MATERIAL SAFETY DATA SHEET
I - PRODUCT IDENTIFICATION
Product: 3 Month Algaecide, Black Algaecide, Winter Algaecide
Chemical Family: A solution of a copper triethanolamine complex in water
Formula: CuC12H30N2O6
CAS Number: 31089-39-1
Synonyms: Copper(II) triethanolamine complex
COMPANY IDENTIFICATION 24 HR EMERGENCY TELEPHONE NUMBER
AllChem Performance Products INFOTRAC (Transportation): (800)535-5053
6010 NW First Place
Gainesville, FL 32607
Tel:352-378-9696
II 鈥? COMPOSITION, INFORMATION ON INGREDIENTS
Exposure Limits
Chemical or Common Name: OSHA PEL ACGIH TLV:
Copper(II) Triethanolamine complex, 30-31% N/A N/A
III 鈥? HAZARDS IDENTIFICATION
Primary Route(s) of Entry:
Ingestion: (X)
Inhalation: ()
Skin Contact: (X)
Eye Contact: (X)
Carcinogenicity Listings: Components are not listed as carcinogens or potential
carcinogens.
OSHA: ()
NTP: ()
IARC: ()
Primary Health Hazards (Acute and Chronic): see below
Signs & Symptoms of Exposure:
Acute:
Ingestion: Can result in burning and metallic taste in mouth, irritation of the
mouth, esophagus and stomach, vomiting, diarrhea, abdominal pain,
jaundice and kidney failure, dizziness, faintness, loss of consciousness and
death.
Inhalation: Not normally an inhalation hazard due to low vapor pressure.
Skin Contact: Contact with skin may result in irritation. Repeated or prolonged
skin contact may lead to skin burns and allergic contact dermatitis.
Eye contact: Eye irritant. May cause watering of the eye and blurred vision.
Contamination of the eye can result in permanent injury.
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Chronic: No information is available.
Note to physician: Treat symptomatically. Corrosive. May cause stricture. If lavage is
performed, suggest endotracheal and/or esophagoscopic control.
IV 鈥? FIRST AID MEASURES
Emergency and First Aid Procedures:
Ingestion: Immediately rinse mouth. If swallowed, DO NOT induce vomiting. Give
water or milk, seek immediate medical assistance.
Inhalation: Remove victim from exposure to fresh air. Seek medical advice if effects
persist.
Skin Contact: Immediately wash contaminated skin with plenty of water. Remove
contaminated clothing and wash before re-use. If irritation occurs, seek
medical advice.
Eye Contact: Immediately irrigate with copious quantities of water for at least 15
minutes. Hold eyelids open. Remove clothing if contaminated and wash
skin. Urgently seek medical assistance.
V 鈥? FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARD DATA
Flash Point: N/A
Auto-ignition Temperature: Not applicable
Flammable Limits:
LEL: Not applicable
UEL: Not applicable
Extinguishing Media: Water fog (or if unavailable, use fine water spray), foam, dry
agent(carbon dioxide, dry chemical powder).
Special Fire-fighting Procedures:
Unusual Fire and Explosion Hazards:
Flammability Data:
Flammable: No
Combustible: Not combustible, however following evaporation of aqueous
component, residual could burn if ignited.
VI 鈥? ACCIDENTAL RELEASE MEASURES
Steps to be taken in case material is spilled or released:
Clear area of all unprotected personnel. Avoid inhalation of vapor or mist. Increase
ventilation, Slippery when spilt. Avoid accidents, clean up immediately. Wear
protective equipment to prevent skin and eye contamination. Avoid contaminating
waterways.
VII 鈥? HANDLING AND STORAGE
Precautions to Be Taken in Handling and Storage:
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Storage: Transport or store in a cool, dry area away from direct heat. Keep container
tightly closed when not in use. Do not pack in unlined steel drums.
VIII 鈥? EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation:
Normal ventilation should be sufficient under normal conditions. Keep containers
closed when not in use.
Personal protection: Avoid skin and eye contact.
Protective Clothing Type: Wear overalls.
Skin and Eye Protective Equipment: Face shield, elbow length PVC gloves.
Work/ Hygienic Practices: Always wash hands before smoking, eating, drinking or using
the toilet. Wash contaminated clothing and other protective equipment before
storing or re-using.
IX - PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point: 100掳C
Vapor pressure: 17mm
Solubility in Water: Miscible
Appearance and odor: Blue liquid with slight odor, may foam.
Specific Gravity (H2O=1): 1.08-1.11
Melting Point: N/A
pH: 8.5
X 鈥? STABILITY AND REACTIVITY
Stability: () Unstable (X) Stable
Conditions to Avoid:
Incompatibility: Strong acids.
Hazardous Decomposition or By-Products: Oxides of carbon and nitrogen. Decomposes
on heating emitting toxic fumes including those of NOx.
Hazardous Polymerization: () May Occur (X) Will Not Occur
Conditions to Avoid:
XI- TOXICOLOGICAL INFORMATION
Animal Toxicology:
Acute Toxicity:
Inhalation LC50: No effect at 2000 mg/kg
Dermal : Greater than 2000 mg/kg
Oral LD50(rat): 4500 mg/kg
Eyes: Irritant
Inhalation: No effect at 2000 mg/kg
Carcinogenicity: This product is not known or reported to be carcinogenic by any
reference source including IARC, OSHA, NTP, Or EPA.
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XII 鈥? ECOLOGICAL INFORMATION
Aquatic Toxicity: No data
Avian Toxicity:
ENVIRONMENTAL HAZARDS (PR Notice 93-10)
This product is toxic to fish and aquatic organisms. Do not contaminate water by
cleaning of equipment or disposal of wastes. Do not discharge effluent containing this
product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance
with the requirements of a National Pollutant Discharge Elimination System (NPDES)
permit and the permitting authority has been notified in writing prior to discharge. Do
not discharge effluent containing this product to sewer systems without previously
notifying the local sewage treatment plant authority. For guidance, contact your State
Water board or Regional Office of the EPA.
XIII 鈥? DISPOSAL CONSIDERATIONS
Waste Disposal Method: After cleaning up spills, refer to State Land Waste Management
Authority for disposal. Decontaminate empty containers.
XIV - TRANSPORTATION DATA
U.S. Department of Transportation - 49 CFR
Not Regulated
Proper Shipping Name: Agricultural herbicide
Hazard Class/Division Number:
ID Number:
Packing Group:
Label Required:
Placard Required:
Marine Pollutant:
International Maritime Organization - IMDG
Not Regulated
Proper Shipping Name:
Hazard Class/Division Number:
ID Number:
Packing Group:
Label Required:
Placard Required:
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Marine Pollutant:
XV - REGULATORY INFORMATION
This chemical appears on the following lists:
() SARA Section 313
() TSCA
XVI - ADDITIONAL INFORMATION
This MSDS replaces the 01/04/2002 version. Any changes in information are as follows:
In Section I - 24 hr emergency telephone number
ALWAYS COMPLY WITH ALL APPLICABLE INTERNATIONAL, FEDERAL,
STATE AND LOCAL REGULATIONS REGARDING THE TRANSPORTATION,
STORAGE, USE AND DISPOSAL OF THIS CHEMICAL.
Due to the changing nature of regulatory requirements, the REGULATORY
INFORMATION listed in Section XV of this document should NOT be considered all-
inclusive or authoritative. International, Federal, State and Local regulations should be
consulted to determine compliance with all required reporting requirements.
The information in this MSDS was obtained from sources, which we believe are reliable.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY,
EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS. The conditions or
methods of handling, storage, use, and disposal of the product are beyond our control and
may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT
ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR
LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY
CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF
THE PRODUCT. This MSDS was prepared and is to be used only for this product. If
the product is used as a component in another product, this MSDS information may not
be applicable.
Issue Date: 01/04/2002
Ref No: 050AAK
Revision Date: 07/12/2005
Revision No: 1
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