Insec'Licid
Flee
C O N T A C T Y O U R L O C A L U A N U A T E R $ & R O E E R S B R A I . I C HC I F F ' I C E A T
V U & R C H I C A G OO F F I C E 704-737-7450 CH:ICAGOH6TS, IL
**********'******************tt****.*********{.**.*****.**{.******{.*.it'*** ********
P R O B T J C T 'B L ] N T ' I F I C A T I O N
I
**rt'***********!t*:t**rt*****'**.*******.******'*****'****'*****{.***{.{.lt.***
****:r****
P R f i B U C TN A i , f E l Flee Insecticide CAS NO,: Unassigned
COMMONNAMES/SYNCINY|i{S: Fi'fC gg??Zj permethnin |{SBS *: P?I?7
F0RMULAI i'lixture BATE IS$UER: Q7/9O
M O L E C U L A Rt t E I 6 H T : Not App l icab te $UPERCEIIES: Nnne
rl.A:,t* *rk*rt ?t*rt.itrt**:trl*** * *:tzt**
EHE:RGF:NCY ERVIEU
OV
ri.{.*t :1.:t*:t***rf :trt****** **** **
NFPA RAT]:N6 (7O4 CRITSRIA) Hi"IIS I.IAZARO RAT.IN6
F I A Z A R BR A T I N G S C A L E
-
lt-.
HEALTH I ?
-
g=i,lINIl'lAL
F-! g=SERICIUS
3 FIRE I ?
REACTIVfTYT O t=$LIGH'f 4,:SEUERE REACTIVITY: O
SPI!.CIALr ? = II0DERATE
None
Protective 鈧? , q ui p m e n t carr
R E P O I T TN U | V { B E R ;9 7 1 V A N U A T E R S & R O G E R SI N C . PAGE: OO3
l'l$tl$ NO: p9Lp7 i'lATERIAI- SiAF}:TY OATA {JHEET
vE:li$I0N I OO3 F Lee I nsect ic ide E F F E C T I V E D A T E: O7/31/9o
O R O E RN O :
PRDD NO r
only be. assigned on a case
by case basis.
*''t*'*:F***********************'*******.**'**.****t
*.*******{.** ******************.
H A Z A R D O U SI N 6 R E T I I E N T S
*****************'******'**********.{.***
***.,A.{.*.****.***.*.** *********** ***i.*.*.**:1.
EXPCISURE IMTTS, PPI.I
L
OSHA ACGIH OTHER
C O M P O N E Ns )(
T CAS No, t4 ut. PEL T'LU L ]:}II I HAZARO
F e n m e t hr i n 5?645-53-1 U n kn ou n N on e None None Toxic
Stoddand Solvent 8053-41-3 U n kn o u r r r.o0
500 None CombustibLe
{':l'*'*':t"***** * **********'* * ***'*.****** * **:}**.**.****.*:r* * *.*.*** ***?t **** it* ** i.*:+.* *
HEALTH HAZARN INFORI,IATION
*'*'*'**'*d'**!t*********rl*'***:i'd'***'***********.**********.ra.******.**d.***:r*******
PRIMARY ROUTESOF EXPOSUIIEI
Sualloured, Skin or eye contact, inhatatiorr
SI6NS ANO SJY},IPTOMS EXPOSURE
OF
rNf-lALATroN; vapors and mists irritate
tht* n0se irnd throat. Inlralatiorr of
highen concentrations rnay cause headache,:;, nausea, vomiting ancf coma.
rnlral'ation of very hish concentrations
or proronged eXPOSure r,Ay CAUg鈧琹
unconsciousness,
i : : Y E :C O N T A C T I None currently knoun,
{:i,(IN CONTACT: No irritat j.nn is LikeLy af ter brie,f contact but nay be
:irritating prolonged
after contact.
$UALLOUEOI i'lay pro duce UNS depressio n
,I|-IRONIC FFECTS OF EXpO$UltE: prolonged
E or repeatetJ 0veFexposure
; may re$ult
delayed liver and/or kidney damage and CNS depression,
" i E l l r c A Lc o N D r T r C I N s E N E R A L LA G G R A u A T E 0y E x p o s u R E r
G Y B None n鈧琾orted
\'*tt*******'****'***********'***************.******.{.*******.****.*d.it
d.** ****rt ****
I
I
I
I
I
g7t
I R E P O R TN I J M B E R I V A N l ^ / A T E : l t S R O G E R FI N C . FAGE! OOg
&
NO: P9L97 i'{ATERIAL $AFETY 0ATA $HEET
|MSU$
I
oo? Flee Insecticide EFFECTIVE tl'qTE o7l3l/9o
t
ftr*ION:
I
I
0 R D E RN O :
I
P R O DN 0 :
I
I
I
t-------
I
I
FIRST AID MEASURE$
I
I
I
l***************************'**'***'{'*'*'*****'*'******.*********{.**.*r\'*******.{.****
IIF INI{ALEI}: Remove to f reEh air, Give artif respiration
icial not
i.f
6et immediate medical
lbreatlrino. attentio n.
IIN CASE OF EYE CIINTACTT fmmediatel,y flush eyes uittr lots of running uater
15 minutes, liftj.ng the upper ancl louer byelids occasj.onal'ly. Get
lfor
medical. attention.
linnediate
I
l f r u C n S f O F S | ( I N C O N T A C T : I m m e dj a t e t y uash sk in ruith to ts of soaF, and
ua{:er. Remove contaminated clothing and shoesj ua:;h trefore rf?use, 6et
nedical attention persis'ts
if irritation a ' ft e r u a s h i n g ,
Get j.rnmediate nedical, attent
IF $UALLOUED: 0o not induce vomiting. ion.
I,f vomiting occurs EpontaneousLy, keep victim's herad beLor,r lris hips to
'eent breathing the vonitus into the luns*,
NOTES TO PHYSfCIAN: T'his product a pyr.athroid
containE insecticide in a
distillate
Fetroleum base. The lou ingestion of the product
toxicity
conpared to the risk of pneumonitis of petroleun
from aspiration
disti1I'ates suggeste enesie shouLd not be intjuced. Considenation shouLcl be
given to reducirrg ingestion expo$ure by g.:**tri.c l!;r.,uge uj.th an r+rrdotracheal
tube in Place. Activated charcoaL and a cathantic ane resommended and
nerrvous systern stimuLation rrrith a ge'clative, e. g.
should tre controlLed
barbiturateg. Tneatment is symptomatic and suppor.tive.
**'*'*rt*********************:{'****.*.*.******.*****{.*****.y\.*********.*.** ***{.******
F I R E A N O E X F I - O S I O NN F O R I I A T I O N
I
t rr l r r r * ' * * ' * * * * * * * * * * **.***** * * *.***.*.*.** **.* * * ^.*.* * * * *.*.***.*.*.* * * {.** **.{.{,** * * ***.*****
''LASH P0IN'f , DEG. Ft lOg
l"lE'l'HOD SEB: FLA|{MAI3IL.I TY L I I,I:TT ( % v o L , ) I
U No Bata AvaiLatrle
UEL: No 0ata AvaiLable No 0arta Avai.latrLe
LEL;
AUTOI6NITIONTEI,IPE:RATURE, :E, ':
T}E F NO Data AvaiLabLe
] Y ' l ' r N G U r s H r N 6l l g 0 r A l use uate'r spray, dry chernical, o r . a l . c o h oI f o a n .
col,
use a dinect ulater stream.
1|rt
v
iPECIAL FIRE FIGHTING PROCEDURESTFirc-r-fishter should rdsar seLf-contained
:roathing protective
appanatus and full cLothing, Use uaten spray to cool
reanby containers and structureis exposed to fire
PAGE: OO4
VAN UATER5 & RIIGER$ INC,
R f : P C I R TN t J l ' i B E R 9 7 t
|
i ' l A T E R J : A LS A F E T Y N A T A S H E E T
l ' l s ; n S iN 0 : P 9 7 9 7
0ATEt' Q7/31'/9O
EFFHCTM
Fl.ee Insecticide
VElt$I0N: 00?
O R I I E R N OI
PROD NO !
UNUSUALFIRE ANO EXPL0$ION l-tAZAR0S: Extj.rrguish aI"L ne:anbv sources of
since vapors decomPog'es to hazardous products at hiSh
ig,nition
rnay
SeaLed overhe'ated containers
tenperatures. combustibLe.
ltloderately
pT'esent an explosion hazard,
*
**'i*
**'*:l**
* **** * ***
* z t* *
**
*it**rr.* *:t***
:'\.*.{.***{.*** * ******
******** ****.*'****.**
HAZAROOU$ EACTIVITY
R
********
* ************
rt*.rld'*****************.**************.************:l****
S t a b L e ; p o l y m e r i z a t i o n u i 1l n ot o c c u r .
$TABILITY:
C O N D I T I T I N S O A V C IB : Excessive heat.
T I
i'TATERIALS O AVOI0I
T Oxidizers.
carbort
l , l a y L i b e n a t e c a r b o n m on o x i d e ,
F I A Z A R I I O U S E C O M P O S I T I O NP R 0 D U C T S
r
D
and aldehydes.
dioxide, hydrogen chloride, chlorine
*'***d"* **'*"***'**
*.*.;'*'**************.************,*************************.*,r'*'*
ANO OISPOSAL PROCETIURES;
SPILL, LEAK,
* **dr *** {'
*** r t* r r * . r t * * * * ' t r t * ' *
*.*.*.*.***rt** * **************rt**********.***.***
*it*****
Uear protective equiPment includi.ns
AC'IION TCI TAI(E FOR SPILLS OR LEAKS:
gloves, rubber aPr0n, and a self-
rubben boots, chernical-protective
in ttre pressure demand mode or a 鈧琲uP,rlied-ai.r'
apparatus
contained.breathing
face Piece air-purj.fving
or leak ie sila11, a full
the spill
re$F,irator, If
In
organj.c vap0rs nay be satisfactory.
respirator equj.pf,ed for
car.tridge
souPcf;r:i.
alurays {rear eye protection, al.l, isnition
Extinguish
ijny event,
lnop or uipe up and cli.gpose of in 0OT-aFproved
[:or. smal]. $Fi11s or dripsr
or othe*r
utith soil
b)'diking
contain
ua:;te containens. For large spills,
ancl {:hen f}umP j'nto 0CIT-erpproved tlaste
non-combustibLe absorbent material$,
Place resicluei
sorbent material,
or abgorb r,rith non-conbuEtible
containens,
Keep out of stebrerE, storn drairrs,
in 0OT-approved uaste containers.
surf ace LrateFs ancl so iL.
g0vernmental and
reportingJ,
0n spill
reguLati0ns
ConrpLy r,rith alt applicable
lrandlins and di5posaL of uaste.
u J . $ P O S A Li I H T H O D S : D i s p o s e o f c o n t a m i n a t s - , d p r o d u c t used in
and naterialLs
material.
in a manner appnoved for this
cJ.eaning up spilLE 0r leaks
agensi,es ttr
and Local regulatory
State
ConsuLt appropriate Federal,
pnoper disposal. procedures.
a:rcertain
g7t
FEPORTNUMBERT pA6E! OO5
VAN UATERS & R06ERS INC.
NO: P9L97 ]TATERIAL SAFETY I]A'[A SHEET
[$0S
-
OO? Flee f nsecticide
[ '- t I o N :
I E F F E C T I V E D A T Et O 7 / . S t / 9 e
ORI]ERNO:
pR0D NO !
r-------
NOTE:: Emptv containens gases-and mists
can have regidues, and are Eubject
t-
Fo proper uaste disposal, as above,
r{'******'*'**'*******r}***'****.**.***********************.*******************rt**
PERST}NAL PROTECTIT}N
bt'{'t}tb***rt* **** **rt*****,****.*:t**** *** *** *.***'** ** *:l*** * * ** **rt** * ** *:t* * *** ** *
/ENl'rLATroN: Local mechanicar exhau:;t ven{:il.ation capable of maintaining
lnissions the point of use belor.r the pEL.
at
tE$PIRATORY PROTECTION: If u5e conrJition.E generate vaporE on nists, uear a
lfO$H-apProved respirator appropriate for thoEe e,missiolr leveJ.:i.
lpPr0priate resPirators may be a fuLl face piece op a half-mask air-
turi.fying cartridge respirator equi.pped for. organic vapors/mists, a self-
:ontained breathing aPPtsnatus in the pressure demand mode, or a supplied-
r;a resp irato r.
-
:YFPROTECTIONI Chernical, sossleE. is generally
It recognized that contact
'enses should not be Lrorn uhen uorking uith chenicaLs because contact
'en$e5 may contribute to the severity of an eye injury.
'RoTEcTIUE
CLOTHIN6: Long-sleeved shirt, trousers, rubber boots, chemicaL-
,rotective gLoveE made of nitrile 0r butyl, rubben and rubber apron.
THER PRoTEcTIvE MEA$URES: An eyeuash and safety shouer should be nearby
nd neady for use.
:t*'{'*'******************.************.*.*******.********:}**
*****.********.**.***
SPECIAL PRECAUTITINS
?k{'*rr*** * * *'****'*** ****.**.*.**.****************** **** * * *.**.* * *********.*:t** *.**,*
T O R A G EA N O H A N D L I N G P R E C A U T I T T N S : S t o r e i n a c o o l , ctry, r,relt-.ventiIated
lace. Store auay from all othen chemicals and potential sources of
ontamination. KeeP container tightLy cLosed uher not in use. 0o not use
re$sure to empty container, lJash thoroughly after handling, Do not get
n eyesr on skinr 0p on clothing. 0o not stone trelou 4o F.
EPAIR ANO I'IAINTENANCE RECAUTION{jr Do not
P grind,
cut, uetd, or dril1 on
r nean this container,
rf PRECAUTICINS: Containensr 鈧琕鈧琻 those that have been enptiecl, uiLl.
product
etain nesidue and vapors. ALr,lays obey hazard uarnings and trandle
'
mpty containens as if they h,ere f utl.
V A N U A T E R S & R O G E R Sr N c .
R EP O I I T N I J H B E R 9 7 1 PAGE: OO6
:
l ' I A T E R I A L l l f r F E T Y n A ' f A SiHEET
HfiU$ N0: PqL97
E F F E C T I U E D A T Et A 7 / 3 1 / 9 A
VEll$I0N: Flee Insecticide
OO3
OROERNO:
PROD NI] :
{'*'*'*'**.*.*:t:f ****tt**:t*.*d'*****{'******'***'******.*.*******:t****!t*****************
PHYSICAL PROPERTIES
Jr*th*'!k*:t** ****:t*
*****tr****rt** ********* ** ***** r+* ** * * *'**:t *******:t*** **!**'****
B0ILINS POINT, DEGF.: No 0ata Availatrl.e
MEL.TIN6 POINT, DEG F.: 3?
GRAVITY (UATER :: 1):
$PECIFIC 1.O43
P l {: 5.9
V A P C I RP R E S S U R E , m n H s I No 0ata AvailabLe
VApOR BENSITY (AIR=t ) r Emulsifies
U A T E RS 0 L U B I L I T Y % t
No Ilata Available
E V A P O R A T I O N A T E ( B U T Y L A C E T A T E= 1 ) :
R No Data AvaiLabl.e
(by
tr /OLATILE l t O L U i r { EI
) No 0ata AvailabLe
petrol.eum
f ' P P E A R A N C EA N 0 C I I l C I R t C l e a n broun liquid; faint mild odor.
*'*t'* *****'* **{'********* **rt*** **{.*** *.*'tt**.******* * * *.*r\.****
* ***rt***tb*.****rk***
T O X I C I T YD A T A
'{ .{ . rt. * * * * ************ ********'****'*.*'**** ***.*.{ ' ******J**.*********r \.************
0RAL: No Data Available
ilERMAL
r No 0ata AvaiLabl.e
IN|-lf'L.ATIFN; No Bata AvirilabLer
ARCINOGENICITY: This rnaterial by the
is not considened to be a cancinogen
'foxicoLogy
attionaL Program, AEency for Research on
the fnternational
erncer or 0SHA,
animal,s, pennethrin
Tl'lEll nATA: In studies urith laboratory did not cau:re
sFrroductive or teratogenicity.
toxicity AnaLysi.s of chronic feeding
in both mice and nats L,ith permethrin
tudies requl.ted in the c0nclusiorr
liat pFrmethrin's potentiat for induction of 0nc0genicitv in experinental
tnals is lou and that the likelihood of 0ncogenic effects in hurrans irr
.texistent or extremely luu. Long-te.rn feedj.ng studies in anirnals
esul.ted in incneased Iiven and kirjney r.reights and induction of the liver
j.crosomal drug netabolizing enzyne sy$tem and hieropathological changes in
lack of genetoxicity
hc' lungs and liver. An riverall lras been demonstrated
perrme{:hrin.
n nutagenicity testing uith Flee uas not nutageni.c in an ames
R E P O R TN T J M B E R : 7 1
9 UAN UATERS & ROGERSI N C . FAGE: OO7
M$tlS NO: PgL?7 |"IATERIAL SIAFETY NATA SHEET
,f ro*, ooz Flee fnsecticide E F F E C T I V ED A T E 0 7 t ? t / 9 0
I
O R 0 E RN OI
P R O DN O i
Assay.
*'*'*'{"**'*********'************'**'*************.*********.*.************:r**:t*****
ECOLCIGICAI- INF'ORMATION
**"**'d'*** * *'*******:t**** * * * **** * ** *:l ***** * * **** *ty*** ** * * *'* **.lt.**rt.*******zt:t* *
No 0ata Available
A'*'?i'******'**'**'*****:t**'*'*****.*,*********.********:r****** ********.****:t********
O T H E RI ? E T ' U L A T O R Y F C I R i { A T I O N
IN
fr*:^"4'***rt* * **/v******.******* ***rt ********.* ***.**.** * * ** *'***.*:t*.******** * *** ****
SECTION 313: N on e
65: None
IOSITION
v
SECTION 31,3 ANO PROPOSITION 65r None
C T I O N 3 1 3 ( U I T H C H E I ' 1 I C A LL I S T E 0 ) :
S None
ROPOSITIIIN 5 (UITH CHEMICALS ISTED):
6 L None
A S S A C H U S E T T S :U n d e r t h e l . l a s s a c h u s e t t s R i g h t - ' f ' o - K n o u L a u , F l a z a r d o u s
ubstance and Extraordinarily f'lazardous Substances components present in
h:ie product r,rhich requines reporting are!
ARI}OUS$UBSTANCES
( cAs No.
HI]MICAL s) CONCENTRATION,T%)
(
ernethrin 5?645-53-t Unknoun
t o d d a n d S ol v e n t 805?*41-3 U n kn o u n
ENNSYLVANIA: Under ttre PennsyLvania Risht-To-t(nou Lau, Hazardous
ubstances and Special Hazardous Substances contponents present in this
roduct r,rhich require reporting are:
AZAROCIUS UBSTANCE$
S
( C O N C E N T R A T I( > I % >
I{EIMICAL s) CAS NO, ON
sol v e n t 8053-41-3 U n kn o u r r
Jaru
ALIFORNIA SCAQI{D: RuIe 443 1 VOC's
No Data Available V A P O RP R E S S U R E I N o 0 a t a A v a i L a b 1 e
PAGE OOB
r
R EP O I I T N I J M B E R 9 7 1 V A N I J A T E R S& R O I } E R S N C .
I I
M A ' T E R I A L A F E T Y O A T AS H E E T
S
M$OS NOr P?l97
EFFECTMI DATE A7/3L/9<'
:
VIiRSI0Nr OO? Flee fn:;ecticide
CIROER O:
N
PR0DNO !
product
TSCA: ingredients
The of this are 0n the TSCA inventory.
***'**.****************** *********'
***********t ****.***rt**********.********.{.**
REVISIT}NS
.:::::1::i:::::::1:::::l;;.;ilffiill.iil;i;l;ili.:::::::::::::i:::::____
C0NTACT: l'ISDS COORBINATOR V U & R C I . I I C A 6 OO F F I C E
( ?06 ) 889-3400
D U R I N G B U S I N E S . SH I T U R S , P A C I F I C T I H E
P R 0 O U CrT O R O E FN O :
I?/O4/91 OBrll CUST NO:
-----NOTTCE ----
("VU&R") EXPRESSLY fSCf-nfilS ALL EXPRESS R
* r r ' U A N U A T E R S6 . R O G E R S N C .
I O
n
I M P L . I E D U A R R A N T I E S F } ' , I E R C H A N T A B I L I T Y I } F I T N E S S F ' O RA P A R T I C U L A R U R P O S E ,
O P
AN
U I I ' H R E S P E C T T O T H E P R O O U C TO R I N F O R I . I A T I O NP R O V I O E OH E R E I N . * *
A L L I N F O R I ' | A T I O N A P P E A R I N C I . I E R E I N I S B A S E D U P O N D A T A O B T A I N E T ]F R O M T H E
I . I A N U F A C T U , R EA N O , / O R R E C O C i N T . Z E T E C H N I C A L S O U R C E S . U F I I L g T F I E I N F O R I , I A T I O N I S
R O
F E . L . I E V E DT O B E A C C U R A T E , V I J & R I . I A I ( E S N O R E P R E S E N T A T I I } N $ A S 1 ' O I T $ A C C U R A C Y C I R
$ U I - ' t s I C I E N C Y . C O N D I T I O N S O F U S E A R E B E Y O N O I ' U & R S }C O N T R I I I - A N O T T . I E R E F O R E S E R S
U
A R E : R E S P O N I J I B L ET O V E R I F Y T H I S D A ' I ' A U N I ] E R T H E I R O U N O P H R A T I N G C O N D I T I I ] N S T O
N E T E R I ' I I N EU H E T F I E RT H E P R O D I ' E T I S S J U I T A B L E F O R ' I ' I { E I R P A R ' T I C U L A RP U R P O $ E SA N O T H E Y
A S $ U I . I EA I - L R I S I ( S C I F T H E I R U S E , H A N T } L I N I ] , A N D D I S P O S A L O F T I - I E P R C I B U C T ,O R F R O M
THE PUBLICATION OR USE OF, OR RELIAI.ICE Ut'ClN , INFCIR|,4ATION ON'fAINE0 llEREfN. C
T H I S I N F O R M A T I O N R E L A T E S O N L Y T O T I . I E P R O O U C TD E S I E N A T E D H E R E I N , A N D T 1 O E S O T N
ITELATE TO ITS USE IN COI'IBINATION IJITH ANY OTHER i'IATERIAL OR IN ANY OTHER
F'ROCESS.
*** ***
END OF I'1905
|