Duniway Part #: EP-8034-Resin-Hardener
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 06
HYSOL 1C
83202 RESIN
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: HYSOL 1C
Item No.: 83202 RESIN Part of Kit: 83202
Product Type: Epoxy Resin
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Epoxy resin 25068-38-6 30-60
TALC 14807-96-6 10-30
TITANIUM DIOXIDE 13463-67-7 .5-1.5
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
TALC 2 mg/m3 TWA 2 mg/m3 TWA None
respirable dust respirable dust
TITANIUM DIOXIDE 10 mg/m3 15 mg/m3 None
Total dust
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Eye and skin irritant. May cause allergic skin
reaction.
Primary Routes of Entry: Eyes: May cause eye irritation.
Skin: Allergic skin reaction. Itching. Moderate
skin irritation. Redness.
Inhalation: May cause irritation to nose, throat
and respiratory tract. Contains crystalline silica
which may cause cancer, but in product as sold is
not in a respirable form. No exposure should
occur unless the cured adhesive is dry sanded or
otherwise cut without proper local exhaust and/or
the use of a NIOSH approved respirator.
Ingestion: Not expected to be a relevant route of
exposure.
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 06
Product Name: HYSOL 1C
Item No.: 83202 RESIN
3. HAZARDS IDENTIFICATION (continued)
Signs and Symptoms
of Exposure: see above
Existing Conditions
Aggravated by Exposure: Respiratory disorders. Skin disorders.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Epoxy resin ALG IRR NO NO NO
TALC IRR LUN SOM NO N/A NO
TITANIUM DIOXIDE IRR RES NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable ALG Allergen
IRR Irritant LUN Lung
RES Respiratory SOM Some evidence of carcinogenicity
4. FIRST AID MEASURES
Ingestion: Keep individual calm. DO NOT induce vomiting.
Get medical attention immediately.
Inhalation: Remove to fresh air. If symptoms develop and
persist, get medical attention.
Skin Contact: Immediately flush skin with plenty of water (using
soap, if available) for at least 15 minutes.
Remove contaminated clothing and shoes. Wash
clothing before reuse. If irritation persists,
get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for 15
minutes. Seek immediate medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: 480掳F PMCC
Recommended
Extinguishing Agents: Water fog, foam, dry chemical or carbon dioxide
Special Firefighting
Procedures: Firefighters should wear self contained breathing
apparatus (SCBA) and full turn out gear.
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 06
Product Name: HYSOL 1C
Item No.: 83202 RESIN
5. FIRE FIGHTING MEASURES (continued)
Hazardous Products formed
by Fire or Thermal Decomp Carbon monoxide, carbon dioxide, smoke.
Aldehydes, organic acids.
Unusual Fire or
Explosion Hazards: Containers exposed to fire should be cooled with
water to prevent vapor pressure buildup which
could result in container rupture.
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Prevent additional discharge of material, if
possible to do so without hazard. Immediately
contact emergency personnel.
Keep unnecessary personnel away.
7. HANDLING AND STORAGE
Safe Storage:
Keep containers tightly closed and sealed until
ready to use. Store in a cool, dry place.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling:
Keep away from heat, sparks and flame. Avoid
contact with eyes. Avoid breathing vapor or mist.
Avoid contact with skin and clothing. Wash
thoroughly after handling.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Chemical splash goggles or safety glasses with
side shields.
Skin: Use chemical resistant, impermeable clothing
including gloves and either an apron or body suit
to prevent skin contact.
Ventilation: Use local exhaust ventilation if the potential for
airborne exposure exists.
Respiratory Use a NIOSH approved respirator if ventilation is
not sufficient and the potential exists to exceed
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 06
Product Name: HYSOL 1C
Item No.: 83202 RESIN
8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued)
any exposure limit.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White viscous liquid
Odor: Mild odor
Boiling Point: >500 Degrees F
pH: Does not apply
Solubility in Water: Insoluble
Specific Gravity 1.57
Volatile Organic Compound
(EPA Method 24) Not available for individual resin. Total
volatiles are determined as mixed for use with
hardener.
Vapor Pressure: Nil
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility:
Oxidizing agents, Strong acid strong bases such as
amines. Reaction with some curing agents may
produce considerable heat.
Conditions to Avoid: See above
Hazardous Decomposition
Products (non-thermal): None known.
11. TOXICOLOGICAL INFORMATION
Product toxicological data not available
12. ECOLOGICAL INFORMATION
No data available
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 06
Product Name: HYSOL 1C
Item No.: 83202 RESIN
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number
Not a RCRA hazardous material for disposal.
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: This product contains chemicals known to the state
of California to cause cancer, birth defects or
other reproductive harm -
phenyl glycidal ether, quartz.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: BEVERLY FISCHER
Title: Manager, Health Safety & Regulatory Affairs
Company: Henkel Loctite Corporation, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 06
Product Name: HYSOL 1C
Item No.: 83202 RESIN
16. OTHER INFORMATION (continued)
Revision Date: March 09, 1999 Revision: 0002
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 06
HYSOL 1C
83202 HARDENER
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: HYSOL 1C
Item No.: 83202 HARDENER Part of Kit: 83202
Product Type: Epoxy Hardener
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
SILICA, QUARTZ 14808-60-7 10-30
TALC 14807-96-6 8-30
DIETHYLENETRIAMINE 111-40-0 10-30
Epoxy resin 25068-38-6 10-30
PHENOL, 4,4'-ISOPROPYLIDENEDI-* 80-05-7 1-5
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
SILICA, QUARTZ 0.05mg/m3 TWA 0.1mg/m3 TWA None
respirable dust respirable dust
TALC 2 mg/m3 TWA 2 mg/m3 TWA None
respirable dust respirable dust
DIETHYLENETRIAMINE 1 ppm skin 1 ppm TWA None
4.2mg/m3 skin 4mg/m3
PHENOL, 4,4'-ISOPROPYLIDENEDI- None None 10 mg/m3
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Causes eye and skin burns. May cause allergic
skin reaction. May cause allergic respiratory
reaction. Causes respiratory tract irritation.
Primary Routes of Entry: Eyes: May cause severe eye irritation. May cause
corneal damage.
Skin: Short exposure may cause severe skin burns.
May cause allergic skin reaction.
Inhalation: May cause irritation to nose and
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 06
Product Name: HYSOL 1C
Item No.: 83202 HARDENER
3. HAZARDS IDENTIFICATION (continued)
throat. May cause respiratory sensitization.
Contains crystalline silica which may cause cancer
but in product as sold is not in a respirable form
No exposure should occur unless the cured adhesive
is dry sanded or cut without local exhaust and/or
the use of a NIOSH approved respirator.
Ingestion: Harmful if swallowed.
Signs and Symptoms
of Exposure: see above
Existing Conditions
Aggravated by Exposure: Respiratory disorders. Skin disorders.
Eye disorders.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
SILICA, QUARTZ AC2 IMM LUN SOM YES 2A NO
TALC IRR LUN SOM NO N/A NO
DIETHYLENETRIAMINE ALG EYE IRR NO NO NO
Epoxy resin ALG IRR NO NO NO
PHENOL, 4,4'-ISOPROPYLIDENEDI- ALG BLO IRR KID SPL NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2A Probably carcinogenic to humans
AC2 ACGIH suspected human carcinogen ALG Allergen
BLO Blood EYE Eyes
IMM Immune system IRR Irritant
KID Kidney LUN Lung
SOM Some evidence of carcinogenicity SPL Spleen
4. FIRST AID MEASURES
Ingestion: Keep individual calm. DO NOT induce vomiting.
Give 3 or 4 glasses of milk or water.
Get medical attention immediately.
Inhalation: Remove to fresh air. If symptoms develop and
persist, get medical attention.
Skin Contact: Immediately flush skin with plenty of water (using
soap, if available) for at least 15 minutes.
Remove contaminated clothing and shoes. Wash
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 06
Product Name: HYSOL 1C
Item No.: 83202 HARDENER
4. FIRST AID MEASURES (continued)
clothing before reuse. If irritation persists,
get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for 15
minutes. Seek immediate medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: 215掳F OC
Recommended
Extinguishing Agents: Water fog, foam, dry chemical or carbon dioxide
Special Firefighting
Procedures: Firefighters should wear self contained breathing
apparatus (SCBA) and full turn out gear.
Hazardous Products formed
by Fire or Thermal Decomp Carbon monoxide, carbon dioxide, smoke.
nitrogen oxides.
Unusual Fire or
Explosion Hazards: Violent steam generation may occur upon
application of direct water stream.
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Eliminate sources of ignition. Prevent additional
discharge of material, if possible to do so
without hazard. Immediately contact emergency
personnel. Keep unnecessary personnel away.
Avoid contact with material.
7. HANDLING AND STORAGE
Safe Storage:
Keep containers tightly closed and sealed until
ready to use. Store in a cool, dry place.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Keep away from heat, sparks and flame. Avoid
contact with eyes. Avoid breathing vapor or mist.
Avoid contact with skin and clothing. Wash
thoroughly after handling.
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 06
Product Name: HYSOL 1C
Item No.: 83202 HARDENER
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Chemical splash goggles or safety glasses with
side shields.
Skin: Use chemical resistant, impermeable clothing
including gloves and either an apron or body suit
to prevent skin contact.
Ventilation: Use local exhaust ventilation if the potential for
airborne exposure exists.
Respiratory Use a NIOSH approved respirator if ventilation is
not sufficient and the potential exists to exceed
any exposure limit.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Tan viscous liquid
Odor: Strong ammonia odor
Boiling Point: 404 Degrees F
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.65
Volatile Organic Compound
(EPA Method 24) Not available for individual hardener. Total
volatiles are determined as mixed for use with
resin.
Vapor Pressure: <1 mmHg @20 C
Vapor Density: 3.5
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility:
Oxidizing agents. Heat is generated when mixed
with water. Metals. Acids. Acrylates.
Conditions to Avoid: Avoid temperatures in excess of 561 F. Avoid
mixing more than 2 pounds with adhesive resin
in a single mass. Considerable heat with
the release of toxic gasses and the possibility
of fire may result.
Hazardous Decomposition
Products (non-thermal): None known.
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 06
Product Name: HYSOL 1C
Item No.: 83202 HARDENER
11. TOXICOLOGICAL INFORMATION
Product toxicological data not available
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number Not a RCRA hazardous material for disposal.
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity (Not more than 1 liter)
Amine, Liquid, Corrosive, n.o.s.
(Diethylenetriamine)
Hazard Class or
Division: ORM-D (NOt more than 1 Liter)
Class 8, PGII
Identification Number: None (Not more than 1 Liter)
UN 2735
Marine Pollutant: None
IATA
Proper Shipping Name: Amines, Liquid, Corrosive, n.o.s.
(diethylenetriamine)
Class or Division: Class 8, PG II
UN or ID Number: UN 2735
15. REGULATORY INFORMATION
CA Proposition 65: This product contains chemicals known to the
State of California to cause cancer, birth defects
or other reproductive harm -
crystalline silica, phenyl glycidal ether
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 3
Fire Hazard: 1
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
HENKEL LOCTITE CORPORATION 07/06/03
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 06
Product Name: HYSOL 1C
Item No.: 83202 HARDENER
16. OTHER INFORMATION (continued)
Health Hazard: 3
Flammability Hazard: 1
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Beverly Fischer
Title: Manager, Health Safety & Regulatory Affairs
Company: Henkel Loctite Corporation, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: March 09, 1999 Revision: 0002
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