2/20/96
rssuED
1OO1 TROUT BROOK CROSSING
CORPORATION
LOCTITE 41212
o6067-39 10
ROCKY Hr LL, cr
(86O) 571-5465
(860) FAX:
571-sloO
E M E R G E N C YF g o t t E :
4
UALEBIAL_!At.Er Y-D A1 A-s HgEI
1 of
Page
q-9.9U ANy.-tqENIte!c AI'J.SN
P
1:---c HEULgA!-eB99,ggL-AN
GR TBlCD
82191 PX SUPRGL GEL 2
Name:
Pnoduct
82191
:
Item No.
8219 '|
Pant No. :
ester
Cyanoacryl ate
Type:
Product
o Mgql!I.J.qN4-I NFo RMAL!qN-9.!-l!9BEq!E Nr s
2:--_c
af
CAS NO. to
Ingredients
85-90
7085-85-O
cyanoacrY I ate
Ethy'l gr'J.11-14-7 5-10
(rn6ttryt m6thacrYlate)
Fotl
5-10
112945-52-5
A M O R P H O U ST R E A T E D
SILTCA,
o.1-O.5
123-31-9
HYDROQU NONE
I
l im'i ts
exposune
have
which
Ingredients
OTHER
OS H A
ACGIH
(TWA)
Limits
Exposure
(rLv) (PEL)
I ngned i ents
2 ppm TWA
None
None
ate
Ethy l cyanoacryl 9. 1 mg,/m3
3 mglm3 TWA
mg,/m3 TWA
6
I O mg,/m3 TUA
A M O R P H O U ST R E A T E D
SILICA, dust
resp.
2 mglm3 Tt{,A
mg,/m3 TWA
2
TIJA
ng/n3
2
HYDROQU NONE
I 4 ng/n3 STEL
OSHA
ACGIH
(STEL)
Llmits
Exposure (PEL)
(TLV)
Ingredients
(t ppm)
(q ppm )
cyanoacrYlate
Ethyt (16 mglm3)
( 1 8 m g , / m g)
3 . ___HAzABgs-I gE!L!E !g.AL I 9.N
roxicity: ;b;!, "311i":"8?L;":;:3ti!i;,".
lFritant.
and eye
Skin
5ooo mg per k9.-
LDSo more than
6nat
EJtimatea
2OOO mg per kg.
LDSO none than
dermal
Estimated
None known
Routes of EntrY:
Primary
and symPtoms
Signs
to eyes and mucous membranes
iFritating
Vapon is
of Exposune: to
overexposure
and repeated
Prolonged
abbve TLV.
of non-al lergic
may produce-sympto4s.
vapors
indivicluals-
in sensitive
asthma
Conditions
Existing
None known
by ExPosure:
Aggravated
cancinggel.
L i t e r a t u n O " g a .R e f e r e n c e d
-e r
NTP IARC OSHA
Effects
Heal th
and Other
Tanget
Ingredients
NO
NO NO
RES
ALG IRR
cyanoacnyl ate
Ethyl N/A No
No
IRR
(metnyr t"if;jl.ylq!9)
Poly NO
N/A
No
NuI
sr LrcA, AMoRPHoU!-iniaieo- NO
N/A
NO
MUT SKI
ELO ENU CI.IS EYE IMM IRR
HYDROQUINONE
Abbreviations
A 1I ergen
ALG
Not Appl i cabl e
N/A
Bone Marrow
BNM
B I ood
BLO
Ey e s
E.YE
sYstem
nervous
Centna'l
CNS
I rr I tant
IRR
Immune sYstem
IMM
Nu i sance dust
NUI
MUT Mutagen
Skin
SKI
Resp i ratory
RES
MEASURES
4. FIRST AID
page for
See supplemental
I ikely.
is not
Ingestion
Ingestion:
procedures.
emergency
I f symptoms Pens i st '
Remove td f nesh a i r.
Inhalation:
attention.
medica'l
obtain
page for
See supplemental
Soak in warm waten.
Contact:
Skin
ernergency pnoceduFes.
page for
See supplemental
wiin'water.
FlusF
Eye Contact:
emergency Procedunes.
20-1240
PAGE 1 OF 4
,,
2/20/96
rssuED
CORPORATION 1OO1 TROUT BROOK CROSSING
LOCTITE
41:12
ROCKY HILL, CT 06057-391O
s7 1-546s
( 860)
EMERG鈧琋cY PHONE: (86O) 57r-5 FAX:
tOO
M A ER l A t _ s A E Er Y _ q A TA _ E H E r
T E Page of 4
2
Product 82191
Name: PX SUPRGL GEL 2 TBICD
cR
Item No.: 82191
MEASURES
5. FIRE FIGHTING
15O -
Flash Point: Tag CI osed
2OO F Method: Cup
Re c o m m e n d e d
Agents: Carbon dioxide, chem i ca I
Extinguishing foam, dry
fonmed
Hazardous Pnoducts
by Fine or Thenmal Decomp Irritating onganic vapors
Fire or
Unusual
None
Expl os i on Hazards:
Limits:
Explosive
(% bv volume Not
in air)Lower available
(% oy volume in ain)Upper Not availab'le
RELEASE MEASURES
6. ACCIDENTAL
in
to be taken case
Steps
polymerize
leak: Flood with up wi th an
of spi'll or water to Soak
i nent absorbent.
7- HANDLING AND STORAGE
F
Stone at or belou, 75 deg.
Safe Storage:
(Contact shelf Life infornation)
Customer Service 1-8OO-243-4A74 fo"
Loctite
Avoid and eyes- Avoid breathing
contact u,ith skin
Handf ing:
vapor.
g 3 _ _ _ Ex P o s u B E _ c g N r oL s a _ PE8 s o N A t _ g B q L E g L r N
R o
glasses or goggles.
Eyes: Safety
gloves
or po'lyethylene and aprons.
Nitrile
Skin:
Do not use cotton.
page for additional information.
See supplemental
should be
venti lation
Positive down-draft exhaust
Ventllation:
pnovided below TLV
vapon concentnation
to maintain
Limits.
2 for Exposure
See Section
AND CHEMICAL PROPERTIES
9. PHYSICAL
l r r a t e r h r hi t e g e l
Appearance:
Shanp, irritating
Odor":
More than 3OO F
Boiling Polnt:
Does not app l y
PH:
Polymerized
ity in Water: by water
Solubil
1.05
Gravlty
Specific
Compound
Volati le Organic
gnams per
(EPA Method 83.4%;897 liter
24)
Less than O.2 mm
Vapor Pnessune:
y3
Approximatel
Vapor Dens I ty:
i on Rate
Evaportat
= 1)
(Etner Not available
AND REACTIVITY
1O. STABI LITY
Stable
Stability:
Wl I I not occur
Polynerization:
Hazardous
water, alcohols,
Polymerized by contact with
ity:
Incompattbil
am{nes, alkal ies.
Decomposi t lon
Hazardous
(non-thermal None
Products ):
11 s _ _ r o x l c o L o g r9 A L _ rN F g S u ar o N
Sect i on 3.
See
' r2 : - - E c o L o g l c a t _ I
NEgRMAT!ON
No available
data
CONSIDERATIONS
13. DISPOSAL
of
methods
Recommended
EPA
f ol lowing
Po'lymerize as above, Incinenate
disposal:
and local regulations.
1 4 . _ _ r R A N SP O R r _ I N E O R M A T l e N
DOT (49 CFR 172)
Ground TransPor^t
Domestic
trroper (Not 45O 1 itens);
more than
Unrestricted
Shipping - Namb:
(Cyanoacrylate esten)
I iquids, n.o.s-
Combustible
(More than 45O 1 iters)
PAGE 2 OF 4 20-1240
CORPORATION 1OO1 TROUT BROOK CROSSING
LOCTITE ISSUED 2/20/96
ROCKY HILL, CT 41:12
06067-3910
EMERGENCYPHoNE: (86O) 57r-51oo (860)
FAX: 571-s465
MArERI At_s AF 鈧? r Y_gALA_gEggI Page 3 of 4
Pnoduct Name: 82I91 GR TB/CD
PX SUPRGL GEL 2
Item No. : 82r91
14:__IRANSeSBL_INFoBMAL!qN_______ i nued)
___!cont
Hazard Class on
(Not mone than 45O I itens)
Division: Unrestricted
(Mone than 450 liters)
Combustible liquid 'l
None ( Not mone than 45O
Identif Number :
ication i tens ) ;
NA 1993 (More than 450 I iters)
Mar i ne Po I I utant : None
I ATA
Sh i pp i ng (ttot more than one pint ); .
Propen Name: UnFestrlcted
(Mone than plnt)
Other regulated substances one
(tlot mone than one pint);
Class or Division: Unnestricted
9 (More than one pint)
Class
None (Not mone than one pint)
UN or ID Number:
ID 8O27 (More than one pint)
15:__R gGg!AI9.8Y_!N!9EUAL!9N
CA Proposi pnesent.
t ion 55: No Prop65 chemical s known be
are to
1g:__o r Hg8_J.!E9.BMAIJ.g!
Estimated NFPA(R) Code:
Hea I th Hazard: 2
F i re Hazard: 2
Reactivity Hazard: 2
Spect f ic Hazard: No water
Estimatecl HMIS(R) code:
Heal th Hazard: 2
Flammability Hazard: 2
React i v i ty Haza rds : 2
Personal Pnotect i on: See Section 8.
NFPA ls a registened tnademark of the National Fire Pnotection Assn-
HMIS is a registered tnademark ot the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Envi ronmental Heal th & Safety
Company: Loctlte Corp., lOOl Tr Br Cn, Rocky Hill CT 06067
(860) 57r-sloo
(24hn.) Phone:
Revision Date: 22, 1995
rjanuary Revision: OO2A-
PAGE 3 OF 20-1240
LOCTITE CORPORATION lOOI TROUT BROOK CROSSING I SSUED 2/20/96
ROCKY HI LL, CT 06067-39 10 4 . 1: 1 2
E M E R G E N C YP H O N E : ( 8 6 O ) 5 7 1 - 5 1 O O FAX: (86O) 571-5465
L_SAggLy_qArA_sUE r
E
UAL-EB-LA Page 4 of 4
Product Name: 42191 PX SUPRGL GEL 2 GR TB/CO
I tern No. : 82191
Supp I emen.
INFORMATION FOR FIRST AID AND CASUALTY ON TREATMENT FOR ADHESION OF
HUMAN SKIN TO ITSELF IF CAUSED BY CYANOACRYLATE ADHESIVES
Cyanoacrylate adhesive is a very fast setting and strong adhesive. It
bonds human tissue including skin in .seconds. has shown
Experience
that to cyanoacny'l ates pass i ve,
acci dents due are hand'l ed best by
nonsurglcal flrst aid- Tneatment of specific of accidents are
types
g i ven be I orr.
SKIN CONTACT
Remove excess adhesive. Soak in warm, soapy wi'll
waten- The adhesive
come loose from the skin in sevenal hours. Cured adhesive does not
pnesent .hazard even when bonded to the skin.
a health
Avoid with clothes,
contact fabnics, rags, Contact with
or tissue-
may cause pol:ymerizat'ion.
these The polymerization
materials large
of
generate
amounts will
of adhesive heat skin burns.
causing smoke,
and strong, polyethylene gloves
irritating vapors. Wear nitri le or and
apron when hand'l ing large amounts of adheslve.
SKIN ADHESION
Flrst lmmerse the bonded surfaces i n wanm, soapy water. Peel or rolI
the sunfaces apant urith the aid of a blunt a spatula or a
edge, e.g.
teaspoon handle; then nemove adhesi ve fnom the skln soap and
with
pul I surf aces
r.rater - Do not try to apant opposing
with a dlrect
actlon.
EYELID TO EYELID OR EYEBALL ADHESION
In the event that eyelids are stuck together or bondecl to the eyebal I,
wash thoroughly with wanm water and apply a gauze patch. The eye wi I I
open rrithout further action, typically ln 1-4 days. There will be no
residual damage. Do not try to open the eyes by manlpulat i on.
ADHESIVE ON THE EYEBALL
Cyanoacrylate introduced into the eyes will itse'lf to the
attach
eye proteln periods,
and wi 1 I disassociate fnom it intermlttent
over I
general ly covering wil I cause perlods
several hours. This of weeping I
the peniod
untll is achieved. During
clearance of contamination,
double vlsion may be expenienced together effect,
a lachrymatory
with
and lt is lmportant to undenstand the cause and realize that
disassoclation will normally occun within even with
of hours,
a matter
gnoss contami nat i on -
MOUTH
y stuck together, o f b r a n mw a t e r t o
apply lots
If are accidental'l
llps
and pnessure
m a xl i m u m w e t t l n g f rom sal'lva lnslcle
the I ips and encourage ' ps
pull
apart. Do not try to the lips
the Pee I or ro I I i
mouth .
uith opposing action.
dlrect
It lnpossible to swal low cyanoacrylate.
is almost The adheslve
solldlfles ln the mouth. the adheslve
and adheres lift in
Saliva will
position
one half In case a lump forms
to two days. mouth, the
in the
patlent to prevent ingestion of the lump when it detaches.
B UR N S
glve
Cyanoacrylates off heat on sol idification. In rane cases a large
dr.op will in tempenatune enough to cause
increase a burn.
normally is
Eurns be tneated aften
should the lump of cyanoacrylate
t i ssue as clescr i bed above.
re I eased from the
SURGERY
It be necessany to use method to separate
should never such a drastic
1y bonded skin.
accldental
20-1240
PAGE 4 OF
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