Material Safety Data Sheet
POWERPLY SUPREME SMOOTH
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : POWERPLY SUPREME SMOOTH
Product code : 36SUSM601
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Roof Sheeting
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Solid ply rolls. Not applicable under normal conditions of use. Generally not required under normal
conditions of use.
Acute Potential Health Effects/ Routes of Entry
Inhalation Not applicable under normal conditions of use.
:
Eyes Not applicable under normal conditions of use.
:
Ingestion Not applicable under normal conditions of use.
:
Skin May cause mild irritation.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
This product contains granular materials which may cause mechanical skin, eye or respiratory irritation. The
International Agency for Research on Cancer (IARC) has classified ceramic fiber, fibrous glasswool, and
mineral wool (rockwool and slagwool) as possible human carcinogens (Group 2B) based on sufficient evidence
of carcinogenicity in animals but insufficient data in humans. In the National Toxicology Program's (NTP) 7th
Annual Report on Carcinogens (1994), respirable glasswool was classified as reasonably anticipated to be
carcinogenic. Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC
concludes sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline
silica dust above the TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed
lung injury, silicosis may result from breathing free silica. OSHA considers fibrous glass dust a nuisance dust.
Fibrous glass can cause dermatitis, local irritation. Fillers are encapsulated and not expected to be released
from product under normal conditions of use.
Target Organs: Skin, Eye, Lung
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Asphalt 8052-42-4 30.0 - 60.0
Calcium Carbonate (Limestone) 1317-65-3 15.0 - 40.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 10.0 - 30.0
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Material Safety Data Sheet
POWERPLY SUPREME SMOOTH
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Styrene-butadiene copolymers NJ TSRN# 51721300-5132P 7.0 - 13.0
Fibrous Glass 65997-17-3 5.0 - 10.0
Hydrocarbon rubber NJ TSRN# 51721300-5140P 3.0 - 7.0
Magnesite 546-93-0 1.0 - 5.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Generally not required under normal conditions of use.
Eye contact : Generally not required under normal conditions of use.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Not applicable under normal conditions of use.
Notes to physician : Not applicable.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Hazardous combustion : Hydrogen sulfide and hydrocarbon fractions.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Scrape up and transfer to appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
Store under normal warehouse conditions.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Not required under normal conditions of use.
Hand protection : Use suitable impervious leather gloves and protective apparel to reduce
exposure.
Eye protection : Wear appropriate eye protection.
Skin and body protection : Not required.
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Material Safety Data Sheet
POWERPLY SUPREME SMOOTH
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Protective measures : Other equipment not normally required.
Engineering measures : General ventilation is sufficient.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Asphalt 8052-42-4 ACGIH TWA: 0.5 mg/m3 Inhalable fraction.as
benzene solubles
Calcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.
(Limestone) OSHA PEL: 15 mg/m3 Total dust.
ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Crystalline Silica 14808-60-7 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
(Quartz)/ Silica Sand OSHA TWA: 0.1 mg/m3 Respirable.
OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
Fibrous Glass 65997-17-3 ACGIH TWA: 5 mg/m3 Inhalable fraction.
Magnesite 546-93-0 ACGIH TWA: 10 mg/m3
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Solid ply rolls
Color : Black
Odor : None
pH : Not available.
Vapour pressure : Not available.
Vapor density : Not available.
Melting point/range : > 250 掳 > 121 掳
F, C
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Not available.
Specific Gravity : 1.0
% Volatile Weight : 0%
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Material Safety Data Sheet
POWERPLY SUPREME SMOOTH
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 10 - REACTIVITY / STABILITY
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
No Data Available
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : As purchased, this product, when discarded, is not a listed or characteristic hazardous
waste according to Federal regulations (40 CFR 261). Check local, regional, state or
provincial regulations for applicable requirements for disposal. Any processing, using,
alteration or chemical additions to the product, as purchased, may alter the disposal
requirements. Under Federal regulations, it is the generator's responsibility to
determine if a waste is a hazardous waste. Empty containers may retain product
residue. Do not reuse.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : None present or none present in regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Asphalt 8052-42-4
Calcium Carbonate (Limestone) 1317-65-3
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Fibrous Glass 65997-17-3
Magnesite 546-93-0
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Material Safety Data Sheet
POWERPLY SUPREME SMOOTH
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 0 g/l
exempt solvent)
VOC Method 310 : 0%
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Fibrous Glass 65997-17-3
U.S. State Regulations:
MASS RTK Components : Asphalt 8052-42-4
Calcium Carbonate (Limestone) 1317-65-3
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Fibrous Glass 65997-17-3
Magnesite 546-93-0
Penn RTK Components : Asphalt 8052-42-4
Calcium Carbonate (Limestone) 1317-65-3
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Styrene-butadiene copolymers NJ TSRN# 51721300-5132P
Fibrous Glass 65997-17-3
Hydrocarbon rubber NJ TSRN# 51721300-5140P
NJ RTK Components : Asphalt 8052-42-4
Calcium Carbonate (Limestone) 1317-65-3
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Styrene-butadiene copolymers NJ TSRN# 51721300-5132P
Fibrous Glass 65997-17-3
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
8052-42-4 Asphalt
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
65997-17-3 Fibrous Glass
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 1 0 = Minimum
1 = Slight
Flammability 0
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
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Material Safety Data Sheet
POWERPLY SUPREME SMOOTH
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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