Helena Chemical Company 06-JUN-2002 08:41:52
PH: 901-761-0050 Page 1 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-JAN-2000
Product: PRO-MATE PINE PLUS
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I. IDENTIFICATION
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Chemical Name: D'LIMONENE, SURFACTANTS, EMULSIFIERS.
Chemical Family: ADJUVANT
Formula: NOT APPLICABLE, FORMULATED MIXTURE.
Synonyms: NONE
CAS Number: NOT APPLICABLE, FORMULATED MIXTURE.
EPA Number: NOT APPLICABLE
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II. PHYSICAL DATA
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Boiling Point: NOT AVAILABLE
Freezing Point: <40 DEGREES F.
Spec Gravity: 0.899 GMS/CC.
Vapor Pressure: <2 MM HG @ 20 C.
Vapor Density: <1
Solubility: DISPERSIBLE
Volatiles: NOT AVAILABLE
Evaporation: NOT AVAILABLE
Melting Point: NOT APPLICABLE
Appearance: AMBER LIQUID, PINE ODOR
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III. INGREDIENTS
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Material CAS Number Percent TLV Hazard
--------------------------- ----------- ------- ------- ---------------
PROPRIETARY BLEND OF 100.00 NOT MILD SKIN & EYE
D'LIMONENE, SURFACTANTS AND ESTABLI IRRITANT
NONIONIC EMULSIFIERS SHED
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IV. FIRE AND EXPLOSION HAZARD
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Flash Point: 120 DEGREES F (PMM)
Autoignition Temp: 460 DEGREES F.
Flammable Limit: NOT AVAILABLE
Extinguishing Media: USE WATER (AS SPRAY ONLY), CARBON DIOXIDE, FOAM,
SAND/EARTH OR DRY CHEMICAL TO EXTINGUISH FIRES.
Special Fire Fight Proc: USE SELF-CONTAINED BREATHING APPARATUS AND
AVOID BREATHING FUMES. AVOID SPRAYING A SOLID
STREAM OF WATER OR FOAM DIRECTLY INTO A POOL OF
HOT, BURNING LIQUID. THIS MAY CAUSE FROTHING.
Fire and Expl Hazard: THERE ARE NO KNOWN UNUSUAL FIRE OR EXPLOSION
HAZARDS.
Helena Chemical Company 06-JUN-2002 08:41:52
PH: 901-761-0050 Page 2 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-JAN-2000
Product: PRO-MATE PINE PLUS
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V. HEALTH HAZARD
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Carcinogen Information: NONE CURRENTLY KNOWN.
ACUTE EFFECTS OF OVER EXPOSURE
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Swallowing: THIS PRODUCT MAY BE HARMFUL IF INGESTED.
Skin Absorption: THIS PRODUCT MAY BE HARMFUL IF ABSORBED
THROUGH SKIN.
Inhalation: SHORT-TERM HARMFUL HEALTH EFFECTS ARE NOT
EXPECTED FROM VAPORS GENERATED AT AMBIENT
TEMPERATURE.
Skin contact: PROLONGED OR REPEATED EXPOSURE MAY RESULT IN
SLIGHT TEMPORARY IRRITATION.
Eye Contact: EYE CONTACT MAY RESULT IN TEMPORARY IRRITATION.
Chronic Effects: NONE CURRENTLY KNOWN.
Other Hazard: NONE CURRENTLY KNOWN.
EMERGENCY AND FIRST AID PROCEDURES
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Swallowing: IF SWALLOWED, DO NOT INDUCE VOMITING. OBTAIN
MEDICAL ATTENTION IMMEDIATELY.
Skin: REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH
SOAP AND WATER.CALL A PHYSICIAN IF IRRITATION
DEVELOPS OR PERSISTS.
Inhalation: MOVE TO FRESH AIR, OBTAIN MEDICAL ATTENTION IF
BREATHING BECOMES DIFFICULT. NO EMERGENCY CARE
ANTICIPATED.
Eyes: IN CASE OF CONTACT WITH EYES, IMMEDIATELY FLUSH
WITH WATER FOR 15 MINUTES. OBTAIN MEDICAL
ATTENTION IF IRRITATION PERSISTS.
Notes to Physician: -THERE IS NO SPECIFIC ANTIDOTE FOR THIS
PRODUCT. TREATMENT SHOULD BE DIRECTED TOWARD
CONTROL OF THE SYMPTOMS AND THE CLINICAL
CONDITION OF THE PATIENT.
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VI. REACTIVITY
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Stability: Stable
Conditions to Avoid: EXCESSIVE HEAT.
Polymerization: Will Not Occur
Conditions to Avoid: POLYMERIZATION CATALYSTS SUCH ASUMINUM CHLORIDE.
Incompatibility material: STRONG OXIDIZING AGENTS.
Hazardous Combustion: BURNING CAN PRODUCE CARBON DIOXIDE AND CARBON
MONOXIDE.
Helena Chemical Company 06-JUN-2002 08:41:52
PH: 901-761-0050 Page 3 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-JAN-2000
Product: PRO-MATE PINE PLUS
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VII. SPILL OR LEAK PROCEDURES
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Spill or Leak Proc: ROPE OFF CONTAMINATED AREA, COVER SPILL WITH AN
ABSORBENT, SUCH AS CLAY, SAND, OR SAWDUST.
PLACE IN RECOVERY DRUMS FOR PROPER DISPOSAL.
WEAR SUITABLE PROTECTIVE EQUIPMENT.
Waste Disposal Method: THIS MATERIAL MUST BE DISPOSED OF ACCORDING TO
FEDERAL, STATE, OR LOCAL PROCEDURES UNDER THE
RESOURCE CONSERVATION AND RECOVERY ACT.
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VIII. SPECIAL PROTECTION INFORMATION
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Respiration: NONE NORMALLY NEEDED. FOR OPERATIONS WHERE EYE
OR FACE CONTACT CAN OCCUR, WEAR CHEMICAL SPLASH
PROOF GOGGLES.
Ventilation: GENERAL (MECHANICAL) ROOM VENTILATION IS
EXPECTED TO BE SATISFACTORY.
Gloves: IMPERVIOUS (PVC-COATED)
Eyes: CHEMICAL GOGGLES
Other: EYE WASH STATION, PROTECTIVE APRON AND
FOOTWEAR.
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IX. SPECIAL PRECAUTIONS
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Special precaution: KEEP OUT OF REACH OF CHILDREN. DO NOT STORE
WITH FOOD, FEED, OR OTHER MATERIAL TO BE USED
OR CONSUMED BY HUMANS OR ANIMALS. DO NOT
CONTAMINATE WATER SUPPLIES, LAKES, STREAMS, OR
PONDS WITH RINSATE FROM CONTAINERS OR
EQUIPMENT.DO NOT GET IN EYES, AVOID CONTACT
WITH SKIN AND CLOTHING, AVOID BREATHING VAPORS,
KEEP CONTAINER CLOSED, USE WITH ADQUATE
VENTILATION, WASH THOROUGHLY AFTER HANDLING.
Other precaution: IMPORTANT: SPILLS OF THIS PRODUCT ARE VERY
SLIPPERY WHEN WET.
STORE AT TEMPERATURES BELOW 140 DEGREES F. FOR
QUALITY CONTROL. PRODUCT MAY EXPAND SLIGHTLY
IN STORAGE CAUSING SLIGHT PRESSURE TO BUILD UP
IN CONTAINER. AVOID TEMPERATURE EXTREMES.
Helena Chemical Company 06-JUN-2002 08:41:52
PH: 901-761-0050 Page 4 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-JAN-2000
Product: PRO-MATE PINE PLUS
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X. SHIPPING INFORMATION
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Shipping name: **REGULATED AS A COMBUSTIBLE LIQUID BY DOT.
REGULATED BY IATA (AIR) AND IMO (VESSEL) AS A
FLAMMABLE LIQUID.
Hazard Class: COMBUSTIBLE LIQUID
Identification No: NONE
Labels Required: NONE
Placarding: NONE
Freight Class: ADJUVANT, SPREADER OR STICKER, LIQUID, NOIBN
Chemical Name Equivalent R.Q.
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NOT APPLICABLE NOT APPLICABLE
**TRANSPORTATION NOTE: PRODUCT HAS BEEN
RECLASSED TO A
COMBUSTIBLE LIQUID PER 49 CFR 173.150(F).
REGULATED BY DOT
AS A COMBUSTIBLE LIQUID IN SINGLE
CONTAINERS OF >119 GAL.
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XI. GENERAL PRODUCT INFORMATION
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National Fire Protection Association Rating:
(Rating level: 4-Extreme, 3-High, 2-Moderate, 1-Slight, 0-Minimum
Health: 1 Fire: 2 Reactivity: 0
S.A.R.A. Title III Hazard Classification: (Yes/No)
Immediate (Acute) Health: Y Delayed (Chronic) Health: N
Sudden Release of pressure: N Fire: N
Reactive: N
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Mail inquiries to: 225 Schilling Blvd., Suite 300 Collierville, TN 38017
Helena Chemical Company believes that the data contained herein is factual.
This data is not to be taken as a warranty or representation of legal
responsibility. It is offered solely for your consideration, investigation
and verification.
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