MSDS: L-NMMA (citrate) 3/21/02 2:50 PM
MATERIAL SAFETY DATA SHEET
SECTION 1. Chemical Product and Company Identification
L-NMMA (citrate)
Product Code: 80200 , Reference #: NO
Product Name: L-NMMA (citrate)
Chemical Family: Nitric Oxides
Synonyms
N5-[imino(methylamino)methyl]-L-ornithine, citrate;
L-NG-Monomethyl arginine citrate
Manufacturer Name and Address: Telephone Numbers: Dates:
Cayman Chemical Company Cayman Chemical Company (800)364-9897 Date Entered: 06/27/1996
1180 E. Ellsworth Rd. Revision: 03/07/2002
Ann Arbor, MI. 48108 Cayman Chemical Company (734)971-3335 Printed: 03/14/2002
SECTION 2. Composition/Information on Ingredients
L-NMMA (citrate)
Hazardous Components (Specific Chemical Identity/Common Name) CAS # Percentage
L-NMMA (citrate) {L-NG-Monomethyl arginine citrate} NA 100.0
SECTION 3. Hazards Identification
L-NMMA (citrate)
Emergency Overview
Route(s) of Entry: Inhalation? Yes , Skin? Yes , Eyes? Yes , Ingestion? Yes , Other:
Potential Health Effects (Acute and Chronic)
Contact may cause skin or eye irritation.
The toxicological properties of this compound have not been fully evaluated.
Carcinogeniticy: NTP? No , IARC Monographs? No , OSHA Regulated? No
Carcinogenicity/Other Information
Signs and Symptoms Of Exposure
Irritating to the skin, eyes, nose, throat, and respiratory tract.
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MSDS: L-NMMA (citrate) 3/21/02 2:50 PM
SECTION 4. First Aid Measures
L-NMMA (citrate)
Emergency and First Aid Procedures
If inhaled remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Get immediate
medical attention.
If swallowed, wash out mouth with water provided person is conscious. Never give anything by mouth to an unconscious
person. Get medical attention.
In case of contact with eyes, hold eyelids apart and flush eyes with plenty of water. After initial flushings, remove any contact
lenses and continue flushing for at least 15 minutes. Have eyes examined and tested by medical personnel.
In case of skin contact, immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical
attention if symptoms occur. Wash clothing before reuse.
Note to Physician
Medical Conditions Generally Aggravated By Exposure
SECTION 5. Fire Fighting Measures
L-NMMA (citrate)
Flash Pt: NE or NA Method Used:
Explosive Limits: LEL: UEL:
Autoignition Pt: NE or NA Extinguishing Media
Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material.
Fire Fighting Instructions
As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent), and full
protective gear to prevent contact with skin and eyes.
Flammable Properties and Hazards
Hazardous Combustion Products
SECTION 6. Accidental Release Measures
L-NMMA (citrate)
Steps To Be Taken In Case Material Is Released Or Spilled
Vacuum or sweep up material and place in disposal container.
After removal, ventilate contaminated area and flush thoroughly with water.
SECTION 7. Handling and Storage
L-NMMA (citrate)
Hazard Label Information:
Avoid contact with skin and eyes. Do not reuse this container.
Use with adequate ventilation. Wash thoroughly after handling.
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Precautions To Be Taken in Handling
Avoid contact with eyes, skin, and clothing.
Do not reuse this container.
Use with adequate ventilation.
Wash thoroughly after handling.
Precautions To Be Taken in Storing
Store at correct temperature.
Other Precautions
Work/Hygienic/Maintenance Practices
Do not take internally.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Wash thoroughly after handling.
SECTION 8. Exposure Controls/Personal Protection
L-NMMA (citrate)
Protective Equipment Summary - Hazard Label Information
Eye wash station in work area Lab coat Latex disposable gloves
Safety glasses Safety shower in work area Vent Hood
Respiratory Equipment (Specify Type)
Eye Protection
Safety glasses
Protective Gloves
Latex disposable gloves
Other Protective Clothing
Lab coat
Engineering Controls (Ventilation etc.)
Good general ventilation should be sufficient to control airborne levels.
SECTION 9. Physical and Chemical Properties
L-NMMA (citrate)
Physical States: [ ] Gas , [ ] Liquid , [ X ] Solid
Boiling Point: NE or NA
Melting Point:
Specific Gravity (Water = 1): NE or NA
Vapor Pressure (vs. Air or mm Hg): NE or NA
Vapor Density (vs. Air = 1): NE or NA
Evaporation Rate (vs Butyl Acetate=1): NE or NA
Solubility in Water: *6 mg/ml at 25.0 C
Other Solubility Notes: *PBS pH 7.2
Percent Volatile: NE or NA
Molecular Formula: 3[C7H16N4O2] C6H8O7
Molecular Weight: 756.80
pH:
Appearance and Odor
A crystalline solid
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SECTION 10. Stability and Reactivity
L-NMMA (citrate)
Stability: Unstable [ ] Stable [ X ]
Conditions To Avoid - Instability
Incompatibility - Materials To Avoid
Hazardous Decomposition Or Byproducts
Hazardous Polymerization: Will occur [ ] Will not occur [ X ]
Conditions To Avoid - Hazardous Polymerization
SECTION 11. Toxicological Information
L-NMMA (citrate)
The toxicological effects of this compound have not been thoroughly studied.
Chronic Toxicological Effects
SECTION 12. Ecological Information
L-NMMA (citrate)
Data not yet available.
SECTION 13. Disposal Considerations
L-NMMA (citrate)
Waste Disposal Method
Dispose in accordance with local, state and federal regulations.
SECTION 14. Transport Information
L-NMMA (citrate)
DOT Proper Shipping Name
Additional Transport Information
Transport in accordance with local, state, and federal regulations.
SECTION 15. Regulatory Information
L-NMMA (citrate)
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The data given here is based on current knowledge and experience. The purpose of this safety data sheet is to describe the
products in terms of their safety requirements. The data does not signify any guarantee with regard to the product's
properties.
SECTION 16. Other Information
L-NMMA (citrate)
For research use only, not for human or veterinary clinical use.
DISCLAIMER: This information is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information,
and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of
the information for their particular purposes.
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