FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 1 of 11
IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
Company:
Sabre Corporation P/L
Address:
75 South Creek Road
Dee Why
NSW, 2099
AUS
Telephone: (+61 2) 9982 0100
Fax: (+61 2) 9972 0747
CHEMWATCH HAZARD RATINGS
Flammability:
Toxicity:
Body Contact:
Reactivity:
Chronic:
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
SYNONYMS
SHIPPING NAME
NONE
Product Name: Fudge Head Paint Professional - Oxidation Colour
Other Names: N-phenyl-p-phenylenediamine is being
introduced on a low volume chemical
permit granted under section 21U of the
Industrial Chemicals (Notification and
Assessment) Act 1989
CAS RN No(s): None
UN Number: None
Packing Group: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule Number: S6
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 2 of 11
IDENTIFICATION ...
USE
Hair colour product.
Product must not be used for dyeing eyelashes or eyebrows.
PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
Cream with mild ammonia odour; mixes with water.
Viscosity 38000-42000 mPa.s.
Boiling Point (掳C): Not available.
Melting Point (掳C): Not available.
Vapour Pressure (kPa): Not available.
Specific Gravity: Not available
Flash Point (掳C): Not applicable
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Solubility in Water (g/L): Miscible
INGREDIENTS
NAME CAS RN %
ammonium hydroxide 1336-21-6 9-12
propylene glycol 57-55-6 <10^
1-tetradecanol 112-72-1 <10^
p-phenylenediamine 106-50-3 <1
m-phenylenediamine 108-45-2 <1
N-phenyl-p-phenylenediamine 101-54-2 <1^
resorcinol 108-46-3 <1^
2,5-diaminotoluene sulfate 615-50-9 <1^
1-naphthol 90-15-3 <1^
HC Yellow No.5 56932-44-6 <1^
additives, unregulated, including balance
conditioners, emulsifiers, chelating agents
perfume, solubilisers, colorants
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
The liquid is discomforting to the gastro-intestinal tract and may be harmful if
swallowed
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Considered an unlikely route of entry in commercial/industrial environments
EYE
The liquid is highly discomforting to the eyes and capable of causing pain and
severe conjunctivitis. Corneal injury may develop, with possible permanent
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FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 3 of 11
HEALTH HAZARD ...
impairment of vision, if not promptly and adequately treated
The vapour is discomforting to the eyes
The material may produce severe irritation to the eye causing pronounced
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
The liquid is discomforting to the skin and is capable of causing skin
sensitisation and allergic skin reactions which may lead to dermatitis from
repeated exposures over long periods
The material may accentuate any pre-existing skin condition
INHALED
The vapour is discomforting to the upper respiratory tract
Inhalation hazard is increased at higher temperatures.
Inhalation of high concentrations of vapour may cause breathing difficulty,
tightness in chest.
Inhalation of vapour may aggravate a pre-existing respiratory condition
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and by
inhalation of vapours especially at higher temperatures.
Sensitisation may give severe responses to very low levels of exposure, i.e.
hypersensitivity. Sensitised persons should not be allowed to work in situations
where exposure may occur.
Sensitisation reactions may appear suddenly after repeated
symptom free exposures
FIRST AID
SWALLOWED
If poisoning occurs, contact a doctor or Poisons Information Centre.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconsciousness
路 Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Immediately hold eyelids apart and flush the eye continuously with running
water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 4 of 11
HEALTH HAZARD ...
路 Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
路 Transport to hospital, or doctor.
ADVICE TO DOCTOR
Treat symptomatically.
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
ES TWA is NOHSC Exposure Standard Australia
OES is British Occupational Exposure Standard
TLVTWA is USAACGIH Exposure Standard
None assigned. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m鲁): 17 mg/m鲁
If the breathing zone concentration of ANYof the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc: (%)
ammonium hydroxide 25 17 12
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANYof the components listed below is
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FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 5 of 11
PRECAUTIONS FOR USE ...
exceeded, "Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m鲁): 12 mg/m鲁
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
p-phenylenediamine 1.4167 1 0
m-phenylenediamine 1.4167 1 0
INGREDIENT DATA
AMMONIUMHYDROXIDE:
TLVTWA: 25 ppm, 17 mg/m鲁; STEL: 35 ppm, 24 mg/m鲁
ES TWA: 25 ppm, 17 mg/m鲁; ES STEL: 35 ppm, 24 mg/m鲁
OES TWA: 25 ppm, 18 mg/m鲁; STEL: 35 ppm, 25 mg/m鲁
MAK value: 20 ppm, 14 mg/m鲁
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
Odour Threshold Value: Variouslyreported as 0.019 ppm and 55 ppm;
AIHAValue 16.7 ppm (detection)
IDLH Level: 500 ppm
NOTE: Detector tubes for ammonia, measuring in excess of 1 ppm, are
commerciallyavailable.
The TLV-TWA is thought to be protective against irritation of the eyes and
respiratory tract and minimise discomfort among workers that are not
inured to its effects and systemic damage. Acclimatised persons are able
to tolerate prolonged exposures of up to 100 ppm without symptoms. Marked
irritation has been seen in persons exposed to ammonia concentrations
between 50 and 100 ppm onlywhen the exposures involved sudden
concentration peaks which do not permit short-term acclimatisation. The
detoxification capacity of the liver is significant since the amount of
ammonia formed endogenouslyin the intestines markedlyexceeds that from
external sources.
Human exposure effects, at vapour concentrations of about:
----------------------------------------------------------------------
ppm Possible Effects
------------------------------------------------------------------------
5 minimal irritation
9-50 nasal dryness, olfactory fatigue and moderate irritation
125-137 definite nose, throat and chest irritation
140 slight eye irritation
150 laryngeal spasm
500 30 minute exposures may produce cyclic hypernea, increased blood
pressure and pulse rate, and upper respiratory tract irritation
which may persist for 24 hours
700 immediate eye irritation
1500-10000 dyspnea, convulsive coughing, chest pain, respiratory spasm,
pink frothy sputum, rapid asphyxia and delayed pulmonary oedema
which may be fatal. Other effects include runny nose, swelling
of the lips, restlessness, headache, salivation, nausea,
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FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 6 of 11
PRECAUTIONS FOR USE ...
vomiting, glottal oedema, pharyngitis, tracheitis, and speech
difficulties. Bronchopneumonia, asphyxiation due to spasms,
inflammation, and oedema of the larynx, may be fatal. Residual
effects include hoarseness, productive cough, and decreased
respiratory function
>2500 severe eye irritation, with swelling of the eyelids,
lachrymation, blepharospasm, palpebral oedema, increased
intraocular pressure, oval semi-dilated, fixed pupils, corneal
ulceration (often severe) and temporary blindness. Depending on
duration of exposure, there may be destruction of the
epithelium, corneal and lenticular opacification, and iritis
accompanied by hypopyon or haemorrhage and possible loss of
pigment from the posterior layer of the iris. Less severe
damage is often resolved. In the case of severe damage,
symptoms may be delayed; late complications including
persistent oedema, vascularisation and corneal scarring,
permanent opacity, acute angle glaucoma, staphyloma, cataract,
and atrophy of the retina, iris, and symblepharon.
Long-term exposure to sub-acute concentrations or single exposures to
high concentrations may produce chronic airway dysfunction, alveolar
disease, bronchiolitis, bronchiectasis, emphysema and anxiety neuroses
P-PHENYLENEDIAMINE:
TLVTWA: 0.1 mg/m鲁 A4 [ACGIH]
PEL TWA: 0.1 mg/m鲁 [OSHAZ1] (SKIN)
ES TWA: 0.1 mg/m鲁 Sensitiser
TLVTWA: 0.1 mg/m鲁 A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
OES TWA: 0.1 mg/m鲁
MAK value: 0.1 mg/m鲁
- as total dust: collected by a sampler with a suction velocity of
1.25 m/s +/- 10%.
Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparablylarger
danger of toxicity than their inhalation. To avoid health risks when handling
such substances, meticulous cleaning of the skin, hair and clothing is
imperative.
Designated S in List of MAK values: Danger of sensitization
MAK Category II Peak Limitation: For substances with systemic effects and with a
half-life in humans of less than two hours.
Allows excursions of 2 times the MAK value, for 30 minutes (on average), four
times per shift.
MAK IIIB: Substances suspected of having carcinogenic potential
MAK Group D: Classification as to the effect of the substance on the developing
embryo/foetus is not yet possible because although data may indicate a trend,
they are not sufficient for a final evaluation.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 25 mg/m鲁
.
p-Phenylenediamine is a known dermal and possible respiratory sensitiser
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FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 7 of 11
PRECAUTIONS FOR USE ...
in humans and cause local dermatitis, urticaria, asthma and inflammatory
reactions of the respiratory tract. Lachrymation, opthalmia and permanent
blindness after eye contact have been described.
Topical applications of (oxidised) p-phenylenediamine to rats has produced
local skin tumours at the site of application or may cause tumours distant
from the site, especiallyof the mammary gland of female rats.
Exposure at or below the recommended level is thought to provide
protection from respiratory and skin sensitisation and to protect against
blood dyscrasia and excess risk of occupational cancer. Even though this
limit may be sufficientlylow to minimise the number of people who may
become sensitised it may not be low enough to prevent exacerbation of
pre-existing asthma. Askin notation was deleted in 1991 because there was
no definitive data to demonstrate that absorption of the substance through
the skin produced systemic damage.
M-PHENYLENEDIAMINE:
TLVTWA: 0.1 mg/m鲁 A4 [ACGIH]
TLVTWA: 0.1 mg/m鲁 A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
ES TWA: 0.1 mg/m鲁 Skin Sensitiser
Exposure limits with "skin" notation indicate that vapour and liquid may be
absorbed through intact skin. Absorption by skin may readilyexceed vapour
inhalation exposure. Symptoms for skin absorption are the same as for
inhalation. Contact with eyes and mucous membranes may also contribute to
overall exposure and may also invalidate the exposure standard.
Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparablylarger
danger of toxicity than their inhalation. To avoid health risks when handling
such substances, meticulous cleaning of the skin, hair and clothing is
imperative.
MAK IIIB: Substances suspected of having carcinogenic potential
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
The recommendation has considered a no-effect-level of 6 mg/kg/day
(in a subchronic rat study) and assumed a respiratory exchange of 10 m3
for a 70 kg adult during an 8-hour day. On this basis it is thought that
exposure at or below the recommended level provides a sufficient safety
margin to minimise the potential for liver damage as suggested by animal
studies. Workers who come in contact with m-phenylenediamine during its
production may experience a slight burning and itching of the skin and
allergic skin reactions.
ENGINEERING CONTROLS
Use in a well-ventilated area
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectivelyremove the contaminant.
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FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 8 of 11
PRECAUTIONS FOR USE ...
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air)
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of veryhigh rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood - local control only
motion
Simple theory shows that air velocity falls rapidlywith distance away from the
opening of a simple extraction pipe. Velocity generallydecreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
Refer also to protective measures for the other component used with the product.
Read both MSDS before using; store and attach MSDS together.
PERSONAL PROTECTION
EYE
Safetyglasses with side shields; or as required, Chemical goggles. Contact
lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.
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FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 9 of 11
PRECAUTIONS FOR USE ...
HANDS/FEET
Wear protective gloves, eg. PVC.
OTHER
Overalls.
Eyewash unit.
RESPIRATOR
Respiratory protection may be required when ANY"Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor (Min) Half-Face Respirator Full-face Respirator
10 xES AK-AUS -
AK-PAPR-AUS -
20 xES - AK-AUS
- AK-PAPR-AUS
100 xES - AK-2
- AK-PAPR-2
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and SafetyAdvisor.
SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Plastic container
路 Check that containers are clearly labelled
STORAGE INCOMPATIBILITY
Avoid storage with acids and oxidising agents.
Avoid metallic bowls and stirrers.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 10 of 11
SAFE HANDLING ...
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Do not store any tint after it has been mixed with developer; the
container may rupture.
TRANSPORTATION
No restrictions.
SPILLS AND DISPOSAL
MINOR SPILLS
Slippery when spilt.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Slippery when spilt.
Minor hazard.
路 Clear area of personnel.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Control personal contact by using protective equipment as required.
路 Prevent spillage from entering drains or water ways.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
路 Wash area and prevent runoff into drains or waterways.
路 If contamination of drains or waterways occurs, advise emergency services.
DISPOSAL
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Management Authority for disposal.
路 Bury residue in an authorised landfill.
路 Recycle containers if possible, or dispose of in an authorised landfill.
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
There is no restriction on the type of extinguisher which may be used.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves for fire only.
路 Prevent, by any means available, spillage from entering drains or water
continued...
FUDGE HEAD PAINT PROFESSIONAL - OXIDATION COLOUR
ChemWatch Material Safety Data Sheet CHEMWATCH 4904-23
Issue Date: Tue 8-May-2001 CD 2003/3 Page 11 of 11
SAFE HANDLING ...
courses.
路 Use fire fighting procedures suitable for surrounding area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
路 The material is not readily combustible under normal conditions.
路 However, it will break down under fire conditions and the organic component
may burn.
路 Not considered to be a significant fire risk.
路 Heat may cause expansion or decomposition with violent rupture of containers.
路 Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
Other decomposition products include carbon dioxide (CO2) , sulfur oxides (SOx)
, hydrogen sulfide (H2S) and nitrogen oxides (NOx)
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result
HAZCHEM
None
CONTACT POINT
COMPANYCONTACT
(+61 2) 9982 0100
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEWZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: 0800 764 766
NZ EMERGENCYSERVICES: 111
End of Report
Issue Date: Tue 8-May-2001
Print Date: Mon 22-Sep-2003
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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