UNLEADED SKYSCRAPER
ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
UNLEADED SKYSCRAPER
SYNONYMS
Manufacturer's Code 850041
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
Hair lacquer. Application is by spray atomisation from a hand held aerosol pack
SUPPLIER
Company: Sabre Corporation P/L
Address:
75 South Creek Road
Dee Why
NSW, 2099
AUSTRALIA
Telephone: (+61 2) 9982 0100
Fax: 02 9972 0747
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Highly flammable.
Irritating to eyes.
Risk of explosion if heated under confinement.
SAFETY
Keep away from sources of ignition. No smoking.
Keep container in a well ventilated place.
Avoid exposure - obtain special instructions before use.
Do not empty into drains.
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ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 2 of 12
Section 2 - HAZARDS IDENTIFICATION ...
Keep container tightly closed.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
ethanol 64-17-5 >60
N-octylacrylamide/ t-butylaminoethyl methacrylate resin Not Avail. <10^
monoisobutanolamine 124-68-5 <10^
dimethyl cyclosiloxanes 69430-24-6 <10^
rosin acrylate <10
cocodimonium hydroxypropyl hydrolysed hair keratin <10
fragrance <1
hydrocarbon propellant 68476-85-7. 30-60
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
Section 4 - FIRST AID MEASURES
SWALLOWED
鈥? Immediately give a glass of water.
鈥? First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.
EYE
If this product comes in contact with eyes:
鈥? Wash out immediately with water.
鈥? If irritation continues, seek medical attention.
鈥? Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
Wash with soap and water.
INHALED
鈥? If fumes or combustion products are inhaled remove from contaminated area.
鈥? Lay patient down. Keep warm and rested.
鈥? Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
鈥? Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
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UNLEADED SKYSCRAPER
ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 3 of 12
Section 4 - FIRST AID MEASURES ...
鈥? Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
鈥? Water spray or fog.
鈥? Foam.
鈥? Dry chemical powder.
鈥? BCF (where regulations permit).
鈥? Carbon dioxide.
FIRE FIGHTING
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? May be violently or explosively reactive.
鈥? Wear breathing apparatus plus protective gloves.
鈥? Prevent, by any means available, spillage from entering drains or water
course.
鈥? If safe, switch off electrical equipment until vapour fire hazard removed.
鈥? Use water delivered as a fine spray to control fire and cool adjacent area.
鈥? DO NOT approach containers suspected to be hot.
鈥? Cool fire exposed containers with water spray from a protected location.
鈥? If safe to do so, remove containers from path of fire.
鈥? Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
鈥? Liquid and vapour are highly flammable.
鈥? Severe fire hazard when exposed to heat or flame.
鈥? Vapour forms an explosive mixture with air.
鈥? Severe explosion hazard, in the form of vapour, when exposed to flame or
spark.
鈥? Vapour may travel a considerable distance to source of ignition.
鈥? Heating may cause expansion or decomposition with violent container rupture.
鈥? Aerosol cans may explode on exposure to naked flames.
鈥? Rupturing containers may rocket and scatter burning materials.
鈥? Hazards may not be restricted to pressure effects.
鈥? May emit acrid, poisonous or corrosive fumes.
鈥? On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include carbon dioxide (CO2) and
nitrogen oxides (NOx)
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ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 4 of 12
Section 5 - FIRE FIGHTING MEASURES ...
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result
HAZCHEM
2Y
Personal Protective Equipment
PERSONAL PROTECTION EQUIPMENT
Breathing apparatus.
Chemical splash suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Shut off all possible sources of ignition and increase ventilation.
Wipe up.
MAJOR SPILLS
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? May be violently or explosively reactive.
鈥? Wear breathing apparatus plus protective gloves.
鈥? Prevent, by any means available, spillage from entering drains or water
course.
Shut off all possible sources of ignition and increase ventilation.
鈥? If safe, leaking/damaged cans should be placed in a container outdoors, away
from all the ignition sources, until pressure has dissipated.
鈥? Undamaged cans should be gathered and stowed safely.
Absorb or cover spill with sand, earth, inert material or vermiculite.
Collect, using a spark-free shovel, and seal in labelled drums for disposal
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
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UNLEADED SKYSCRAPER
ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 5 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES ...
From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 8 metres
IERG Number 49
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk
of harmful exposure. This zone assumes that random changes in wind direction
confines the vapour plume to an area within 30 degrees on either side of the
predominant wind direction, resulting in a crosswind protective action distance
equal to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with
those closest to the spill and working away from the site in the downwind
direction. Within the protective action zone a level of vapour concentration
may exist resulting in nearly all unprotected persons becoming incapacitated
and unable to take protective action and/or incurring serious or irreversible
health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the
incident, within which a high probability of localised wind reversal may
expose nearly all persons without appropriate protection to life-threatening
concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less,
such as a drum (jerrican or box with inner containers). Larger packages leaking
less than 200 litres and compressed gas leaking from a small cylinder are also
considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of
greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne"
compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Avoid smoking, naked lights, heat or ignition sources
Wash hands with water after handling.
SUITABLE CONTAINER
Aerosol dispenser.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers
STORAGE REQUIREMENTS
Keep out of reach of children.
Store in approved flammable liquid storage area.
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UNLEADED SKYSCRAPER
ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 6 of 12
Section 7 - HANDLING AND STORAGE ...
No smoking, naked lights, heat or ignition sources.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available for ethanol as (CAS: 64-17-5) / (CAS: 68476-85-7) / (CAS: 68476-86-8)
None assigned. Refer to individual constituents.
ODOUR SAFETY FACTOR (OSF)
OSF=0.16 (hydrocarbon propellant)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 As "A" for 50-90% of
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of being
tested
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into
consideration reproductive end points that are clearly below the thresholds for
other toxic effects. Occupational reproductive guidelines (ORGs) have been
suggested as an additional standard. These have been established after a
literature search for the reproductive no-observed-adverse effect-level (NOAEL)
and the lowest-observed-adverse-effect-level (LOAEL). In addition the US EPA's
procedures for risk assessment for hazard identification and dose-response
assessment as applied by NIOSH were used in the creation of such limits.
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UNLEADED SKYSCRAPER
ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
TLV
Ingredient ORG UF Endpoint CR Adeq
ethanol 1880 mg/m鲁 NA NA NA Yes
These exposure guidelines have been derived from a screening level of risk
assessment and should not be construed as unequivocally safe limits. ORGS
represent an 8-hour time-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996)
INGREDIENT DATA
ETHANOL:
TLV TWA: 1000 ppm A4 [ACGIH]
PEL TWA: 1000 ppm, 1900 mg/m鲁 [OSHA Z1]
TLV TWA: 1000 ppm, 1880 mg/m鲁 A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
ES TWA: 1000 ppm, 1880 mg/m鲁
OES TWA: 1000 ppm, 1920 mg/m鲁
MAK value: 500 ppm, 960 mg/m鲁
MAK Category II Peak Limitation: For substances with systemic effects and with a
half-life in humans of less than two hours.
Allows excursions of 2 times the MAK value, for 30 minutes (on average), four
times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
Odour Threshold Value: 49-716 ppm (detection), 101 ppm (recognition)
IDLH Level: 3300 ppm (lower explosive limit)
Eye and respiratory tract irritation do not appear to occur at exposure
levels of less than 5000 ppm and the TLV-TWA is thought to provide an
adequate margin of safety against such effects.
Experiments in man show that inhalation of 1000 ppm caused slight symptoms
of poisoning and 5000 ppm caused strong stupor and morbid sleepiness.
Subjects exposed to 5000 ppm to 10000 ppm experienced smarting of the
eyes and nose and coughing. Symptoms disappeared within minutes.
Inhalation also causes local irritating effects to the eyes and
upper respiratory tract, headaches, sensation of heat intraocular
tension, stupor, fatigue and a need to sleep.
At 15000 ppm there was continuous lachrymation and coughing.
HYDROCARBON PROPELLANT:
PEL TWA: 1000 ppm, 1800 mg/m鲁 [OSHA Z1]
hydrocarbon propellant, as liquified petroleum gas
TLV TWA: 1000 ppm, 1800 mg/m鲁
ES TWA: 1000 ppm, 1800 mg/m鲁
OES TWA: 1000 ppm, 1750 mg/m鲁; STEL: 1250 ppm, 2180 mg/m鲁
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UNLEADED SKYSCRAPER
ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
PERSONAL PROTECTION
EYE
None under normal operating conditions.
HANDS/FEET
None under normal operating conditions.
OTHER
No special equipment needed when handling small quantities
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Substance
________________________________________
ethanol
BUT YL A
NITRILE+P VC A
PE/EVAL/ PE A
NEOPRE NE A
NITRI LE A
P VC B
NATURAL+NEOPRE NE C
NATURAL RUBB ER C
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove,
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
of gloves which might otherwise be unsuitable following long-term or frequent
use. A qualified practitioner should be consulted.
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
ENGINEERING CONTROLS
Use in a well-ventilated area
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ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 9 of 12
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear colourless fragrant liquid; mixes with water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): 78 (ethanol)
Melting Range (掳C): Not Available Specific Gravity (water=1): <1 (ethanol)
Solubility in water (g/L): Miscible pH (as supplied): 7
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): >60 Evaporation Rate: <1 Ether=1
Relative Vapour Density (air=1): 1.59 (ethanol) Flash Point (掳C): 13 (ethanol)
Lower Explosive Limit (%): 3.3 (ethanol) Upper Explosive Limit (%): 19.0 (ethanol)
Autoignition Temp (掳C): 363 (ethanol) Decomposition Temp (掳C): Not Available
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
鈥? Elevated temperatures.
鈥? Presence of open flame.
鈥? Product is considered stable.
鈥? Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Small amounts or low dose rates are regarded as
practically non-harmful
The liquid is discomforting to the gastro-intestinal tract and may cause
dizziness, disorientation, mental confusion, slurred speech if swallowed
in large quantity.
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ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION ...
EYE
The material may produce severe irritation to the eye causing pronounced
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
Not considered to cause discomfort through normal use.
The material may cause skin irritation after prolonged or repeated exposure and
may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis.
Histologically there may be intercellular oedema of the spongy layer
(spongiosis) and intracellular oedema of the epidermis.
INHALED
Not considered to cause discomfort through normal use.
Acute effects from inhalation of high concentrations of vapour are pulmonary
irritation, including coughing, with nausea; central nervous system depression -
characterised by headache and dizziness, increased reaction time, fatigue and
loss of co-ordination.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are usually by skin contact and inhalation of spray
mist/vapour. WARNING: Aerosol containers may present pressure related hazards.
Unleaded Skyscraper
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
ETHANOL:
TOXICITY IRRITATION
Oral (rat) LD50: 7060 mg/kg Skin (rabbit):20 mg/24hr-moderate
Oral (human) LDLo: 1400 mg/kg Skin (rabbit):400 mg (open)-mild
Oral (man) TDLo: 50 mg/kg Eye (rabbit):100mg/24hr-moderate
Oral (man) TDLo: 1.40 mg/kg Eye (rabbit): 500 mg SEVERE
Oral (woman) TDLo: 256 mg/kg/12 wks
Inhalation (rat) LC50: 20,000 ppm/10h
HYDROCARBON PROPELLANT:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
Refer to data for ingredients, which follows:
ETHANOL:
Hazardous Air Pollutant: No
Fish LC50 (96hr.) (mg/l): 13480
Algae IC50 (72hr.) (mg/l): 1450
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ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 11 of 12
Section 12 - ECOLOGICAL INFORMATION ...
log Kow (Sangster 1997): -0.3
BOD5: 63%
ThOD: 2.1
Half-life Soil - High (hours): 24
Half-life Soil - Low (hours): 2.6
Half-life Air - High (hours): 122
Half-life Air - Low (hours): 12.2
Half-life Surface water - High (hours): 26
Half-life Surface water - Low (hours): 6.5
Half-life Ground water - High (hours): 52
Half-life Ground water - Low (hours): 13
Aqueous biodegradation - Aerobic - High (hours): 26
Aqueous biodegradation - Aerobic - Low (hours): 6.5
Aqueous biodegradation - Anaerobic - High (hours): 104
Aqueous biodegradation - Anaerobic - Low (hours): 26
Aqueous biodegradation - Removal secondary treatment - High (hours): 67%
Photooxidation half-life water - High (hours): 3.20E+05
Photooxidation half-life water - Low (hours): 8020
Photooxidation half-life air - High (hours): 122
Photooxidation half-life air - Low (hours): 12.2
log Kow : -0.31- -0.32
Half-life (hr) air : 144
Half-life (hr) H2O surface water : 144
Henry's atm m3 /mol: 6.29E-06
BOD 5 if unstated: 0.93-1.67,63%
COD : 1.99-2.11,97%
ThOD : 2.1
When ethanol is released into the soil it readily and quickly biodegrades
but may leach into ground water; most is lost by evaporation. When
released into water the material readily evaporates and is biodegradable.
Ethanol does not bioaccumulate to an appreciable extent.
The material is readily degraded by reaction with photochemically produced
hydroxy radicals; release into air will result in photodegradation and wet
deposition.
HYDROCARBON PROPELLANT:
No data for hydrocarbon propellant.
Section 13 - DISPOSAL CONSIDERATIONS
鈥? Consult State Land Waste Management Authority for disposal.
鈥? Discharge contents of damaged aerosol cans at an approved site.
鈥? Allow small quantities to evaporate.
鈥? DO NOT incinerate or puncture aerosol cans.
鈥? Bury residues and emptied aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
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ChemWatch Material Safety Data Sheet CHEMWATCH 67468
Issue Date: Mon 28-Feb-2005 CD 2004/4 Page 12 of 12
Section 14 - TRANSPORTATION INFORMATION ...
Shipping Name:
AEROSOLS
Dangerous Goods Class: 2.1
UN/NA Number: 1950
ADR Number: None
Packing Group: None
Labels Required: flammable gas
Additional Shipping Information:
International Transport Regulations:
IMO: 1950
HAZCHEM
2Y
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Mon 28-Feb-2005
Print Date: Mon 28-Feb-2005
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