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SIGMACHEMICAL CO -. SODIUM AZIDE-- 6550-00N084899
f dentification
Product
P r o d u c t I D : S O D I U MA Z I D E
M S D SD a t e : 0 8 / 2 0 / 1 9 9 1
F S C :6 5 5 0
NIIN:00N084899
MSDSNumber: CGVDR
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Raqn^nci l.rl a D:rtrr
.^mn^n\/ N:mc.STGMj\ CO
CHEMICAL
Box:14508
City: ST LOUIS
State :MO
Z I P : 6 3 1 18
Counlry: US
I n f o P h o n e N u m : 3 1 4 - 1 11 - 5 7 5 5
rimarooncrz Fhnne Num: 31 4-11 ]-51 65
C A G E2 1 0 16
:
:::
::: ConLractor Identification
/-nmn:nu rrlrma. ar-MA COMPANY
CHEMICAL
Address:3050 SPRUCE T S
Box:14508
City: ST LOUIS
State :MO
Z I P : 6 3 1 1B
Country: US
P h o n e : 3 1 4 - 1 11 - 5 7 6 5
C A G E : : . 0 16
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onlTnform:ti
(CERCLA)
I n g r e d N a m e : S O D I U MA Z I D E ( S A R A 3 0 2 )
CAS 26628-22-8
:
R T E C S# : V Y 8 0 5 0 0 0 0
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O S H AP E L : S , C 0 . 1 P P M ( H N 3 )
ACGIHTLV:C 0.11 PPM; 9495
EPA Rpt Qty:1000 LBS
DoT Rpt Qty:1000 LBS
Hazards Identification
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Skin:YES Ingestion:YES
Routes of Entry: Inhalation:YES
Rannrfs oF f-:reirncenicifrr'\-P.NO IARC:NO OSHA:NO
MAY BE HARMFUL BY INHALATION,
Hazards Acute and Chronic:ACUTE:
Heafth
INGtrST]ON, OR SKIN ABSORPTION. MAY CAUSE EYE IRRITATION. MAY CAUSE
S K I N I R R T T A T I O N . M A T E R I A L M A Y B E I R R I T A T I N G T O M U C O U S M t r M B R A N E SA N D
UPPER RESPIRATORY TRACT. TO THE BEST OE MFR'S KNOWLEDGE, THE
CHtrMTCAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVtr NOT BEEN
THOROUGHLY]NVESTIGATED.
r ^-I - - rt d-r'l . ^ !L f I U l - U I ' U uA r rv -r-- vr\ o o e n i c i f v : N O T R E L E V A N T .
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Effects HEALTH HAZARD.
of Overexposure:SEE
Mcd i c: l Cond A.t.rr:\r:f ad hrr F,vnnsure: NONE SPECIFIED BY MANUFACTURER.
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uvs
First Measures
Aid
IMMEDIATELY FLUSH WITH COPIOUS AMOUNTSOF WATER FOR AT
Ard:EYES:
First
LEAST 15 MINUTES, SKIN: IMMEDIATELY WASH W]TH SOAP AND COPIOUS
AMOUNTS OF WATER. INHAL: REMOVtr TO FRESH AIR. ]F NOT BREATHING GIVE
AL RESPIRATION. IF BREATHING ]S D]FFICULT/ GIVE OXYGEN.
ART]FICI
TNGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON 15 CONSCIOUS.
08t37t2007
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Page2of3
C A L L A P H Y S I C I A N . W A S H C O N T A M I N A T E D L O T H I N G B E F O R ER E U S E .
C
tri al't inc Ma:srrros
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Flash Point:NOT KNOWN
trxtinguishing'Media:WATER S P R A Y . C A R B O N D I O X I D E , D R Y C H E M I C A L P O W D t r RO R
APPROPR]ATE FOAM.
Fighting
rire Procedures i USE NIOSH APPROVED SCBA & FULL PROTtrCTIVE
EQUIPMENT
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
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auuf uclr Lda neled.be uI e5
Refease Procedures:WEAR RESPIRATOR, CHEMICAL SAFETY COGGLES,
Spill
RUBBtrR BOOTS AND HtrAVY RUBBER GLOVES. SP]LLED MATER]AL SHOULD BE
CAREFULLY WIPED UP OR MO]STENED WITH WATER AND REMOVED. VENTILATE
AREA AND WASH SPILL S]TE AF TER MATER]AL PICKUP IS COMPLETE.
Neutrafizing Agent:NONE SPECIFIED BY MANUFACTURER.
qtor:flo
Hanrll i nn :nrl
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
TIGHTLY CLOSED. AVOID INHALATION. AVOID CONTACT W]TH EYES, SK]N AND
C L O T H I N G . A V O I D P R O L O N G E DO R R E P E A T E D E X P O S U R E .
Precautions:
Other SODIUM AZIDE MAY REACT WITH LEAD AND COPPER PLUMBING
TO FORM HIGHLY EXPLOSIVE METAL AZIDES.
Protection
Exposure Controls/Personal
Respiratory Protection:NIOSH APPROVEDRESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves : CHEMICAL*RESISTENT GLOVES.
I-,rreProf er-tion:ANSf A P P R O V E D C H E M W O R K E R SG O G G S
E q u i p m e n t : E Y E W A S H F O U N T A I N & D E L U G E S H O W E RW H I C H M E E T
Protective
Oiner
ANSI DESIGN CRITER]A
Work Hygienic Pract.ices:WASH THOROUGHLY FTER HANDLING. A
Qrrnnl omonJ. : l Q:fal- rz :nr] FIa: ll- h
MATER]ALS TO AVOID: ARE MORE SENSIT]VE THAN NITROGLYCERINE. AZIDE
REACTS WITH METAL HAL]DES TO GIVE A RANGE OF METAL AZIDE HALIDES,
MANY OF WHICH ARE EXPLOS]VE. INCOMPAT]BLE WITH CHROMYL CHLORIDE, HY
DRAZINE, BROMINE, CARBON DISULFIDE, DIMETHYL SULFATE,
DIBROMOMALON]TRILE.
Dlrrrqic:I /f-homin:l Drnnorf iac
Spec Gravity:NOT KNOWN
F,rz:nor:f i nn Ref c & Ref erence rNOT KNOWN
o ^ r , , L r ' l i Fy, , r. r;n hvro t e r : N o T K N o w N
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Si:hi I iirz Tnclie:torlMateriafs to Avoid:YES
DIMETHYL SULFATtr ]S ]NCOMPATIBLE W/SODIUM AZIDE. ACID CHLORIDES,
H A L O G E N A T E DS O L V S , A V O I D C N T C T W / M E T A L S . A V O ] D C O N T W / A C I D . A Z I D E
RtrACTS W/MANY HVY METALS SUCH AS LEAD, COPPtrR, MERCURY, SILVER,
GOLD TO FORM EXPLO COMPOUNDS
SfabiIitv Con
H:zerdors Decomnssftion Products :NOT KNOWN.
Considerations
Disposal
W a s t e D i s p o s a l M e t h o d s : C O N T A C T L I C E N S E D P R O F E S S I O N AW A S T ED I S P O S A L
A L
S E R V I C E T O D I S P O S E O F T H I S M A T E R I A L . S O D ] U MA Z I D E M A Y R E A C TW I T H
http ://www2.hazard.com/msdslf2lcgvlcgvdr.html 0813U2007
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LEAD AND COPPER PLUMBING TO FORM H]GHLY EXPLOSlVE METAL AZIDES.
OBSERVE ALL F'EDERAL, STA TE AND LOCAL ENV]RONMENTAL REGULATIONS.
I
information by the compiling agencies):
Discfaimer (provided with Ehis
for use by elements of the Department
is formulated
This information
of America in no manner whatsoever'
The United States
of Defense.
to be accurate and
axnrcqsl rz ori mnl i ed, warr:nf .s this information
v! rrL,yrruv,
e^IJ!v,url
Any person utilizing this
for its use.
discLaims aII liability
advice to verify and
professional
document shoufd seek competent
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to
information
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http ://www 2 .hazard.coml msds f2 I cgvlc gvdr.html 08t3r/2007
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