Material Safety Data Sheet
TREMPLY HP4510 ADH. WB 5 Gl
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : TREMPLY HP4510 ADH. WB 5 Gl
Product code : 046404 805
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Coating
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
White. Liquid. No serious effects anticipated under normal conditions of use. Leave area to breathe fresh air.
Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation No serious effects anticipated under normal conditions of use.
:
Eyes Direct contact may cause mild irritation.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause mild irritation.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Ammonia is corrosive. Can cause severe respiratory system irritation, skin and eye burns and damage to eyes.
Methanol (methyl alcohol) may cause adverse liver, kidney, lung, spleen and nervous system damage.
Ingestion may cause visual disturbances including optic nerve damage and blindness. Long term inhalation
exposure to vinyl acetate at high levels (600 ppm) caused nasal tumors in laboratory animals, some of which
were shown to be carcinomas. However, there is no evidence that vinyl acetate may cause cancer in humans.
Fillers are encapsulated and not expected to be released from product under normal conditions of use.
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Polymer NJ TSRN# 51721300-5688P 40.0 - 70.0
Water 7732-18-5 40.0 - 70.0
Dispersion Stabilizer NJ TSRN# 51721300-5689P 5.0 - 10.0
Sodium polyacrylate 9003-04-7 0.5 - 1.5
Ammonia 7664-41-7 0.5 - 1.5
Methanol 67-56-1 0.5 - 1.5
Vinyl acetate 108-05-4 - <1.0
1/6 046404 805
Material Safety Data Sheet
TREMPLY HP4510 ADH. WB 5 Gl
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Get medical attention. Do not induce vomiting.
Notes to physician : Not applicable.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not applicable.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : This product is not expected to burn under normal conditions of use.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : This product not expected to ignite under normal conditions of use.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Transfer to appropriate container for disposal. Stop flow. Contain spill. Keep out of water courses. Absorb
spill in sand, earth or other suitable material. Transfer to appropriate container for disposal. Use appropriate
protective equipment. Avoid contact with material.
SECTION 7 - HANDLING AND STORAGE
Handle in compliance with common hygienic practices. Clean hands thoroughly after handling. Keep from
freezing. Do not use in confined or poorly ventilated areas. Prevent inhalation of vapor, ingestion, and contact
with skin eyes and clothing. Keep container closed when not in use. Precautions also apply to emptied
containers. Store in sealed containers in a dry, ventilated warehouse location above freezing.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
2/6 046404 805
Material Safety Data Sheet
TREMPLY HP4510 ADH. WB 5 Gl
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Respiratory protection : Not required under normal conditions of use.Wear appropriate, NIOSH/MSHA
approved respirator with combination particulate filter and vapor/gas
removing cartridge when the ventilation is not adequate or if it is necessary to
abrade or grind surfaces coated with this product.
Hand protection : Use suitable impervious rubber or vinyl gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Other equipment not normally required.Use professional judgment in the
selection, care, and use.
Engineering measures : Not required under normal conditions of use.Use local exhaust when the
general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Ammonia 7664-41-7 ACGIH TWA: 25 ppm
ACGIH STEL: 35 ppm
OSHA PEL: 35 mg/m3
Methanol 67-56-1 ACGIH TWA: 200 ppm
ACGIH STEL: 250 ppm
OSHA PEL: 260 mg/m3
Vinyl acetate 108-05-4 ACGIH TWA: 10 ppm
ACGIH STEL: 15 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : White
Odor : Slight Ammonia
pH : Not available.
Vapour pressure : 17 hPa
Vapor density : Heavier than air
Melting point/range : < 32 掳 < 0 掳
F, C
Freezing point : Not available.
Boiling point/range : > 212 掳 > 100 掳
F, C
Water solubility : Soluble
Specific Gravity : 1.01
% Volatile Weight : 42 %
3/6 046404 805
Material Safety Data Sheet
TREMPLY HP4510 ADH. WB 5 Gl
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Strong acids.Strong bases.
Stability : Stable
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Ammonia, CAS-No.: 7664-41-7
Acute oral toxicity (LD-50 oral) 350 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 5.1 mg/l ( Rat )
Vinyl acetate, CAS-No.: 108-05-4
Acute oral toxicity (LD-50 oral) 2,920 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 3,680 mg/l ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Waste not regulated under RCRA. Incinerate at EPA approved facility or dispose of
waste in compliance with state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Ammonia 7664-41-7
Methanol 67-56-1
Vinyl acetate 108-05-4
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Ammonia 7664-41-7
4/6 046404 805
Material Safety Data Sheet
TREMPLY HP4510 ADH. WB 5 Gl
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Methanol 67-56-1
Vinyl acetate 108-05-4
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 17 g/l
exempt solvent)
VOC Method 310 : 0%
U.S. State Regulations:
MASS RTK Components : Methanol 67-56-1
Ammonia 7664-41-7
Penn RTK Components : Polymer NJ TSRN# 51721300-5688P
Water 7732-18-5
Dispersion Stabilizer NJ TSRN# 51721300-5689P
Ammonia 7664-41-7
Methanol 67-56-1
NJ RTK Components : Polymer NJ TSRN# 51721300-5688P
Water 7732-18-5
Dispersion Stabilizer NJ TSRN# 51721300-5689P
Sodium polyacrylate 9003-04-7
Ammonia 7664-41-7
Methanol 67-56-1
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
None known.
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 1 0 = Minimum
1 = Slight
Flammability 0
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
5/6 046404 805
Material Safety Data Sheet
TREMPLY HP4510 ADH. WB 5 Gl
Version 1.1 Print Date 09/11/2006
REVISION DATE: 09/01/2006
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
6/6 046404 805
|