303t
SAFETY.KLEEN
PREMIUM
G ReorderNo. 17t35
Lab Safety Supply Inc.
MATERIATSAFETYDATA SHEETFORUSAAND CANADA
sEcrloN 1: cHEMtcALPRoDUcr ANDco|}lpANytDENTtFtcATtoN
PRODUCTNAME: SAFETY-KLEEN
PREMIUMGOLDSOLVENT
SYNONYMS: (Alsoknownas SAFEW-KLEEN PREMIUM GOLD
-
SOLVENT cALrF-andSAFEW-KLEEN pREMruM SOLVENT.)
Parts vlhsher solvent; petroteumDistilfates;petrofeumlta ptrttra
;
Naphtha, lvenl; Stoddard
So Sofvent;
Minera Spirits.
I
PRODUCT
PART
NUMBERS: (Alsoknownas 6639.) 6638.
PRODUGT
USE: Cleaning degreasing
and metalparts.
productis usedin c_ombination otherchemicals,
rf thrs_ with referto
the MaterialSafety DataSheetsfor ttrosJchemicajs.
MEDICAL: TRAIUSPORTATTON
(SPILL}:
Thesenumbersare for r-80o-752-786s
(usA) 1-800-468-1760(USA)
emergency only. lf
use Extensaon2
you desire non-emergency
injorrnationabout this 1-312-942.596e
(CANADAI 1.613-se6鈧?666 (CANADA)
product pleasecall a
lelephonenumberlisted
MANUFACTURERTSUPPLTER:
Safety-Kteen Corp.
1@0 NorthRandbll Roao
Elgin,lL, 60123-7ES7USA
1-800-669-5740
TECHNIGAL
rNFoRf,rATrot{: -900-669-9740
r Extensbn 7s00
MsDs FORMNUMBER:92659{atso
formerty
826sr) tssuE: April4,1997
ORIGINAL
ISSUE:
JanuaryZO,
1995 SUPERSEDES: $eptember 1996
18.
PREPARED Product
BY: MSDSCoordinator APPROVED MSDS
By: TaskForce
FormNo.92658 page1 of 9
-
Revision
04/97;
MSDS
SAFEW-KLEEN PREMIUM GOLDSOLVENT
IIATERIALSAFETYDATA SHEETFORUSA AND CANADA
sECTloN 2: COMPOSITION/INFORMAT|ON TNGREDTENTS
ON
OSHAFEL ACGIHTTV
Wr% NAME CASNo.
SY{OtVrti TWA STEL TWA STEL @a Ld
t@ Didlates(petoteum), Niv. a74247-E 500c tS@Od >a1OO
N:{v. NAv,
l00c
hydr鈧瑃eded tiffr ppm ppm mglm3l
4 holrs
cBaseo soddardSoNern.
NAv. = NdA\rdable m
aor*nat tHO imdkc) dskin-RdLD5D200omslkg
bhhdafion-R* LC50
see 29 cFR 1910.100qdx2) ACGIHTresfroit Limilvatues chemicatS.rfr;tances ptttsicdt
and {d aM Agen9 aiabgicatExpasure/rdiresbooklet
(Appendx ftr trteddermindion expo$re limtts mixtJres.
c) of for con$dtan indusfiial
hygienis6r sfniiarprrofessiorul cmfrm mattfie calqJlated
to
expGure Imrtsareappropriate.
SECTION HAZARDS
3: |DENT|F|CAT|ON
Y
WARNING!
APPEARANCE
Liquid,clear,colorless paleyellow,mildhydrocarbon
to odor.
IMMEDIATE HAZARDS
Combustible liquid and vapor.
Harmful inhaled-
if
Eye and skin initant.
May be harnrfulif swaflowed.
DELAYEDHAZARDS
Containsmaterial wttp!_qy cause centralnervous
POTENTIALHEALTHEFFECTS
INHALATION Hiohvaporor mist concenrations
mgy..bg
harmfuf
if.inhaled.
High
{BREATHING):
coicentrations
Jiv;il;;t mist iriitaie resprrarory (nose,
may tire tract throat,
andlungs)..H.igh
concentrations-of \鈧琾oror mtstfflaycause
vomiting. concentrationsvapo'r mistmaycause nausea and
High of or headaches,
dizziness,incoordjnation,
numbneii,irreg'ul;i ro""i, ;;;iir;; central
n"
nervous systemefiects.Massiveacute oierexposure result rapid
may in
centralnervous systemdepression,suooen'Coilifse,d;i death.
"-oH,'"no
EYES: Direct
contact withrnateriafs exposure vapors
or to maycauseirritation.
SKIN: Direct
contact materials. exp.osure vaporsmaycauseirritation.
with or to A
prolonged
single, exposure notiikely cause rnaterial be absorbed
is ' to the to
through skinin harnrful
the amounts.
lNGEsTfoN May caus-e
throatirritation,
nau-se-a,
vomiting,
and
centralnervous
{swAtlottutNG}:
sysielngffects
asnoieu
und;lnHilli?rbnrq3enrHtpc}. Breathins
material the lungs
into duringingestion voriiting;;y ;,j;rjung
or inj;ry
and possible death.
FormNo.g2659- page2 of 9
Revision
04/97; MSDS
SAFEW.KLEENPREMIUM GOLDSOLVENT
MATERIALSAFETYDATA SI{EETFORUSA AND CANADA
MEDIGAL
CONDITIONSlndividuals
wit!nrecxjsting.lung,
cardiac,
central nervous system,
AGGRAVATEDBY or skindisorderd haveincr6irseo
may sui.pti-uilityii-tn"effects
EXPOSURE: of exposure.
CHRONIC: Prolonged repeated
or toxiceffects.prolonged
inhalation cause
may or
repeeted contact
eye maycauseinflammation the membranJ
of ii;ing the
*y"li1r.?.1,9_*I_11T9-9"_-"L^!-"]t o.r
..proronged repeated contact rnay
cause dryrng,cracking,
redness,itching,
svrlelling,.6l "Nn
burns.
CANCER No knowncarcinoqenicity. rnoreinforrnation, SECTION
For see 11:
INFoRMATION: CARctNOGENcfiV-
Also see SECTION15: CAL|FORN|A.
SECTION FIRST tttEASUREs
{: AtD
INHALATION: Remove freshair- rf
to giveartificiar
respiration.
rf
oxygen-_.someone staywithviciiml-'oet breathing
is,.difficult,-give ":ly:3llilg,s}o-ulo
{BREATHTNG)
medical
attention breathing
if difficulty
persists.
EYES: Fordirectcontact, imn,ediateryJ,.u:.n with.prenty water,
-lf of hording
_gv""
eyelidsapart, 15 minutes. initatidn r9d.ie_ss
for or ig"rn to vapor
or.mistdeverops. mol/_e_ayuayexposure tiJsrr-iii.6& medical
fro.m ' into "*p,i"ure
attention irritation painpersists.
if or
SKIN: Remove contaminateddothing.gnd.shoeg. skin
soapandwater.Germedicarinenrionirrih-tion';; thoroughry wfth
.lAhsh
if iii,iiiJ[Ltr.
INGESTION: lmmediately medical
get attention. Nor induce
Do vomitinq. lf
(SwALLOWtNG) spontaneous vomiting
occurs,keepheadueuwr,ips;;';;id breathing
material the lungs,
into
NOTETO Nospecific antidote
avairabre.
Treat symptomrqtica.rlv
andsupportivefy.
PHYSICIAhIS: Administrationgastric
of tav.agj,_if
warijnieo,
should
ueperrrjrineo
oy
quaIifiedredicalperso
nne.l.
ball rneciciiemergency ptro number
tere rie
(seeSECT|oil1)for additionalinformalion.
SECTION FIREF|GHTING
5: MEASURES
FLASHPOINT: 148"F(64'C)TagClosed (minimum)
Cup
FLAMMABLELIII,IITS AIR:
IN LOWER: VOLo,6
0.5 {minimum}
UPFER: VOL%
9.3 lmaximumi
AUTOIGNITION
TEMPERATURE: (227'Q\(minimum)
44ooF
HAZARDOUSCOilIBUSTION
PRODUCTS: Burning produce
rnay carbon
monoxide.
coNDtnoils
oF
FLAMMABILITY: Heat,
sparks, flame.
or
Revision
04/97;MSDSFormNo.8265e page3 of 9
_
SAFEW-KLEENPREMIUM GOLDSOLVENT
MATERIALSAFETVDATA SHEETFORUSA AND CANADA
EXflNGUISHING Carbon
MEDIA: dioxide,
foam, chemical,
dry uaterspray, \4ater
or
fog.
NFPA 704
HAZARD This infornationis intendedsolelyfor the use by individuals
IDENTIFICATION: trainedin thissystem.
HEALTHIIAZARD HFEnrZmo
Gu,E) (FED)
SPECNFIC
REACfrv|TY
\-
FIAZARD
0Erofl)
$ffirq
FIREFIGHTING Keep.storage containers coolwih waterspray.
INSTRUCTTONS: Positive-pressure, nta
serf-co ineuureatrringppa
a ratus(sc BA)
andstructu | firefiohte protective-
ra - rs' cloii,ngrnayprovide
protection.
limited
FIREAND and
Fjcomposition combustion producis maybetoxic.
'Emptv"
EXPLOSIONHAZARDS: containers rerain
mav idlilll ai'J iiri6.Gig"rour.
Heated oontainers rupture Vapors
mgV can
source flashback.Vipor exptoilon traveltoignition
and hazard indoors,
outdoors, in sevrers,.
or Run-otrt6iJ*r'm"V create - or
fire
hazard. ot.sensitive mecliiana irpu"i.' -'
expfosion N to r
Material besensitive it"fi" ii!"-fr#ge, which
may to could
result fireor explosion.
in
EMERGENCV RESPOSISE 128
GUIDENUITIBER: Reference
NorthAmerican
Emergency
Respons Guidebook
e
SECTION AGCTDENTAL
6: Rm
Remove isnition
ail sources- nottouch^or
Do wat[ht:g! :p,.lJg{g49riar. stop reak you
if
cando it wfthout wear protective
risk. equrpmentspeciriEo srcnoru 8: EXposuRE
in
coNTRoLvPERSoNAL Phoriditdil' V"ntirat"-"*i-Jnia.voio bre-athing
vaporor mist.A
vaporsuppressing maybeused reoucJ'vil;;. c;;drn
foam to a\f,rayfrom
surhcewaters
sewers'contain a liquid possible and
as for recovery sorbwithcompatibte
or sorbent
shovel material
witha crean, and
non-sparkirig intosearabrc.conl"ini, disposar.
io;r to,'
Additionafly, farge
for spiilr: isorate
hazard-a.rea.. unnecessary unprotec,ted
Keep and
personnel entering.
from Dikefar aheadolticrii iiitiioi andtateidisposat.
"JTrlcion
Revsion FormNo.g265e page4 of 9
04/97;MSDS _
SAFEW-KLEENPREMIUM GOLDSOLVENT
MATERIALSAFETYDATA SHEETFORUSA AND CANADA
SECTIOII7: HANDLINGAND STORAGE
HANDLING: Keepavrayfrom heat,sparks,or flame. lMrere explosive
mixtures
b."preserrt,
equjpment for
Tgyctean,non-sparking safe such
locations
snouto used.
ne
toolsand explosion-proof
equiprnent.
,use
yvne rranste
n rnngmate l, meta containers,'includiris cks and
ria I tru
tank cars,shouldbe grounded and bonded.A6id;;;d"tGr,
eyes., crothing, shoes. inueitventJutJi'iiri.'bL
skin, and use nor
breathe
vapor mist.
or
SHIPPING
AND Keep oontainer tighdycrosedwhennotin
use.and during transport.
Dop.t pressurize,wetd,
STORING: cut, braee,
soiier,iriiii;J,il;,.o;;;ilr"
containers heat,
to frame,sparks,
siatic r[ur"",
gf ignition;
containers 6xptod" "t""lriciti,;;d;
may JnJ i,iiit ;;;;ur'
produdcontainer_s retain "ar.erediarie-ano
may product
Fmptv *'n o"
seesECTroN TRArusponr
li:
{anggrous. rnFbhnnnirbirr ror
Packing Group information.
PERSONAL use good.personarhy-giene. thoroughry soapandwater
with
afterhandring bei6re .lffash '
HYGIEIIE: and eating,uriiir
isiil
prod - clean conta minateiiotring, "shoes, proteJive
ucts o aid
equipment before
reu_s-q:
Discardcont?minated dotf,i;;, iiio"*, o.'
'- -'
protective
equipmenttheycannot iirorougnry
if oe creirido.
SECTION EXPOSURE
8: CONTROLffi
ENGINEERING Providege!'gqarventiration
neededto rnaintain concentration of
CONTROLS: vapor mistbetow
or appticabte
p*poiur" ri'mt.Whilff#Ji;"
generalventilation unavairabre,'use
is piocess
-contro
encrosures, rocal
exha ventilatio of
ust n. _oth",,' giil; ririg
;n rsto contro| irborne
a
levets
betow recommended exfrsureliirit. Wh;;;6ft;;"'
p_rxture: be present,
rnay equii'mlniraiJtor suchrocations shourd
be used.
PERSONAL
PROTECTIVE
EQUIPMENT
RESPIRATORY Use NIOSH/MsHA-alplgved.respiratory protectiveequipme when
nt
PROTECTION: concentation ofvapor mist
or elbeggs lfpiiJi,diiliil",l",ilJiii"it.
n
setf-co in d brealhg-apa
nta e in p ratus -oi ;il ii,G'rJt;fi;
(SciiXi
esuipme arereoire-d rs" sprJGrilJ ; ;;E 5;;;:" "
nt u foli?
selectionand usaof respiratoiT
protective
equipment shourd in
be
accordance USA osFiA
inrhe with c6;;irffi;i,y stiiio?Li
29 CFR 191A.84:or in CanadawitfiCsn Sbndard 1g4.4-MtgAZ.
EVE lMre.re eye contactislikely,u,earchemicalgoggles;
contactlens
PROTECTION: use is not recommended.'
SK|il lMrere skin contactis likely,wear nitrile,
Viton@, equivalent
or
PROTECTION: protectivegloves;use of.b-utyrrubber,niturat r"bb;r, ;;' ;;iiu" r"nt
glovesis not recommended.-
Revision
04/97; MSDSFormNo.92659- page5 of g
SAFEW-KLEENPREMIUM GOLDSOLVENT
MATERIALSAFETYDATA SHEETFORUSA AND CANADA
OTHER trp.rg spillsand splashes likely,wearappropriate
are
PROTECTIVE chemical-resistantboots,apron,or otherploi6cti'ire
cfothino.
EQUIPMENT: clean watershoufdbe availabre urork
in ireas ror flus-h-i-ngih"
and skin. "y""
SECTION PHYSIGAL CHEMTCAL
pROpERTtEs
9: AND
PHYSICALSTATE,
APPEARANCE,AND ODOR: Liquid,
clear,cororress pareyeilow,mirdhydrocarbon
to odor.
ODORTHRESHOLD: 30 ppm (basedon StoddardSolvent)
SPECIFICGRAUIW: 0.78to 0.8260"F/60.F (1S.6"C11S.6"CI =
(water 1)
DEhISITY: 6.5 to 6.8lblU$ gat (780to e2Og/t)
VAPORDENSITY: 5 (air = 1) approximately
VAPORPRESSURE: *r
9.? Hsat6E"F
(2!l!)(annroximatety)
0.6 Hsat100.F
mm (38"ciiii;pioiimiiJVl
BOILINGPOINT: 350'F (177"C,(iniliat)
pOtNT:
FREEZING/|IIELT|NG lessthan-45"F (-43"C)
PH: Notapplicable.
EVAPORATIONRATE: 0.1 (butylacetate 1)
=
SOLUBILITY WATER:
IN Insoluble.
MOLECULARIITIEIGHT: 160 (approximately)
SECTION STABIL|TY
10: ANDnenCrtVrrV
Stableunder norma temperatures pressures.
I and
Avoidheat,sparks,or flame.
INCOI'IPATIBILITY: Avoi{ acids,atkalies.
oxjdizing
agents,reducing
agents, reaetive
or halogens.
REACTIVITY: Polymerization not knownto occurunder
is normaf
temperatures pressures.
and Not;";#;; wfthwater.
!Il,44RDoUs DEcolrtpostTtoN N.o e_g$91_nrmaI temE> res and pressures.
n o ra_t!
PRODUCTS: See
{9o_ c_noN HnzAdDdUi-coft
s:
!! Etisrlor
PRODUCTS.
SECT|OTUTOXtCOT_OCrcer_
1I : rruroEinATpil
Based bestcurrent
on information, is noknown
there human
sensitization
associated tresemalerials.
wtth
'Revision
04/97;MSDSFormNo.g265g page6 of 9
-
SAFETY.KLEEN PREMIUM GOLDSOLVENT
IilATERIALSAFETYDATA SHEETFORUSA AND CANADA
CARCINOGENICITY: IARCclassifies dremicalsbytheir carcinogenicrisk,including
agentsthatare known,probable, possible
or carcinoqens. Nip
classifreschemicals eitherknown.carcinogens,
as orior whichthere
is limitedevidence carcinogenicity huminJ or sumcient
of in
evidenceof carcinogenicity experimental
in -ca aninats.ACoFr
recognizes severa categories
I of rcinogens, ind uain.q confirrne
o
hurnancarcinogens suspected
and hurna-n
caicinogeni.
Basedon bestqrrrent inforrmtion,
there is no knoyrrn
carcinogenicity
associated
wfththese materials.
Also see SECnOil 15: CAL|FORNUI.
REPRODUCTIUE Basedon bestcurent infornmtion, there is no knownreproductive
TOXICITY: toxicityassociatedwith these materials.
Also see SECTIOI|15: CALIFORN|A.
TERAToGENICITY: Based bestc.urrent
on infornution,
thereis noknown
teratogenicity
associated thesematerials-
with
MUTAGENIGITY: Basedon bestcurrentinformation,
thereis no knownmutagenicity
associated
withthese materiafs.
ToxlcoLoGlcALLY Based bestcurrent
on inforrnation, are no known
there
sYStlERclsrtc toxicologicallysynergisticproou#associatedwiththese
'
PRODUCT(S): materiaii.
SECTION EGOLOGTCAL
12: WfOnlrtnflont
A Static
AcuteBioassay perthe
as
FishandGane\lvpcl, wis-do;; carifornia Department
of
andupto 250ppmof the proOuctsl;,,Ai;r.
";il;;iiiaJ;l;;;;d,-'
Thermterial pas5e{ bioassay onty
the with
minnornes Tofaitthebioas&v,*i"if,,, 1 outdi,10
of
iyjng. n- o:t
tn"
fishwould in 250ppm.
die
OCTANOLfWATER
PARTITION
COEFFICIENT: Not available.
UOLATILEORGANIC 6.5
lF.W.f"rO; to 6.8tb/US j Z8-0 820gtl
gal;
Photoch micalty reactiveI s"p r'qb-ro il-Faii's 1
COUTPOUNDS: e c'e .100(s).
sEcTtoN3: DtsposRl
1 consloeRFrpns
Dispose accordance federar,
in with provinciar, rocal
state, and
regulation.s...
Rgguration_s arsoiffiio *.pty containers.
rnay The
respo
nibilfu f91proRerwasie dispoili'rilswithirrJownei'J'itn"
waste'contact safety-Kreenregaioin!recvcring ;ipr;il; iisposar.
Revision
04/97; MSDSFormNo.g2658 page7 of 9
_
SAFEW-KLEENPREMIUM GOLDSOLVENT
MATERIALSAFETYDATA SHEETFORUSA AND CANADA
Not regulated.'
USEPAWASTE
coDE(s): Basedon available data,this information
appliesto the materialas
qupplied the user-Processing, or contamination -'' make
to use, rnay--'
this informationinappropriate,inaccuiate, incomplete.
or
SECTION14: TRANSPORT
INFORIU|AT|ON
CoMBUST|BLE LtOUtD,
N.O.S.
(PETROLEUM
NAPHTHA),
NA1993,PGTII
Not regulated.
SECTK)iI REGULATORY
15: TNFORMATTON
USA REGULATIONS
SARA SECTIONS p9_sq foilowing
Materials q1e physicar hearth
and hazards
as
311AND 312: defined 40cFR e.1t-3fQa1C subject itrJiEquirernents
in are to or
sections and312of_Tifle of thesuperrunoam'ena#ents
311 III ano
Reauthorization of 1986:
Act
lmmediate(Acute)
HealthHazard
(Chronic)
Delayed HealthHazard
FireHazard
SARASEGTION
313: products notcontain
These do toxicchemicalssubiect the
to - '-
r-equirements
of section of Titte of thJ Supehund-
313 III
Anrendnents Reauthorization or tgs6 Jid qo crn part372.
and Act
TSGA: Alftheoomponenb these products listed theTscA
of are on
lnventory.
CALIFORNIA: rmy contain detectable
Il":: prglqctg a amount benzene
of
cAS 71-43-2.Thismateriat tisted thestite-;ib;iii;;;
is by u"
known carcinogen. "
our testing tfrgse
of productsindicates thiscompound not
that is
allgv.sdetectable.
However, whendetected, u",ir.nJriuet is at
the - - --'
or below product
the specificatio O,aigti.
n ot
These.pro.ducts go_nlain
rnay a detectabfe
amount
of
p-drcnrorobenzene 1864&7.Thismaterialis
cAg listedbythe
State Califomia a known
of as carcinogen.
products
indicates ttriscompound not
that is
9.111:^.tlg 9ll$r". r'rowever,
oeredabre. whendeteded, p-dichlorobenzene
3N\qys the
levelis at or below mg/|.
7-S
It.:qpp9^u$11rgvcontain detectabte
a amount totuene
of
cAS l0&86-3.Thismaterial listed thestateof datirornia
is by us
knovwr cause
to reproductive
toxicig.
MSDSFormNo.82658 page8 of9
-
GOLDSOLVENT
PREMIUM
SAFETY.KLEEN
DATA SHEETFORUSA AND CANADA
MATERIALSAFETY
Ourtesting theseproducts
of indicates thiscompound not
that is
However, detected, totuene isar
when the tevet
lffifj?,Sff.ge-
CANADIANREGULATIONS
Theseproductshavebeen classifted accordance
in withthe hazardcriteriaof the Controlled
(CPR)and the MSDScontainsallthe information
Products
Regulations requiredby the CpR.
WHMIS: 83, D2B
CANADIAN
ENUIROruMENTAL
PROTECTIONACT All the oomponents theseproducts listedon the canadian
of are
(CEPA): DomesticSubsta nces List.
SECTION16: OTHERINFORMATTON
REVISIOI{llrlFOR[|!AT|ON Newforrmt.
:
LABEUOTI{ERINFORMATbN:
I!""." products Underwriters
are Laboratories
(UL)
listed.
User assunes all ridts ircident to the use ofthis prod;d. To lhe bed ofqr knowledge,ttre rrfcnnlion containcd
herein is accurate. Ftcrvs\,鈧瑀,
saEtrKleen assumes ng liabilitywhdsos/er for he acolraq/ or c$rpldeness af the iqffination cor[ained
herein.No represenft*ifis or warardes.
dk exDPssed or imDlid. or memhantahilltv. fuss fd a particular Eulpose 6 of anv offi6 ndure are made hereunderuith resoed
lo infrxmatqo
or the orodud to wtrich informalion refus. The data oontainedon thb sheet apply to tfrc m*erid as suppliedb
the ustr.
otggz Printed the usA.
in
"Revision FormNo.3265S pageg of 9
-
04t/97;
MSOS
|