MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
Page 1 of 8
SNOW White庐 Filler
United States Gypsum Company Product Safety: 1 (800) 507-8899
125 South Franklin Street www.usg.com
Chicago, Illinois 60680-4124 Version Date: January 15, 2004
A Subsidiary of USG Corporation Version: 5
SECTION 1
CHEMICAL PRODUCT AND IDENTIFICATION
PRODUCT: SNOW White庐 Filler
CHEMICAL FAMILY: Anhydrous Gypsum (Calcium Sulfate, CaSO4)
SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
TLV (mg/m3) PEL( mg/m3)
MATERIAL WT% CAS NUMBER
Anhydrite (Calcium Sulfate) 100 10 15(T)/5(R) 14798-04-0
Crystalline Silica <0.1 0.05(R) 0.1(R) 14808-60-7
(T) 鈥? Total (R) 鈥? Respirable (NE) 鈥? Not Established mmpfc - million particles per cubic foot of air
Respirable crystalline silica: IARC: Group 1 carcinogen, NTP: Known human carcinogen. The weight percent for silica
represents total quartz and not the respirable fraction. Testing of dust from USG gypsum powders has not detected
respirable crystalline silica.
Food and Drug Administration [CFR Title 21, v.3, sec 184.1230] 鈥? Calcium Sulfate is Generally
Recognized as Safe (GRAS).
All ingredients of this product are included in the U.S. Environmental Protection Agency鈥檚 Toxic Substances Control Act
Chemical Substance Inventory. All components of this product are included in the Canadian Domestic Substances List
(DSL).
SECTION 3
HAZARD IDENTIFICATION
INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS
0 = Minimal Hazard
0
HEALTH *
0
NFPA Ratings: HIMS Ratings: 1 = Slight Hazard
0
FLAMMABILITY
0
0
Health: 0 Health: *0 2 = Moderate Hazard
PHYSICAL HAZARD 0
Fire: 0 Fire: 0 3 = Serious Hazard
PERSONAL PROTECTION E
Reactivity: 0 Reactivity: 0 4 = Severe Hazard
Personal Protection: Use eye and skin protection. Use NIOSH/MSHA-approved respiratory protection when necessary.
*Respirable crystalline silica can cause lung disease and/or cancer. E- Safety glasses, gloves and dust respirator
EMERGENCY OVERVIEW: This product is not expected to produce any unusual hazards during normal use. Exposure
to high dust levels may irritate the skin, eyes, nose, throat, or upper respiratory tract.
MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
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SNOW White庐 Filler
SECTION 3 HAZARD IDENTIFICATION (continued)
POTENTIAL HEALTH EFFECTS
ACUTE:
Eyes: Airborne dust or direct contact can cause mechanical irritation of eyes. If burning, redness, itching, pain or other
symptoms persist or develop, consult physician.
Skin: Direct, prolonged or repeated contact with the skin may cause irritation.
Inhalation: Dust exposures generated during the handling of the product may irritate eyes, skin, nose, throat, and upper
respiratory tract. Persons subjected to large amounts of this dust will be forced to leave area because of nuisance
conditions such as coughing, sneezing and nasal irritation. Labored breathing may occur after excessive inhalation. If
respiratory symptoms persist, consult physician.
Ingestion: If ingested may cause temporary irritation to the gastrointestinal tract, especially the stomach. No known
effects.
CHRONIC:
Eyes: None known.
Skin: None known.
Ingestion: No known effects.
Inhalation: Testing of dust from USG gypsum powders has not detected respirable crystalline silica. Exposures to
respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be
determined by workplace hygiene testing.
Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis)
and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of
developing silicosis is dependent upon the exposure intensity and duration.
TARGET ORGANS: Eyes, skin and respiratory system.
PRIMARY ROUTES OF ENTRY: Inhalation, eyes and skin contact.
SECTION 4
FIRST AID MEASURES
FIRST AID PROCEDURES
Eyes: In case of contact, do not rub or scratch your eyes. Flush thoroughly with water for 15 minutes to remove
particles. If irritation persists, consult physician.
Skin: Wash with mild soap and water. A commercially available hand lotion may be used to treat dry skin areas. If skin
has become cracked, take appropriate action to prevent infection and promote healing. If irritation persists, consult
physician.
Inhalation: Remove to fresh air. Leave the area of dust exposure and remain away until coughing and other symptoms
subside. Other measures are usually not necessary, however if conditions warrant, contact physician.
Ingestion: This product is not intended to be ingested or eaten. No harmful effects expected. No specific
recommendations. If gastric disturbance occurs, call physician.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED: Pre-existing upper respiratory and lung diseases such as,
but not limited to, bronchitis, emphysema and asthma. Pre-existing skin diseases such as, but not limited to, rashes and
dermatitis.
MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
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SNOW White庐 Filler
SECTION 5
FIRE FIGHTING MEASURES
Not expected to burn.
General Fire Hazards:
Water or use extinguishing media appropriate for surrounding fire.
Extinguishing Media:
Wear appropriate personal protective equipment (See section 8).
Special Fire Fighting Procedures:
None
Unusual Fire & Explosion Hazards:
Above 1450潞 C - decomposes to calcium oxide (CaO) and sulfur dioxide (SO2).
Hazardous Combustion Products:
None Known Not Applicable
Flash Point: Auto Ignition:
Not Applicable
Method Used: Flammability
Not Applicable
Classification:
Upper Flammable Limit (UFL): Not Applicable
Not Applicable Not Applicable
Lower Flammable Limit (LFL): Rate of Burning:
SECTION 6
ACCIDENTAL RELEASE MEASURES
CONTAINMENT:
No special precautions. Wear appropriate personal protection (See Section 8).
CLEAN-UP:
Use normal clean up procedures. Wear appropriate protective equipment. Ventilate area. If dry, shovel or sweep up
material from spillage and place collected material into a container for recovery or waste disposal. Avoid dust
generation. Avoid inhalation of dust and contact with eyes and skin. Maintain proper ventilation. If vacuum is used to
collect dust, use an industrial vacuum cleaner with a high efficiency air filter. If sweeping is necessary, use dust
suppressant. Do not use compressed air for clean up. These procedures will help minimize potential exposures. If
washed down, may plug drains.
DISPOSAL:
Follow all local, state, provincial and federal regulations. Never discharge large releases directly into sewers or surface
waters. Trace amounts of residue can be flushed to a drain, using plenty of water.
SECTION 7
HANDLING AND STORAGE
HANDLING:
Minimize dust generation and accumulation. Avoid breathing dust. Wear the appropriate respiratory protection against
dust in poorly ventilated areas and if TLV is exceeded (see Sections 2 and 8). Avoid dust contact with eyes. Wear the
appropriate eye protection against dust (See Section 8).
Use good safety and industrial hygiene practices.
STORAGE:
Store at room temperature in a dry location.
Keep containers closed when not in use
MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
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SNOW White庐 Filler
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Provide ventilation sufficient to control airborne dust levels especially respirable crystalline silica.
If user operations generate airborne dust, use ventilation to keep dust concentrations below permissible exposure limits
(See Section 2).
Where general ventilation is inadequate, use process enclosures, local exhaust ventilation, or other engineering controls
to control dust levels below permissible exposure limits (see Section 2). If engineering controls are not possible, wear a
properly fitted NIOSH/MSHA-approved particulate respirator.
RESPIRATORY PROTECTION:
Wear a NIOSH/MSHA-approved respirator equipped with particulate cartridges when dusty in poorly ventilated areas,
and if TLV is exceeded. A respiratory program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator's use.
OTHER PERSONAL PROTECTIVE EQUIPMENT:
Eye/Face: Wear eye protection (safety glasses or goggles) to avoid particulate irritation of the eye.
Skin: Gloves or protective clothing are usually not necessary but may be desirable in specific work situations. For brief
contact, no precautions other than clean body-covering clothing should be needed. Wear gloves and protective clothing
to prevent repeated or prolonged skin contact. Barrier creams or skin lotion may be applied to face, neck, wrist and
hands when skin is exposed to help prevent drying of skin.
General: Selection of Personal Protective Equipment will depend on environmental working conditions and operations.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Not Applicable
White to off white
Appearance Viscosity
Solid (powder) ~ 0.27 g/100 g solution
Physical State Solubility (H2O)
Low to no odor Not Applicable
Odor Boiling Point
~7-10.4 Not Applicable
pH @ 25 潞 C Melting Point
Varies Not Applicable
Particle Size Softening Point
~136 g/mole Not Applicable
Molecular Weight Freezing Point
~ 45-70 lb/ft3 Not Applicable
Bulk Density Vapor Density (Air = 1)
2.96 Not Applicable
Specific Gravity (H20 = 1) Vapor Pressure (mm Hg)
Zero Not Applicable
Percent Volatile Evaporation Rate (BuAc = 1)
Zero
VOC Content
SECTION 10
CHEMICAL STABILITY AND REACTIVITY
Stable.
STABILITY:
Contact with incompatibles.
CONDITIONS TO AVOID:
None known.
INCOMPATIBILITY:
Will not occur.
HAZARDOUS POLYMERIZATION:
Above 1450潞 C - decomposes to calcium oxide (CaO) and sulfur dioxide (SO2
HAZARDOUS DECOMPOSITION:
MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
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SNOW White庐 Filler
SECTION 11
TOXICOLOGICAL INFORMATION
ACUTE EFFECTS:
Direct contact may cause eye, skin and/or respiratory irritation.
LD50: Not Available for product. LC50: Not Available for product.
CHRONIC EFFECTS / CARCINOGENICITY:
Crystalline silica: Testing of dust from USG gypsum powders has not detected respirable crystalline silica. Exposures
to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be
determined by workplace hygiene testing.
Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis)
and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of
developing silicosis is dependent upon the exposure intensity and duration.
In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall
evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on
external factors affecting its biological activity or distribution of its polymorphs.
IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to
humans (Group 1).
SECTION 12
ECOLOGICAL INFORMATION
ENVIRONMENTAL TOXICITY: This product has no known adverse effect on the ecology. A large discharge directly
into waterways would not be expected to kill aquatic life.
Ecotoxicity value: Not determined.
SECTION 13
DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD:
Dispose of material in accordance with Federal, State, Provincial, and Local regulations. Consult with environmental
regulatory agencies for guidance on acceptable disposal practices. Never discharge directly into sewers or surface
waters.
SECTION 14
TRANSPORT INFORMATION
U.S. DOT INFORMATION: Not a hazardous material per DOT shipping requirements. Not classified or regulated.
Same as product name.
Shipping Name
Not classified
Hazard Class:
None. Not classified.
UN/NA #:
None.
Packing Group:
Not applicable.
Label (s) Required:
Not classified.
GGVSec/MDG-Code:
Not applicable.
ICAO/IATA-DGR:
None
RID/ADR:
None
ADNR:
MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
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SECTION 15
REGULATORY INFORMATION
UNITED STATES REGULATIONS
All ingredients of this product are included in the U.S. Environmental Protection Agency鈥檚 Toxic Substances Control Act
Chemical Substance Inventory.
CAA Sec.
CERCLA
RCRA
Code
112
302 304 313
MATERIAL WT%
Anhydrite (Calcium Sulfate) 100 NL NL NL NL NL NL
Crystalline Silica <1 NL NL NL NL NL NL
Key : NL = Not Listed
SARA Title III Section 302 (EPCRA) Extremely Hazardous Substances: Threshold Planning Quantity (TPQ)
SARA Title III Section 304 (EPCRA) Extremely Hazardous Substances: Reportable Quantity (RQ)
SARA Title III Section 313 (EPCRA) Toxic Chemicals: X= Subject to reporting under section 313
CERCLA Hazardous Substances: Reportable Quantity (RQ)
CAA Section 112 (r) Regulated Chemicals for Accidental Release Prevention: Threshold Quantities(TQ)
RCRA Hazardous Waste: RCRA hazardous waste code
Food and Drug Administration [CFR Title 21, v.3, sec 184.1230] 鈥? Calcium Sulfate is Generally
Recognized as Safe (GRAS).
CANADIAN REGULATIONS
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations. All components of this product are
included in the Canadian Domestic Substances List (DSL).
MATERIAL WT% IDL Item # WHMIS Classification:
Anhydrite (Calcium Sulfate) 100 Not Listed Not Listed
Crystalline Silica <1 1406 D2A
IDL Item # : Canadian Hazardous Products Act 鈥? Ingredient Disclosure List Item #
WHMIS Classification: Workplace Hazardous Material Information System
CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S)
All substances listed are associated with the nature of the raw materials used in the manufacture of this product and are
not independent components of the product formulation. All substances, if present, are at levels well below regulatory
limits. See Section 11 : Toxicology Information for detailed information
MATERIAL IARC NTP ACGIH CAL- 65
Respirable Crystalline Silica 1 1 A2 Listed
IARC 鈥? International Agency for Research on Cancer (World Health Organization)
1- Carcinogenic to humans
2A 鈥? Probably carcinogenic to humans
2B 鈥? Possibly carcinogenic to humans
3 - Not classifiable as a carcinogen
4 鈥? Probably not a carcinogen
MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
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SECTION 15 REGULATORY INFORMATION (continued)
NTP 鈥? National Toxicology Program (Health and Human Services Dept., Public Health Service, NIH/NIEHS)
1- Known to be carcinogen
2- Anticipated to be carcinogens
ACGIH 鈥? American Conference of Governmental Industrial Hygienists
A1 鈥? Confirmed human carcinogen
A2 鈥? Suspected human carcinogen
A3 鈥? Animal carcinogen
A4 - Not classifiable as a carcinogen
A5 鈥? Not suspected as a human carcinogen
CAL-65 鈥? California Proposition 65 鈥淐hemicals known to the State of California to Cause Cancer鈥?
SECTION 16
OTHER INFORMATION
Label Information
鈭哤ARNING!
Dust created from product may cause eye, skin, nose, throat or upper respiratory irritation. Avoid inhalation of dust and
eye contact. Use in a well-ventilated area. Wear a NIOSH/MSHA-approved respirator when dusty. Use proper
ventilation to reduce dust exposure. Wear eye protection. If eye contact occurs, flush thoroughly with water for 15
minutes. If irritation persists, call physician. Wash thoroughly with soap and water after use. Do not ingest. If ingested,
call physician. Product safety information: (800) 507-8899 or www.usg.com
KEEP OUT OF REACH OF CHILDREN.
Key/Legend
TLV Threshold Limit Value
PEL Permissible Exposure Limit
CAS Chemical Abstracts Service (Registry Number)
NIOSH National Institute for Occupational Safety and Health
MSHA Mine Safety and Health Administration
OSHA Occupational Health and Safety Administration
ACGIH American Conference of Governmental Industrial Hygienists
IARC International Agency for Research on Cancer
DOT United States Department of Transportation
EPA United States Environmental Protection Agency
NFPA National Fire Protection Association
HMIS Hazardous Materials Identification System
PPE Personal Protection Equipment
TSCA Toxic Substances Control Act
DSL Canadian Domestic Substances List
NDSL Canadian Non-Domestic Substances List
SARA Superfund Amendments and Reauthorization Act of 1986
RCRA Resource Conservation and Recovery Act
CERCLA Comprehensive Environmental Response, Compensation and Liability Act of 1980
UN/NA# United Nations/North America number
CFR Code of Federal Regulations
WHMIS Workplace Hazardous Material Information System
MATERIAL SAFETY DATA SHEET MSDS # 52-500-005
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SECTION 16 OTHER INFORMATION (continued)
Prepared by:
Product Safety
USG Corporation
125 South Franklin St.
Chicago, Illinois 60606
END
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