Creation Date: 08-31-2007
Revision Date: 08-31-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Mix B Purgeable Gases Method 624
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01
Version #
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Mixture
CAS #
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N9331061
Item #
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Methanol solution containing trace solvents
Synonym(s)
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent PEL TLV
ETHYL CHLORIDE 75-00-3 0.1 - 1 1000 ppm 100
METHYL BROMIDE (BROMOMETHANE) 74-83-9 0.1 - 1 5 ppm 1
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CHLOROMETHANE 74-87-3 0.1 - 1 50 ppm 50
VINYL CHLORIDE 75-01-4 0.1 - 1 1
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METHANOL (METHYL ALCOHOL) 67-56-1 > 90 200 ppm 200
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Non-hazardous component(s) CAS # Percent
TRICHLOROFLUOROMETHANE 75-69-4 0.1 - 1
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3. Hazards Identification
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Health: 2*
HMIS RATINGS
Flammability: 3
Physical hazard: 0
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Health: 2
NFPA RATINGS
Flammability: 3
Instability: 0
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4. First Aid Measures
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
Material ID 17642 Material Name Mix B Purgeable Gases Method 624
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MSDS US
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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5. Fire Fighting Measures
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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Handling
Keep away from heat and sources of ignition.
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
Material TWA STEL
Mix B Purgeable Gases Method 624 200 ppm 250 ppm
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
CHLOROMETHANE 74-87-3 50 ppm TWA
ETHYL CHLORIDE 75-00-3 100 ppm TWA
METHYL BROMIDE 74-83-9 1 ppm TWA
(BROMOMETHANE)
VINYL CHLORIDE 75-01-4 1 ppm TWA
OSHA - Final PELs - Time Weighted Averages (TWAs)
CHLOROMETHANE 74-87-3 100 ppm TWA
ETHYL CHLORIDE 75-00-3 1000 ppm TWA; 2600 mg/m3 TWA
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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Hand protection
gloves
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Eye protection
goggles If splashes are likely to occur, wear:
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9. Physical & Chemical Properties
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Important health, safety and environmental information
51.8 掳F (11 掳C) estimated
Flash Point
Material ID 17642 Material Name Mix B Purgeable Gases Method 624
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867.2 掳F (464 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
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148.1 掳F (64.5 掳C) estimated
Boiling Point
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2.1 (butyl acetate = 1)
Evaporation Rate
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-144.4 掳F (-98 掳C) estimated
Melting Point
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Characteristic pungent odor
Odor Threshold
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0.79 g/l 1.1 (air = 1)
Vapor Density
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128.9273 hPa estimated
Vapor Pressure
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100 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Further information
Stable at normal conditions
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11. Toxicological Information
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Dermal LD50 (Rabbit): 15800 mg/kg
Other Toxicological
Inhalation LC50 (Rat): 64000 mg/kg/4h
Information
Oral LD50 (Mouse): 7300 mg/kg
Oral LD50 (Rat): 5628 mg/kg
Potential Dermal Absorption
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Acute Toxicity
NIOSH - Selected LD50s and LC50s
CHLOROMETHANE 74-87-3 Inhalation LC50 Rat: 5300 mg/m3/4H; Inhalation
LC50 Mouse: 2200 mg/kg/6H; Oral LD50 Rat: 1800
mg/kg
ETHYL CHLORIDE 75-00-3 Inhalation LC50 Rat: 152 g/m3/2H; Inhalation LC50
Mouse: 146 g/m3/2H
METHYL BROMIDE 74-83-9 Inhalation LC50 Rat: 302 mg/kg/8H; Inhalation LC50
(BROMOMETHANE) Mouse: 1540 mg/m3/2H; Oral LD50 Rat: 214 mg/kg
VINYL CHLORIDE 75-01-4 Inhalation LC50 Rat: 18 pph/15M; Oral LD50 Rat:
500 mg/kg
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Carcinogenicity
IARC - Group 1 (Carcinogenic to Humans)
VINYL CHLORIDE 75-01-4 Supplement 7, 1987; Monograph 19, 1979
OSHA - Hazard Communication Carcinogens
VINYL CHLORIDE 75-01-4 Present
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Carcinogenicity Data
OSHA Select Carcinogen
Material
IARC Group 1 Carcinogen - Humans
NTP Known Carcinogen
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CHLOROMETHANE
Ingredient(s)
- ACGIH Not Classified Carcinogen
ETHYL CHLORIDE
- ACGIH Animal Carcinogen
METHYL BROMIDE (BROMOMETHANE)
- ACGIH Not Classified Carcinogen
VINYL CHLORIDE
- OSHA Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
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Symptoms and Target Organs
NIOSH - Pocket Guide - Target Organs
CHLOROMETHANE 74-87-3 CNS, liver, kidneys, reproductive system (in animals:
lung, liver and forestomach tumors)
ETHYL CHLORIDE 75-00-3 liver, kidneys, respiratory system, CVS, CNS
METHYL BROMIDE 74-83-9 skin, eyes, CNS, respiratory system (in animals: lung,
(BROMOMETHANE) liver and forestomach tumors)
VINYL CHLORIDE 75-01-4 liver, CNS, blood, lymphatic system, respiratory
system (liver cancer)
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12. Ecological Information
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Ecotoxicity
Ecotoxicity - Freshwater Fish Species Data
METHYL BROMIDE 74-83-9 96 Hr LC50 bluegill: 1.4 mg/L (Static)
(BROMOMETHANE)
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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14. Transportation Information
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US DOT
Methanol
Proper shipping name DOT
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3
Labels required
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Other Information
According to IATA respectively ICAO exempt from regulations up to 1 per each inner packaging and
15 per each outer packaging. DOT regulated, small quantity provisions apply (see 49CFR173.4)
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15. Regulatory Information
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CERCLA/SARA Section 313
Mix B Purgeable Gases Method 624
Material
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METHANOL (METHYL ALCOHOL)
Ingredient(s)
Material ID 17642 Material Name Mix B Purgeable Gases Method 624
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US Federal Regulations
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
CHLOROMETHANE 74-87-3 100 lb final RQ; 45.4 kg final RQ
ETHYL CHLORIDE 75-00-3 100 lb final RQ; 45.4 kg final RQ
METHYL BROMIDE 74-83-9 1000 lb final RQ; 454 kg final RQ
(BROMOMETHANE)
VINYL CHLORIDE 75-01-4 1 lb final RQ; 0.454 kg final RQ
CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
METHYL BROMIDE 74-83-9 1000 lb TPQ
(BROMOMETHANE)
CERCLA/SARA - Section 313 - Emission Reporting
CHLOROMETHANE 74-87-3 1.0 % de minimis concentration
ETHYL CHLORIDE 75-00-3 1.0 % de minimis concentration
METHYL BROMIDE 74-83-9 1.0 % de minimis concentration
(BROMOMETHANE)
VINYL CHLORIDE 75-01-4 0.1 % de minimis concentration
OSHA - Specifically Regulated Chemicals
VINYL CHLORIDE 75-01-4 1 ppm PEL; 5 ppm STEL; 0.5 ppm Action Level
(Cancer suspect agent - see 29 CFR 1910.1017)
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State Regulations
California - Proposition 65 - Developmental Toxicity
CHLOROMETHANE 74-87-3 developmental toxicity, initial date 3/10/00
METHYL BROMIDE 74-83-9 developmental toxicity, initial date 1/1/93 (as a
(BROMOMETHANE) structural fumigant)
California - Proposition 65 - No Significant Risk Levels (NSRL)
ETHYL CHLORIDE 75-00-3 150 g/day NSRL
VINYL CHLORIDE 75-01-4 3 g/day NSRL
Connecticut - Carcinogenic Substances
VINYL CHLORIDE 75-01-4 Present
Massachusetts - Right To Know List
CHLOROMETHANE 74-87-3 Present
ETHYL CHLORIDE 75-00-3 Present
METHYL BROMIDE 74-83-9 Extraordinarily hazardous
(BROMOMETHANE)
VINYL CHLORIDE 75-01-4 Carcinogen; Extraordinarily hazardous; Teratogen
Massachusetts - Toxics Use Reduction Act
CHLOROMETHANE 74-87-3 CERCLA and 313 chemical
ETHYL CHLORIDE 75-00-3 CERCLA and 313 chemical
METHYL BROMIDE 74-83-9 CERCLA and 313 chemical
(BROMOMETHANE)
VINYL CHLORIDE 75-01-4 CERCLA and 313 chemical
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International Regulations
Canada - WHMIS - Ingredient Disclosure List
CHLOROMETHANE 74-87-3 1 % (English Item 1027, French Item 507)
ETHYL CHLORIDE 75-00-3 1 % (English Item 705, French Item 497)
VINYL CHLORIDE 75-01-4 0.1 % (English Item 1685, French Item 538)
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16. Other Information
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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Material ID 17642 Material Name Mix B Purgeable Gases Method 624
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MSDS US
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