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Material Data
Safety HourAssistance:
Sheet
1 - Ghemical
Product Gom
/ Information
Product
Name: Revision
Painters Date: 1113012006
TouchAerosol Top Coats
1970830,925830,
1 1931830,1941830,
1952830, 1961830, 1962830,1965830,
1922830, 926830,
1 1930830,1933830,
1938830, 945830,
1 1946830,1949830,
1950830,953830,
1 1963830,1964830,
1966830,967830,
1 1974830,1976830,
ldentification
1977830,979830,
1 1982830,1986830,
Number: Lab Saigty Supply Inc. ReorderNo- 17135
1992830, 994830,
1 1995830,1996830,
1924830,927830,
1 1934830,1947830,
1948830,951
1 830,1971830, 1972830,
1973830, 1975830, 1990830,1993830,
224356, 224357, 224358,224359,
225191 240268,240217
, ,240255
Product Use/Class:
Topcoats/Aerosol
Rust-Oleum Corporation
Supplier: Manufacturel Rust-Oleum Corporation
11 Hawthorn Parlotay 11 Hawthorn Parkway
VernonHills,lL 60061 Vernon Hills. 60061
lL
USA USA
Preparer: Regulatory Department
2-Gom ition/ Information
On ients
Ghruicd.XaE CAS Numher Wighr % LGs ThmAcclH TLv-TwA AcctH TLV-STEL OSUAIEkIIUA OSSAIELCELNG.
Acetone 40.0 5OO
67-d-1 PPM 750 PPM 750 PPM N.E
LiquefiedPetsdeumGas 35.0 1MOPPM
6847G86鈧? N.E. 1fiD PFM NE.
AfiphaticPetrdeum DiSillates 20.0 4OO
647478-9 PPM N.E. 4OO PPM NE.
n.o
-3
Toluene 108"88 50 PPM 150PPM 2OO PPM 3OOPPM
Titanium Dioxide 1346$6/-7 150 10mg/m3 N.E. 10mg/m3 N.E.
133p-n-7
Xylene 15.0 1OO PPM 150PPM 1OO PPM N.E.
AromdicSolwnl 64742-96鈧? 10.0 N,E, N.E. N.E. N,E.
Naphtha eo32-3p,4 10.0 3OO PPM N.E. N.E. N.E.
Stoddard Sdwnts 8052-41-3 10.0 1OO PPM N.E. 5OO PPM N.E.
Magnesiurn Silicde 1,|807-S鈧? 5.0 10mg/m3 N.E. 15mg/m3 N.E.
10041-4
Ethylbenzene 50 1OO PPM 125PPM 1OO PPM N.E
ArofitdicHydrocarbon 64242-5鈧? 5,0 N.E. N.E. N.E, N.E.
Eth$ene GlycolMonobutyt
Ether111-76-2 5.0 20PPM N.E. 50PPM N.E.
1,2,+Tdmetlylbenzere F6B鈧? 5.0 25PPM N.E. N.E. N.E.
Pigment 122
Red 99G26-7 5.0 15mg/m3 N.E. 5mg/m3 N.E,
Pigment Black7 1333-&t4 5.0 3.5mg/m3 N.E. 3.5mg/m3 N.E.
PigmentViold 32 1n2+@4 0.1 N.E. N.E. N.E. N.E.
3 - Hazards
ldentification
** Emergency **: Contents
Overview UnderPressure.
Harmful inhaled.
if Mayaffectthe brainor nervoussystem
causingdizziness,
headache nausea.
or Vapors
maycauseflash or explosion.
fire Extremely flammable liquidand
vapor.Harmful swallowed.
if
-
EffectsOf Overexposure Eye Contact: Causeseye irritation.
- SkinContact: Maybe harmful absorbed
Effects Overexposure
Of if throughskin.Prolonged repeated
or contact
may causeskinirritation.
Substancemaycauseslightskinirritation.
-
Effects OverexposureInhalation.Highvaporconcentrations irritating the eyes,nose,throatand lungs.
Of are to
Avoidbreathing
vaporsor mists.Highgas,vapor,mistor dustconcentrations be harmful inhaled.
may if Harmfut lt
inhaled.
-
!ff9cfs Of OverexposureIngestion:Aspiration
hazard swallowed; enterlungsandcausedamage.
if can
Substance be harmfulif
may swallowed.
-
E_ffects overexposure Chronic
Of Hazards: IARClistsEthylbenzene a possible
as (group
human carcinogen 2B).
Maycausecentralneryous system (e,g,narcosis
disorder involving lossoi coordination,
a weakne*s, -fatigue,
mentalconfusion, blurred
and vision)andiordamage. Reports haveassociated and prolonged
repeated
occupational overexposure solvents with permanent
to brainand neryous systemdamage. Overexposure xylene
to
in laboratoryanimalshas beenassociated liverabnormalities,
with kidney, lung,spleen,lye and blooddarnagb as
well as reproductive
disorders. Effects humans, to chronic
in due overexposure, haveincluOeO cardiac
liver,
abnormalities nervous.system
and damage. Overexposure toluene laboratory
to in animalshas beenassociated
with liverabnormalities,
kidney, lungand spleendarirage. Effects humans
in haveincluded liverand cardiac
abnormalities.
Contains carbonblack.Chronic inflammation, fibrosis, lungtumorshavebeenobserved somerats
lung and in
expenmentally exposed long periods timeto excessive
for of concentrations carbonblackand severalinsoluble
of
finedustparticles.Tumors havenotbeenobserved otheranimalspecies mouse
in (i.e., and hampster) under
calstudies NorthAmerican
of workers showno evidence
lationalexposure carbonblack
to
nicto humans' IARCand is proposed be listed
by to as
,anConference Govermental
of IndustrialHygienists.
;ation drying.Riskof overexposure
or depends on
lingof surfaces spraymistandthe actualconcentration
or
Primary
Route(s) Entry:skincontact, Absorption,
of skin Inhatation, contact
Eye
4 - FirstAid Measures
Fjrst - EyeContact:
Holdeyelids
apart flush plenty water at least minutes. medical
and with of for 1S Get
4id
attention.
First - SkinContact:
Aid Vi/ash soap water. medical
with and Get attentionirritation
if develops persists.
or
First - Inhalation.youexperience
Aid lf difficulty breathing, thearea obtain
in leave to fresh lf continued
air.
difficulty experienced, medical
is get assistanceimmediately.
First - Ingestion:
Aid Aspiration
hazard: notinduce
Do vomiting giveanything mouth
or by because material
this
canenter lungs cause
the and severe damage. immediatjmedical
lung Get attention.
on 5 - Fire hting Measures
-156F
FlashPoint. LO\ /EREXPLOSIVE
LIMIT:0.7 %
(Setaflash)
LIMIT: 32 5 o/o
UPPER EXPLOSIVE
Extinguishing Dry
Media: Chemical,
Foam,
Water
Fog
Fire
.Unusual And Explosion Hazards:
Perforation the pressurized
of containermaycausebursting the can.
of
Waterspraymaybe ineffective.
Closed containersmayexplodewhenexposed extreme
to treat.ftRSH POINTlS
LESSTHAN20".F. XTREMELYFLAMMABLELlQUlDANDVAPORiVaporsmayformexptosivemixtures
-E
air. VapoJs travelto a source ignition
can of and flashback.Keepcontainerstighflyclosed.lsolatefrom heat,
electrimlequipment,
sparks openflame.
and
specialFirefighting
Procedures:
Evacuate
areaand fightfirefroma safedistance.
6 - Accidental
ReleaseMeasures
StgOs Be Takenlf Material Released Spilled:
To ls Or Remove sources ignition,
all of ventilate
areaand remove
with inertabsorbent non-sparking
and tools.
Cohtain
spilled
liquid withsandoiearth.OOruOf usecombustible
materials suchas sawdust.
Dispose according local,state(provincial) federalregulations. not
of to and Do
incinerateclosedcontainers.
7 - Handl And
Handling:
Wash hands
bgfo_reea!!ng. onlyina well-ventilated Wash
Use area. thoroughly handling.
after Avoid
breathing
vapor mist.
or Follow MSDS/labelprecautions after
all even eontaineremltieO
is because riay retain
it
product
residues.
Storage: not$oreabove ' F. Store
Do 120 quantities buildings
large in designed protected storage
and for of
NFPA Class flammable
I liquids.
Keep
containers
tightly
closed.lsolaie
from-heat,
electrical
equipment,
sparksand
above . F.
openflame. pressure. notexpose heat store
contents
under Do to or 120
I - Exposure protection
Controls/ Personal
Prevent -upof vapors opening doors windows achieve
Engineering
Controls: build by all and to cross-ventilation.
Useprocessenclosures, exhaust
local ventilation, other
or engineering
controls control
to airborne
levels
below
recom - proof
mended exposure its.useexplosion
Iim ventilation uipment.
eq
Respiratory
Protection:A
NIOSH/MSHAapproved purifying
air respirator anorganic
with vapor cartridge canister
or
maybe permissible certain
under circumstances air'boiire
where c6ncentrations
are?pectdd exceeld
to exposure
limits.
provided airpurifylng
Protection by respiratorslimited. a positive
is pressure supplied
Use air if
respiratorthere
is
anypotential an uncontrolled
for release,
exposure levels notknown, anyother
are or ciicumstances air
where
puriffing
respirators prwideadequate
maynot protection.respiratory
proteciion
program meets
A that OSHA
1910.134 ANSI
and 288.2requirements befollowed
must wheneverwbitptaceconditi6ns
warrant respirator's
a
use.
SkinProtection:
Nitrile Neoprene
or gloves afford
may adequate protection. impeMous
skin gloves prevent
Use to
skincontact absorptionthismaterial
and of through skin.
the
EyeProtection: safety
Use eyewear
designed protect
to against
splash liquids.
of
protectve
Other equipment: to safety
Refer supervisor industrial
or hygienist further
for information
regarding
personal
protective
equipment itsapplication.
and
Hygienic
Practices: thoroughly soap water
Wash with and before
eating,
drinking smoking.
or
Section9 - I And Chemical
Properties
-34 - 999 F
Boiling
Range: VaporDensity: Heavier air
than
Odor. OdorThreshold:
SolventLike ND
Appearance: Evaporation
Rate:
Liquid Faster Ether
than
Solubility H2O:
in Slight
FreezePoint: ND Specific
Gravity:
VaporPressure. PH: NE
PhysicalState: Liquid
(See section 16 for abbreviationlegend)
Section10 - Stabilitv And
above120' F. Avoidall possible
Conditions Avoid:Avoid
To temperatures sources ignition.
of
fncompatibility:
Incompatible strong
with oxidizing
agents,
strongacidsand strongalkalies.
Hazardous Decomposition:
\Men heated demmposition, emitsacridsmokeand initating
to it fumes.By open
flame,carbonmonoxide carbon
and dioxide.
Hazardous
Polymerization: notoccurundernormal
will conditions.
Stability:
This product stableundernormal
is storageconditions.
Section11- Tox al Information
Product
LD50:
ND Product
LC50:
ND
ChemicalNarne LD5O LC50
Acetone N.D N.D.
Liquefied PetroleumGas N.D. N.D.
AliphaticPetroleumDistil
lates N.D. N.D.
Toluene N.D N.D.
TitaniumDioxide >7500 (ORAL,
mg/kg RAT) N.D.
Xylene N.D N.D.
Aromatic Solvent 4700 (ORAL,
mg/kg (lNH,
RAT) 3670 mg/kg RAT)
Naphtha >5000mg/(g(ORAL,RAT) N.D.
Stoddard Solvents N.D. N.D.
Magnesium Silicate N.D. TCLo:11m9/m3
inh.
Ethylbenzene 3500 (ORAL,
mg/kg RAT) N.D.
Aromatic Hydrocarbon N.D. ND
Ethylene GlycolMonobutyl Ether (ORAL,
1519mg/kg PPM(lNH7 Hr,RAT)
MOUSEF0O
1,2,4-Trimethylbenzene N.D. 18000 (RAT, HR)
mg/m3 4
Pigment Red 122 N.D. N.D.
Pigment Black 7 >8000mg/kg(ORAL,RAT) N.D.
Pigment Violet32 >10000 (ORAL,
RAT) N.D.
mgiKg
12 - Eco Information
productis a mixture listedcomponents.
Ecological
Information: of
Section - Di
13 Information
Disposal Information:Dispose material accordance local,
of in to stateandfederalregulations ordinances.
Do
and
not allowto enterstormdrainsor sewersystems.
Section14 - Tra tion Information
DOTProper Aerosol
Shipping
Name: PackingGroup:
DOTTechnicalName: HazardSubclass:
DOTHazard
Class: 2.1 Resp.
Guide Page: 126
DOTUN/NANumber: uN1950
15- lnformation
CERCLA- SARA HazardGategory
This product beenreviewed
has acmrdingto the EPA"Haz Categories"
promulgated
ard underSections311and
312of theSuperfund Amendment Reauthorization of 1986(SARA
and Act TitlellD-and considered,
is under
applicable
deftnitions, meetthe following
to categories:
IMMEDIATE
HEALTH
HAZARD,
CHRONIC
HEALTH
HAZARD,
FIREHAZARD
SARA Section313:
Listedbelowarethe substances any)contained this product are subject the reporting
(if in that to ot
requirements
Section313 of Title lll of the Superfund
Amendment Reauthorization of 1986and 40 CFR part372:
and Act
ChemicalNanB CASNumber
Toluene 108鈧?8-3
Xylene 133U20-7
Ethylbenzene 1co41-4
Ethylene
Glycol
Monobutyl
Ether 111-76-2
1,2,4-Trimethylbenzene 9163鈧?
ToxicSubstances
Gontrol
Act:
Listed
below thesubstances any)contained thisproduct aresubject thereporting
(if
are in that to requirements
of
TSCA 12(B) exported theUnited
if from States:
Noneknown
U.S.StateRegulations: follows-
As
NewJersey Right-toKnow :
Thefollowing
materials non-hazardous, are among top five components this product.
are but the in
ChemicalNann CAS Number
Modified
Alkyd PROPRIETARY
Pennsylva Right-to-Know
nia :
The following
non-hizardous
ingredients present the product greater
are in at than37o.
Chamieal Nanre CAS Numher
Modified
Alkyd PROPRIETARY
Modified
Alkyd PROPRIETARY
BariumSulfate 7727-43-7
CalciumCarbonate 1317-653
lronOxide 130937-1
GaliforniaProposition65:
WARNING! product
This contains chemical(s)
a known theState Calrfornia cause
by of to cancer.
WARNING! product
This contains chemical(s)
a known thestate Califomia cause
to of to birthdefects other
or
reproductive
harm.
International Regulations: As follows -
CANADIAN
WHMIS:
ThisMSDS beenprepared compliance Controlled
has in with Product
Regulations
except theuseof the16
for
headings.
CANADIAN
WHMTS
GLASS:
AB5,
D2A,
D2B
on 16 - OtherInformation
HMISRatlngs:
Health:2 Flammability:4 Reactivity:0 Personal
Protection:X
VOLATILE
ORGANIC g/t:
COMPOUNDS, M
REASON
FORREVISION:
Legend:N.A.- NotApplicable, - NotEstabtished, - NotDetermined
N.E. N.D.
Theinformationcontained thisMSDS been
on has checked should accurate.
and be However.isthe
it
responsibility user comply allFederal,
ofthe to with State, Local
and laws regulations.
and
|