
should be incinerated in approved facilities only. In it's uncatalyzed liquid state this material is a hazardous waste due to it's
flammability and should not be released into the environment. The preferred waste management option is to send material that has been
declared waste to a licensed or permitted recycler, reclaimer, or incinerator. Use proper waste manifests and permitted haulers for
transportation of and material which has been declared a waste. Waste disposal and characterization are the responsibility of the
waste generator.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Do not store above 120 deg. F. Store large quantities in buildings designed to comply with Osha, EPA, and local fire department
regulations. KEEP AWAY FROM HEAT, SPARKS AND FLAMES. Keep containers closed and upright when not in use to prevent the escape of
fumes and liquid into the work or storage area.area. Inspect containers frequently to detect any possible damage or deterioration
which might cause release of the material to the environment.
Polymerization of this coating during storage may cause the container to burst explosively. STORE IN COOL DRY AREA.
OTHER PRECAUTIONS
Containers should be grounded when the material is being transferred/mixed to prevent static build up. Empty containers retain all of
the hazardous characteristics of the material itself and should be handled carefully until1 they are thoroughly clean or destroyed.
Large quantities of this material should be stored only in buildings which conform to OSHA standards. If any materials (such as
catalysts, colorants, or thinners)_ are added to this product read all relevant MSDS as the mixture will retain ALL of the hazardous
characteristics of the chemicals added.
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----------------_---- SECTION VIII - CONTROL MEASURES
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RESPIRATORY PROTECTION
During the application of this product or at any time vapors escape into the work space, exposed persons should use appropriate
cartridge respirators (NIOSH/MSHA approved) or in instances of high concentrations, air provided breathing apparatus. Refer to OSHA
regulations to maintain workspace safety. If respirators are required, employees must be trained to use the respirators, the fit of
the respirator must be tested, and the employee's lung capacity must be tested for ability to use the respirator. Respiratory
protection should be used during the curing, cutting, sanding, or polishing of this product. If Respirators are required they must
be carefully selected according to the conditions present at customers location.
VENTILATION
Clean air dilution and local exhaust may be used to maintain the vapor concentration below current exposure limits and 20% below the
LEL, except in confined areas where forced ventilation may be necessary. Refer to OSHA guidlines for handling these types of
materials.
PROTECTIVE GLOVES
Solvent impermeable gloves should be worn to prevent physical contact with the product.
EYE PROTECTION
To protect your eyes, wear safety glasses with side shields, chemical goggles, or face shields.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Solvent impermeable, protective clothing should be worn to minimize skin contact with this product. Emergency showers and eye wash
stations should be provided in the work space. Wear steel toed shoes when handling heavy objects.
MATERIAL SAFETY DATA SHEET
47 VE PRIMER WHITE Page: 4
WORK/HYGIENIC PRACTICES
Inspect Fire extinguishers at regular intervals. Keep work space clean. Retain safty features on all equipment.
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SECTION IX - DISCLAIMER
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To the best of our knowledge this MSDS is accurate. To the extent allowed by law, this statement is made in lieu of any other
warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular
purpose and is in lieu of any other obligations or liability on the part of DURA TECHNOLOGIES, INC.
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