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SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
ryMA-ALDFICH sArNT LOUTS, MTSSOURT 3179, USA 5
ATTN: SAFETYDIRECTOR EM ERGENCY
PHONE 314- 77T - 5755
1-
ST CLOUD STATE UNIV
AS 122 DATE 03/L2/99
720 FOURTH AVE S CUST#:0:-494-7 811
3
SAINT CLOUD MN 55301-4498 PO#: 58252
:i:::::::i::t: :::i::::l PAGE 1
THIS MSDS IS FOR A COMPONENT CATALOG#:
OF 5 2 0 -3 0
SECTION 1. CHEMICAL IDENTIFICATION-
520-200
CATALOG #I
NAME: A.NAPHTHOL 99+I
- COMPOSITION/INFORMATTDN INGREDIENTS
SECTION 2. ON
CAS #: 90-15-3
MF: C10H8O
EC NOz 20I-969-4
SYNONYMS
B A S F U R S O LE R N * C . I . * *
765A5 C . T . O X I D A T I O NB A S E 3 3 DURAFUR
snN-E--rUiino *
pEYEI,o_qEB_D
I FoURAMINE
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* *
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ALPHA-HYDROXYNAPHTHALENEI_HYDROXYNAPHTHALENE NAKO TRg
* AtpHA:NApHrH0r,--*-tERtriAi--EiiN-F-'Unsoil'-ilFr.r sRr.rtc
NAPHTHALENOL
I
I
SETION 3. HAZARDS DENTIFICATION
I
LAEET] PRECAUTI ONARY STATEMENTS
-
TOXI C
TOXIC BY INHALATION, IN CONTACT ITH SKIN AND IF SWALLOWED.
W
C A U S E SS E V E R E I R R I T A T I O N .
READILY ABSORBED HROUGH KIN. T S
T A R Q E TO R G A N ( S ) :
EYES
KIDNEYS
IN CASE OF AqCIDENT OR IF YOU FEEL UNWELL,. EEK MEDICAL ADVICE S
I M M E D I A T E L Y ( S H O WT H E L A B E L W H E R EP O S S I B L E ) .
I N E A S E O F C O N T A C T I T H E Y E S , R I N S E I M M E D I A T E L YW I T H P L E N T Y O F
W
WATER AND SEEK MEDICAL ADVICE.
crovEs ANDEyElFAcE
{EAE_SUtTaEln--pii6TFdrlvif-cidTnrHc,
PROTECTION.
S E C T I O N4 . FIRST-AID MEASURES-
IN qASE QE CONTACT, IMMEDIATSLY FLUSH EYES OR SKIN WITH COPIOUS
AMSqNTS OF.'-WAIEB E'ORAT LEAST 15 MINUTES WHILE REMOVINGEOHTAMTHATNO
C L O T H I N GA N D S H O E S .
FLUSHING rHE EYES SEPARATTNG EyELrDs
oF By rHE
fiif;H*Frft8BRglt"
I F I N H A L E D , R E M O V E O F R E S H A I R . I F N O T B R E A T H I N GG I V E A R T I F I C I A T
T
RESPIRATIoN. IF BREATHINGS DIFFICULT, GIVE oxYGEN.
I
-QUT MQUTHWITH WATERPROVIDED PERSONIS CONSCIOUS.
IF SWALIOIIED._WASLI
CALL A PHYSICIAN IMMEDIATELY.
WASH CONTAMINATEDCLOTHING BEFORE REUSE.
S E C T I O N5 . FIRE FIGHTING MEASURES
CONTINUED ON NEXT PAGE
4855
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are Committed t o the S uccess of our Customers through Scienc e, TechnoLogl and Service.
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SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
S A I N T L O U I S , M T S S O U R I5 3 1 7 8 , U S A
CUST#: 0-494-7 38I1
PO#: 68252
PAGE
DATA SHEET
MATERIAL SAFETY
524-34
T H I S M S D S I S F O R A COMPONENT CATALOG #t
OF
5?0-200
CATALOG#:
A-NAFHTHOL 99+Z
NAME:
E X T I N G U I S H I N GM E D I A
WATERSPRAY.
CARBONDIOXIDE, DRY CHEMTCALPOWDER FOAM.
OR APPROPRTATE
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF_CONTAINED BREATHING APPARATUSAND PROTECTIVE CLOTHING TO
PREVENTCONTACTWITH SKIN AND EYES.
UNUSUALFIRE AND EXPLOSIONSHAZARDS
E M I T S T O X I C F U M E SU N D E RF I R E C O N D I T I O N S .
-l'' ACCIDENTAL RELEASE MEASURES-
SECTION 5.
EVACUATEAREA.
wEaB-SELF-_C_ONTATNED
BREATHTNGAPPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES
UF,_gLIeg--lN A BAGANDHoLDFoR wASrEDrsposAl.
$WqgP
AVOID RAISING DUST.
V E N T I L A T E A R E A A N D W A S HS P I L L S I T E A F T E R M A T E R I A L P I C K U P I S C O M P L E T E .
- H A N D L I N GA N D S T O R A G E -
SECTION 7.
. .. :
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PROTECTION- *
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SECTION8. EXPOSURECONTROLS,/PENSON*L
zusHe-eppRovED REspIRAToR, cHEMIcAL-REsISTANT
WEARAPPROPRIATENIOSHz
GLOVES. SAFETY GOGGLES', OTHER PROTECTIVE CLOTHING.
S A F E T Y ' S H O W EA N D E Y E B A T H .
R
USE ONLY IN A CHEMICAL FUME HOOD.
DO NOT BREATHEDUST. .
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
AVOID PROLONGED REPEATED, OR, EXPOSURE.
READILY ABSORBED HROUGH KIN. T S
WASHTHOROUGHLY AFTER HANDLING.
S E V E R EI R R I T A N T .
TOXIC .
-
KEEP TIGHTLY CLOSED.
PLAcE.
sTOne-
iH--A-eodl-DRY
PHYSICAL AND CHEMICALPROPERTIES
SECTION 9.
APPEARANCE AND ODOR
S O L ID .
PHYSICAL PROPERTIES
BOILING POINTz 278 C TO 280 C
MELTING POINTI 95 C TO 95 C
E X P L O S I O } IL I M I T S I N A I R :
-
53
0.83
CONTINUED NEXT PAGE
ON
4 85 5
SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
ryMA-ALDFIc:H s A r N T L O U I S , M I S S O U R T5 3 1 7 9 , U S A
C U S T # : 0 - 4 9 4 - 73 8 1 1
PO#: 68252
DATA
MATERIAL SHEET PAGE
SAFETY
THrs MsDs ron i Eor'rpoHiHr
rs or-careioc *r- 5 2 0 -3 0
C A T A L O G: " 520-200
#
NAME: A-NAPHTHOL 99+Z
A UT O I G N I T I ON E MP E R A T U R E :
T 1007 F 54lC
vAPoR PRES9UBE! U4_{ 94-c
V A P O RD E N S I T Y : 4.5 G I20 C
S E C T I O N1 0 .
rr:
rNcoMPATr
BrlrrrEs
STRONGOXIDI ZING AGENfS
STRONGBASES
le to--dH[6Ftbes
ACID ANHYDRIDES
HALOGENS
-r,icHT--sEHSiiIve
AIR SENSITIVE
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HAZARDQUS CQT4BUSTTON DECOMPOSTTTON
OR PRODUCTS
TOXIC FT]MESOF:
eAnBON-
MclnOxiDE, DroxrDE
cARBoN
snroN 11. -
*HIH"FEi"lFtrwALLowED
, r NHALED AB''RBED
rHRoucH N.
. oR sKr
C A U S E SS E V E R E I R R I T A T I O N .
HtGu-eoNenntnefiONS
ARE-
ExtneMELyDESTRUcTTvE rrssuEs oF rHE Mucous
To
MEMBRANES AND UPPER RESPIRATORYTRACT. EYES AND SKIN.
SYMPTOMS EXPOSURE MAY INCLT'DE BURNING SENSATION, COUGHING,
OF
!{!-E-EZINq, LARYNGTTIS, SHORTNESS OF BREATH, HEADACHE, NAUSEAAND
VOMITING.
rAnGsT ncaN(s):
O
EYES
LIVER. KIDNEYS
Biodit
THE CHEMICAL,pHysrcAt,, AND
To-iHe BEST oF ouR KNowLEDGE,
TOXICOLOGICAL PROPERTIESHAVE NOT BEENTHOROUGHLY INVESTIGATED.
R T E C S# : O L 2 8 0 0 0 0 0
I-NAPHTHOL
IRRITATION DATA
BroFx* 25-,4/L973
SKN-RBT 5OO MG/24H SEV
ucDs** rL/Lo/t964
S K N - R B T 5 5 0 M G ' O P E NM O D
ucDs** rr'/t0'/r964
EYE-RBT 1 MG SEV
TOXICITY DATA
O R L --R A T L D 8 8 51 8 7 0 M c / K c
50: TSCAT*
FYr OTS-0 - 0443
IHL-RAT LC50 t>420 MG./|"I3/IH BIOFX* 25-4/t973
I P R - R A T L D 5 OI 2 5 O M G / K G TSCAT*
'
FYr-OTS-0885-0443
GI SAAA 3 0 ( 9 ) . 2 2 . 1 9 5 s
ORL-MUS LD50 2275 MGIKG
GI SAAA 3 0 ( 9 ) ' , 2 2 ; 1 9 5 5
O R L - C A TL D 5 O : 1 3 4 M G 7 K G
CONTINUED ON NEXT PAGE
4857
We are Committed to the Success of our Customers Science, Technolo gy and Serlice,
through
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SIGMA CHEMICAL COMPANY
POSTOFFICE BOX 14508
sArNT LOUTS, MTSSOURT3178, USA
6
CUST# 0-494-7 3811
!
PO#! 68252
Y 4
MATERIAL DATA SHEET PAGE
SAFET
THIS MSDS IS FOR A COMPONENT 520-30
OF CATALOG #t
CATALOG #: 520-20A
ee+z
p"FMlFG,,.^o-*o""rHoL GII H A A P 3 0 ( 9 ) , 2 2 , 1 9 5 5
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S K N - R B T i*=n
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O R L - G P GL D 5 0 : 2 G M I K G
TARGET ORGAN DATA
E F F E C T SO N F E R T I L I T Y ( L I T T E R S I Z E )
EFFECTS ON EMBRYOOR FETUS (FETOTOX rf,,y)
ONLY SELECTED REGISTRY OF TOXIC EFF TS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE L ENTRY IN RTECS FOR
COMPLETEINFORMATION.
; E
SECTION 12. BOOLOGTCAL INFORMATION
.]..
DATA NOT YET AVAILABLEo
SECTION 13.
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBTESOLVENTAND BURN IN
CHEMICAL INCINERATOR EOUIPPED WITH AN AFTERBURNERAND SCRUBBER.
OBSERVEALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
;
SECTION 14. TRANSPORT INFORMATXON
CONTACTSIGMA CHEMICAL COMPANYFOR TRANSPORTATION
INFORMATION.
SECTION 15. REGULATORY
INFORMATION
EUROPEANINFORMATION
EC INDEX NOI 604-029-00-5
TOXI C
R 2t/22
rN CONTACTWrTH SKrN AND rF SWALLOWED.
HABUqLTL
R 3 7/ 3 8
T R B I t A f T N G T o R E S p T R A T o R ys y s r g M A N D s K r N .
R41
RISK OF SERIOUS DAMAGETO EYES
s22
DO NOT BREATHE DUST.
s25
I N C A S E O F C O N T A C T I T H E Y E S , R I N S E I M M E D I A T E L YW I T H P L E N T Y O F
W
AND SEEK MEDICAL ADVICE.
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REVIEWS, STANDARDS, AND REGULATIONS
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L - R U S S I A : S T E L 0 . 5 M G , / M 3J A N 1 9 9 3
HS I974t HZD 8L592; NIS 20t TNF 1281; NOS 28: TNE 12938
E S 1 9 8 3 r H Z D 8 L 6 9 2 i N I S 7 ; ' T N F 5 4 9 7 ; ' N O S 2 4 ; ' T N E 5 7 2 5 5': T F E 4 3 2 4 8
, NEGATI : N' CRASSA-ANEUPLOI
VE DY; HI STI DI NE
A".QE$$TQX_ _P-BQGBAI_{_198I
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SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
ryMA-ALDFllcH sArNT LOUTS, MTSSOURT 3178, USA 6
CUST#: 0-494'7 3811
PO#: 68252
M ATERIAL DATA
SAFETY SHEET PAGE 5
T H I S M S D S I S F O R A coMPoNENTOF CATALOG 5 2 0 - 30
#:
520-2oO
CATALOG #:
A-NAPHTHOL
NAME: 99+Z
- O T H E RI N F O R M A T I O N -
SECTION 16.
THE ABOVE INFOR}IATION IS BELIEVED TO BE CORRECTBUT DOES NOT PURPORTTO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA SHALL NOT BE
HELD LIABLE FOR ANY DAMAGERESULTING FROM HANDLING OR FROM CONTACTWITH
T H E A B O V E P R O D U C T .S E E R E V E R S ES I D E O F : ] N V O I C E O R P A C K I N G S L I P F O R
A D D I T I O N A L T E R M SA N D C O N D I T I O N SO F S A L E .
C O P Y R I G H T1 9 9 8 S I G M A - A I D R I C H C O .
LICENSE GRANTEDTO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
MATERIAL WAS SHIPPED TO THIS ADDRESS:
ST CLOUD STATE UNIV
RECEIVINGDEPT
MAINTENANCEBLDG
2IT IITH ST S
SAINT CLOUD MN 56301
4 85 9
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are Committed. to the Srccess of Customers Science, Technology and
our throzgh Seruice.
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