PYROCAP B-136鈩?
MATERIAL SAFETY DATA SHEET
APPROVED BY DEPARTMENT OF AGRICULTURE, U.S. FOREST SERVICE
EFFECTIVE DATE: 1 MARCH 1997
CAUTION
Avoid eye contact with concentrate; may be irritating. Avoid unprotected prolonged exposure of the skin to concentrate.
CLASSIFICATION: NON-HAZARDOUS
A. PRODUCT IDENTIFICATION
PYROCAP B-136 is a proprietary mixture of surfactants and other materials in an aqueous solution.
B. HAZARDOUS COMPONENT(S)
ACGIH OSHA PERCENT
HAZARDOUS COMPONENT(S) CAS NUMBER TLV PEL COMPOSITION
NONE
Substances present at a concentration of 0.1% or more classified as a carcinogen by IARC, NTP or OSHA: None
known
Substances subject to the reporting requirements of Section 313 of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372: None
C. OCCUPATIONAL CONTROL PROCEDURES
1. For Handling Concentrates:
a. Avoid eye contact with concentrate. Wear goggles when handling concentrate.
b. Avoid prolonged skin contact with concentrate. Use of rubber or plastic gloves is recommended
to avoid prolonged skin contact with concentrate.
c. Avoid excessive inhalation of concentrate's vapors.
d. Ventilation- Handle concentrate in a well ventilated area.
e. Avoid ingestion of concentrate.
2. For Handling Diluted Product:
a. Avoid unnecessary eye contact.
b. Minimal effects expected when contact with eyes does occur. Rinse with water if material should
get into eyes.
D. FIRE PROTECTION INFORMATION FOR CONCENTRATES
Flash point: Flash point is greater than 500oF.
1.
2. Unusual Fire of Explosion Hazards: NONE.
E. PHYSIOLOGICAL EFFECTS AND HEALTH INFORMATION
NOTE: All animal tests reported in this section for both the concentrate and diluted mixtures were done in
accordance with the requirements found in "Interim Requirements and Manufacturer Submission Procedures for
Wildland Fire Foams: Special Report 8651 1803, 5100-Fire, August, 1986".
The results of the test, which follow, are all acceptable under these requirements:
1. For concentrate before diluting water:
a. Eye Irritation: Moderately irritating
b. Skin Irritation: Moderately irritating
c. Acute Oral Toxicity: Low: LD50 >5050 mg/Kg
d. Acute Dermal Toxicity: Low: LD50 >2020
2. For Diluted Product (1 percent by volume):
a. Eye Irritation: Moderately irritating
b. Skin Irritation: Moderately irritating
c. Acute Oral Toxicity: Low: LD50 >5050 mg/Kg
d. Acute Dermal Toxicity: Low: LD50 >2020
F. PHYSICAL DATA OF CONCENTRATE
1. Color: Dark reddish/brown
2. Odor: Slightly eucalyptol
3. pH: 7.65
4. Specific Gravity: 1.04
Vapor Pressure: (mm.Hg) at 20oC; Less than 1
5.
G. REACTIVITY DATA
Stability: Concentrate has the stability of five years for temperatures between 35oF and 90oF (sustained
1.
heat exposure). For extreme temperatures (up to 120oF) the shelf life will be less. Freezing point of
concentrate is 14oF (-10oC). If frozen, the concentrate can be used after thawing.
2. Corrosion Performance: All uniform and interangular corrosion tests were performed and completed by
the USFS in accordance to the procedures outlined in "interim Requirements and Manufacturer
Submission Procedures for Wildland Fire Foams: Special Report 8651 1803, 5100-Fire, August, 1986".
Results of uniform corrosion tests on aluminum, brass, and mild steel were found to be in the acceptable
limits. However, the corrosion test for magnesium exceeded the required limit for all wildland fire
chemicals for use in fixed tank helicopters. With the exception of magnesium, long term corrosion tests
were all within the acceptable limits. Therefore, PYROCAP B-136 IS NOT APPROVED FOR USE IN FIXED
TANK HELICOPTERS.
Interangular corrosion tests were found to be within the acceptable range.
3. Storage: The concentrate should be stored in high density polyethylene or polyethylene-lined containers,
fiberglass, or steel tanks only.
H. SPILL, LEAK, and DISPOSAL INFORMATION
Amounts of five (5) gallons or more may be mopped up and disposed as chemical waste. Smaller amounts may be
flushed where local ordinances do not prohibit disposal of biodegradable detergent materials.
I. TRANSPORTATION DATA
1. D.O.T.: Not regulated
2. Reportable Quantity: Not applicable
3. Freight Classification: Cleaning compound
4. Non-hazardous, non-flammable, non-corrosive
J. ENVIRONMENTAL PROTECTION
Results of dynamic toxicity test with killifish in accordance with ASTM E729 were within acceptable limits.
Reference: "Results of Flow-Through Toxicity Tests on Test Materials from Pyrocap Inc." EA Engineering, Science
and Technology, Inc. July 1989.
K. EMERGENCY & FIRST AID PROCEDURES (FOR CONCENTRATES)
EYE CONTACT: FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SEEK
MEDICAL ATTENTION.
SKIN CONTACT: Wash o
ff with water.
NOTICE OF WARRANTY: Pyrocap International Corporation warrants that Pyrocap International Corporation products are
reasonably fit for the purposes for which they were developed only when used in accordance with recommended use
practices under the above conditions. In no case shall Pyrocap International Corporation be liable for consequential,
special, or indirect damages resulting from the use or handling of these products. All such risks shall be assumed by the
Page 2
buyer. PYROCAP INTERNATIONAL CORPORATION MAKES NO WARRANTIES OF MERCHANTABILITY OR FITNESS FOR
A PARTICULAR PURPOSE NOR ANY OTHER EXPRESSED OR IMPLIED WARRANTY EXCEPT AS STATED ABOVE.
Page 3
|