Creation Date: 07-03-2007
Revision Date: 07-05-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Standard Butanetriol Internal in Pyridine, 5mL
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01
Version #
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Mixture
CAS #
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N9331072
Item #
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Pyridine solution containing a trace element
Synonym(s)
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent PEL TLV
PYRIDINE 110-86-1 > 90 5 ppm 1
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Non-hazardous component(s) CAS # Percent
1,2,4-BUTANETRIOL 3068-00-6 < 0.01
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3. Hazards Identification
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Emergency Overview
Combustible Avoid contact and inhalation.
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Potential Short Term Health Effects
Skin
Contact causes skin irritation.
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Eyes
Contact may irritate or burn eyes.
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Inhalation
May be harmful by inhalation.
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Target Organs
Kidney. Liver.
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Health: 2
NFPA RATINGS
Flammability: 3
Instability: 0
Material ID 16951 Material Name Standard Butanetriol Internal in Pyridine, 5mL
1/ 5
MSDS US
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4. First Aid Measures
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.If skin irritation persists, call a physician and
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Rinse
thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Inhalation
Move to fresh air. Oxygen or artificial respiration if needed. Call a physician or Poison Control
Centre immediately.
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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5. Fire Fighting Measures
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Suitable extinguishing media
Do not use a solid water stream as it may scatter and spread fire. Use extinguishing measures that
are appropriate to local circumstances and the surrounding environment.
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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Handling
Keep away from heat and sources of ignition.
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
Material TWA
Standard Butanetriol Internal in Pyridine, 5mL 1 ppm
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
PYRIDINE 110-86-1 1 ppm TWA
OSHA - Final PELs - Time Weighted Averages (TWAs)
PYRIDINE 110-86-1 5 ppm TWA; 15 mg/m3 TWA
Material ID 16951 Material Name Standard Butanetriol Internal in Pyridine, 5mL
2/ 5
MSDS US
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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Hand protection
gloves
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Eye protection
goggles If splashes are likely to occur, wear:
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9. Physical & Chemical Properties
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General Information
Form
Liquid.
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Color
colorless
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Odor
strong pungent
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Important health, safety and environmental information
68 掳F (20 掳C) estimated
Flash Point
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899.6 掳F (482 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
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239.9 掳F (115.5 掳C) estimated
Boiling Point
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-43.6 掳F (-42 掳C) estimated
Melting Point
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0.65
Octanol Water
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8.5, conc: 0.2M (aqueous solution)
pH
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2.73 (air = 1)
Vapor Density
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26.6642 hPa estimated
Vapor Pressure
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100 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Further information
Stable at normal conditions
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11. Toxicological Information
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Dermal LD50 (Rabbit): 1121 mg/kg
Other Toxicological
Inhalation LC50 (Rat): 28500 mg/m3/1h
Information
Oral LD50 (Mouse): 1500 mg/kg
Oral LD50 (Rat): 891 mg/kg
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Acute Toxicity
NIOSH - Selected LD50s and LC50s
PYRIDINE 110-86-1 Inhalation LC50 Rat: 28500 mg/m3/1H; Oral LD50
Rat: 891 mg/kg; Oral LD50 Mouse: 1500 mg/kg;
Dermal LD50 Rabbit: 1121 mg/kg
Material ID 16951 Material Name Standard Butanetriol Internal in Pyridine, 5mL
3/ 5
MSDS US
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Carcinogenicity Data
ACGIH Animal Carcinogen
Material
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PYRIDINE
Ingredient(s)
- ACGIH Animal Carcinogen
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Symptoms and Target Organs
NIOSH - Pocket Guide - Target Organs
PYRIDINE 110-86-1 CNS, liver, kidneys, skin, GI tract, eyes
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12. Ecological Information
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Ecotoxicity
Ecotoxicity - Freshwater Algae Data
PYRIDINE 110-86-1 24 Hr EC50 freshwater algae (Tetrahymena
pyriformis): 520 mg/L
Ecotoxicity - Freshwater Fish Species Data
PYRIDINE 110-86-1 96 Hr LC50 fathead minnow: 93.8 mg/L
(flow-through); 96 Hr LC50 carp:26.0 mg/L
Ecotoxicity - Water Flea Data
PYRIDINE 110-86-1 48 Hr LC50 water flea: 520 mg/L
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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14. Transportation Information
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US DOT
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Other Information
DOT regulated, small quantity provisions apply (see 49CFR173.4) According to IATA respectively
ICAO exempt from regulations up to 1 each per each inner packaging and 6 each per each outer
packaging.
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15. Regulatory Information
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CERCLA/SARA Section 313
Standard Butanetriol Internal in Pyridine, 5mL
Material
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PYRIDINE
Ingredient(s)
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US Federal Regulations
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
PYRIDINE 110-86-1 1000 lb final RQ; 454 kg final RQ
CERCLA/SARA - Section 313 - Emission Reporting
PYRIDINE 110-86-1 1.0 % de minimis concentration
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State Regulations
Massachusetts - Right To Know List
PYRIDINE 110-86-1 Present
Massachusetts - Toxics Use Reduction Act
PYRIDINE 110-86-1 CERCLA and 313 chemical
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International Regulations
Canada - WHMIS - Ingredient Disclosure List
PYRIDINE 110-86-1 1 % (English Item 1374, French Item 1459)
Material ID 16951 Material Name Standard Butanetriol Internal in Pyridine, 5mL
4/ 5
MSDS US
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16. Other Information
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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Material ID 16951 Material Name Standard Butanetriol Internal in Pyridine, 5mL
5/ 5
MSDS US
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