Creation Date: 08-31-2007
Revision Date: 08-31-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Mix C Method 624
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01
Version #
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Mixture
CAS #
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N9331062
Item #
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Methanol solution containing trace organics
Synonym(s)
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent PEL TLV
Benzene 71-43-2 0.1 - 1 10 ppm 0.5
ETHYLBENZENE 100-41-4 0.1 - 1 100 ppm 100
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DICHLOROBROMOMETHANE 75-27-4 0.1 - 1
TRANS-1,3-DICHLOROPROPENE 10061-02-6 0.1 - 1
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METHANOL (METHYL ALCOHOL) 67-56-1 > 90 200 ppm 200
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Non-hazardous component(s) CAS # Percent
1,1,1-TRICHLOROETHANE 71-55-6 0.1 - 1
Toluene 65266-80-0 0.1 - 1
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2-CHLOROETHYL VINYL ETHER 110-75-8 0.1 - 1
CIS-1,3-DICHLOROPROPENE 10061-01-5 0.1 - 1
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3. Hazards Identification
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Health: 2*
HMIS RATINGS
Flammability: 3
Physical hazard: 0
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Health: 2
NFPA RATINGS
Flammability: 3
Instability: 0
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4. First Aid Measures
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.If skin irritation persists, call a physician and
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Rinse
thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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5. Fire Fighting Measures
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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Handling
Keep away from heat and sources of ignition.
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
Material TWA STEL
Mix C Method 624 200 ppm 250 ppm
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
1,1,1-TRICHLOROETHANE 71-55-6 350 ppm TWA
Benzene 71-43-2 0.5 ppm TWA
ETHYLBENZENE 100-41-4 100 ppm TWA
OSHA - Final PELs - Time Weighted Averages (TWAs)
1,1,1-TRICHLOROETHANE 71-55-6 350 ppm TWA; 1900 mg/m3 TWA
Benzene 71-43-2 10 ppm TWA (apply only to exempt industry
segments)
ETHYLBENZENE 100-41-4 100 ppm TWA; 435 mg/m3 TWA
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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Hand protection
gloves
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Eye protection
goggles If splashes are likely to occur, wear:
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9. Physical & Chemical Properties
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Important health, safety and environmental information
51.8 掳F (11 掳C) estimated
Flash Point
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867.2 掳F (464 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
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148.1 掳F (64.5 掳C) estimated
Boiling Point
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2.1 (butyl acetate = 1)
Evaporation Rate
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-144.4 掳F (-98 掳C) estimated
Melting Point
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Characteristic pungent odor
Odor Threshold
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0.79 g/l 1.1 (air = 1)
Vapor Density
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128.1459 hPa estimated
Vapor Pressure
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98.8 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Further information
Stable at normal conditions
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11. Toxicological Information
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Dermal LD50 (Rabbit): 15800 mg/kg
Other Toxicological
Inhalation LC50 (Rat): 64000 mg/kg/4h
Information
Oral LD50 (Mouse): 7300 mg/kg
Oral LD50 (Rat): 5628 mg/kg
Potential Dermal Absorption
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Acute Toxicity
NIOSH - Selected LD50s and LC50s
1,1,1-TRICHLOROETHANE71-55-6 Inhalation LC50 Rat: 18000 ppm/4H; Inhalation LC50
Mouse: 3911 mg/kg/2H; Oral LD50 Rat: 9600 mg/kg;
Oral LD50 Mouse: 6 g/kg
Benzene 71-43-2 Inhalation LC50 Rat: 10000 ppm/7H; Oral LD50 Rat:
930 mg/kg; Oral LD50 Mouse: 4700 mg/kg; Dermal
LD50 Rabbit: >9400 L/kg
DICHLOROBROMOMETHANE
75-27-4 Oral LD50 Rat: 430 mg/kg; Oral LD50 Mouse: 450
mg/kg
ETHYLBENZENE 100-41-4 Oral LD50 Rat: 3500 mg/kg; Dermal LD50 Rabbit:
17800 L/kg
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Carcinogenicity
IARC - Group 1 (Carcinogenic to Humans)
Benzene 71-43-2 Supplement 7, 1987; Monograph 29, 1982
OSHA - Hazard Communication Carcinogens
Benzene 71-43-2 Present
DICHLOROBROMOMETHANE 75-27-4 Present
ETHYLBENZENE 100-41-4 Present
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Carcinogenicity Data
OSHA Select Carcinogen
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IARC Group 1 Carcinogen - Humans
NTP Known Carcinogen
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1,1,1-TRICHLOROETHANE
Ingredient(s)
- ACGIH Not Classified Carcinogen
Benzene
- OSHA Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
DICHLOROBROMOMETHANE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
ETHYLBENZENE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
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Symptoms and Target Organs
NIOSH - Pocket Guide - Target Organs
1,1,1-TRICHLOROETHANE 71-55-6 skin, CNS, CVS, eyes, liver
Benzene 71-43-2 eyes, skin, respiratory system, blood, CNS, bone
marrow (leukemia)
ETHYLBENZENE 100-41-4 eyes, respiratory system, skin, CNS
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12. Ecological Information
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Ecotoxicity
Ecotoxicity - Freshwater Fish Species Data
1,1,1-TRICHLOROETHANE 71-55-6 96 Hr LC50 fathead minnow: 42.3 mg/L
(flow-through);96 Hr LC50 bluegill sunfish (juvenile):
72 mg/L (Static);96 Hr LC50 sheepshead minnow: 53
mg/L
Benzene 71-43-2 96 Hr LC50 fathead minnow: 12.6 mg/L
(flow-through);96 Hr LC50 rainbow trout: 5.3 mg/L
(flow-through);96 Hr LC50 bluegill: 22 mg/L (Static)
ETHYLBENZENE 100-41-4 96 Hr LC50 rainbow trout: 14.0 mg/L (Static);96 Hr
LC50 fathead minnow: 9.09 mg/L (flow-through);96
Hr LC50 bluegill: 150.0 mg/L (Static)
Ecotoxicity - Microtox Data
ETHYLBENZENE 100-41-4 30 min EC50 Photobacterium phosphoreum: 9.68
mg/L
Ecotoxicity - Water Flea Data
1,1,1-TRICHLOROETHANE 71-55-6 48 Hr EC50 water flea: >530 mg/L
Benzene 71-43-2 48 Hr EC50 water flea: 356 mg/L (Static)
ETHYLBENZENE 100-41-4 48 Hr EC50 water flea: 2.1 mg/L
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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14. Transportation Information
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US DOT
Methanol
Proper shipping name DOT
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3
Labels required
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Other Information
According to IATA respectively ICAO exempt from regulations up to 1 per each inner packaging and
15 per each outer packaging. DOT regulated, small quantity provisions apply (see 49CFR173.4)
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15. Regulatory Information
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CERCLA/SARA Section 313
Mix C Method 624
Material
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METHANOL (METHYL ALCOHOL)
Ingredient(s)
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US Federal Regulations
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
1,1,1-TRICHLOROETHANE 71-55-6 1000 lb final RQ; 454 kg final RQ
Benzene 71-43-2 10 lb final RQ (receives an adjustable RQ of 10 lbs
based on potential carcinogenicity in August 14, 1989
final rule); 4.54 kg final RQ (receives an adjustable
RQ of 10 lbs based on potential carcinogenicity in
August 14, 1989 final rule)
DICHLOROBROMOMETHANE 75-27-4 5000 lb final RQ; 2270 kg final RQ
ETHYLBENZENE 100-41-4 1000 lb final RQ; 454 kg final RQ
CERCLA/SARA - Section 313 - Emission Reporting
1,1,1-TRICHLOROETHANE 71-55-6 1.0 % de minimis concentration
Benzene 71-43-2 0.1 % de minimis concentration
DICHLOROBROMOMETHANE 75-27-4 0.1 % de minimis concentration
ETHYLBENZENE 100-41-4 0.1 % de minimis concentration
OSHA - Specifically Regulated Chemicals
Benzene 71-43-2 1 ppm PEL; 5 ppm STEL; 0.5 ppm Action Level
(Cancer hazard, Flammable - see 29 CFR
1910.1028)
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State Regulations
California - Proposition 65 - Developmental Toxicity
Benzene 71-43-2 developmental toxicity, initial date 12/26/97
California - Proposition 65 - No Significant Risk Levels (NSRL)
Benzene 71-43-2 6.4 g/day NSRL (oral); 13 g/day NSRL (inhalation)
DICHLOROBROMOMETHANE 75-27-4 5 g/day NSRL
Connecticut - Carcinogenic Substances
Benzene 71-43-2 Present
Massachusetts - Right To Know List
1,1,1-TRICHLOROETHANE 71-55-6 Present
Benzene 71-43-2 Carcinogen; Extraordinarily hazardous
DICHLOROBROMOMETHANE 75-27-4 Carcinogen; Extraordinarily hazardous
ETHYLBENZENE 100-41-4 Present
Massachusetts - Toxics Use Reduction Act
1,1,1-TRICHLOROETHANE 71-55-6 CERCLA and 313 chemical
Benzene 71-43-2 CERCLA and 313 chemical
DICHLOROBROMOMETHANE 75-27-4 CERCLA and 313 chemical
ETHYLBENZENE 100-41-4 CERCLA and 313 chemical
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International Regulations
Canada - WHMIS - Ingredient Disclosure List
1,1,1-TRICHLOROETHANE71-55-6 0.1 % (English Item 1610, French Item 1644)
Benzene 71-43-2 0.1 % (English Item 153, French Item 277)
DICHLOROBROMOMETHANE 75-27-4 1 % (English Item 219, French Item 325)
ETHYLBENZENE 100-41-4 0.1 % (English Item 697, French Item 854)
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16. Other Information
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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