Material Safety Data Sheet
DURATREM EP KIT
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
This is a kit that contains the following components:
DURATREM EP CURATIVE (PART A)
DURATREM EP PART B BASE
1/14 104200 804
Material Safety Data Sheet
DURATREM EP CURATIVE (PART A)
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : DURATREM EP CURATIVE (PART A)
Product code : 104200 804
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Curative
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Liquid. May cause slight irritation to the respiratory system. Move to fresh air. If required, artificial
respiration or administration of oxygen can be performed by trained personnel. Remove to fresh air. Get
immediate medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Vapors or liquid may cause tearing, blurred vision, severe irritation, and possible chemical
:
burns.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting. May cause chemical burns to
:
stomach, mouth, nose, and throat.
Skin May cause itching, reddening, inflammation. May cause severe burns, blistering and skin
:
damage. May cause sensitization resulting in irritation, itching and redness. May cause a
rash.
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
May cause sensitization by contact. Prolonged skin contact may cause irritation, burns or dermatitis. Repeated
overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless suitable
engineering controls and/or personal protective equipment are used. May aggravate persons sensitized to
amines. Repeated inhalation of nonyl phenol may cause lung damage. Repeated skin contact with nonyl phenol
may cause skin irritation and dermatitis. Fillers are encapsulated and not expected to be released from product
under normal conditions of use.
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
3/14 000000004109
104200 804
Material Safety Data Sheet
DURATREM EP CURATIVE (PART A)
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
Proprietary Ingredient (Non-hazardous) NJ TSRN# 51721300-5744P 40.0 - 70.0
Calcium Carbonate (Limestone) 1317-65-3 10.0 - 30.0
Nonylphenol 25154-52-3 10.0 - 30.0
Benzyl alcohol 100-51-6 10.0 - 30.0
Tetraethylene pentamine 112-57-2 7.0 - 13.0
N Amino ethyl piperazine 140-31-8 3.0 - 7.0
Tris(dimethylaminomethyl)phenol 90-72-2 3.0 - 7.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Remove to fresh air. Get immediate medical
attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : 131 掳 268 掳
C, F
Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.Nitrogen
products oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
4/14 000000004109
104200 804
Material Safety Data Sheet
DURATREM EP CURATIVE (PART A)
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear NIOSH/MSHA approved vapor respirator with appropriate cartridge
when the vapor concentration is expected to exceed exposure limits indicated
on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear chemical safety goggles and/or face shield to prevent eye contact. Do
not wear contact lenses. Do not touch eyes with contaminated body parts or
materials. Have eye washing facilities readily available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Inspect and replace equipment at regular intervals.Use professional judgment
in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Calcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.
(Limestone) OSHA PEL: 15 mg/m3 Total dust.
ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : Black
Odor : Amine
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
5/14 000000004109
104200 804
Material Safety Data Sheet
DURATREM EP CURATIVE (PART A)
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : > 196 掳C, > 385 掳F
Water solubility : Partially soluble
Specific Gravity : 1.34
% Volatile Weight : 22 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.Epoxies.Isocyanates.Acids.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Nonylphenol, CAS-No.: 25154-52-3
Acute oral toxicity (LD-50 oral) 1,620 mg/kg ( Rat ) 1,600 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 2,140 mg/kg ( Rabbit )
Benzyl alcohol, CAS-No.: 100-51-6
Acute oral toxicity (LD-50 oral) 1,580 mg/kg ( Mouse ) 1,940 mg/kg ( Rabbit ) 3,100 mg/kg (
Rat ) 1,230 - 3,100 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 200 - 300 mg/l for 8 h ( Rat ) 1,000 mg/l for 8 h ( Rat )
Tetraethylene pentamine, CAS-No.: 112-57-2
Acute oral toxicity (LD-50 oral) 2,100 mg/kg ( Rat ) 3,990 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 660 mg/kg ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Contains Aliphatic Amine), 8, UN3267, PG III
6/14 000000004109
104200 804
Material Safety Data Sheet
DURATREM EP CURATIVE (PART A)
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : None present or none present in regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Calcium Carbonate (Limestone) 1317-65-3
OSHA Status: Considered : Irritant
hazardous based on the Corrosive
following criteria:
OSHA Flammability : IIIB
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
< 5 g/l
Regulatory VOC (less water and : 295 g/l
exempt solvent)
VOC Method 310 : 22 %
U.S. State Regulations:
MASS RTK Components : Calcium Carbonate (Limestone) 1317-65-3
Nonylphenol 25154-52-3
Benzyl alcohol 100-51-6
Tetraethylene pentamine 112-57-2
N Amino ethyl piperazine 140-31-8
Penn RTK Components : Proprietary Ingredient (Non- NJ TSRN# 51721300-5744P
hazardous)
Calcium Carbonate (Limestone) 1317-65-3
Nonylphenol 25154-52-3
Benzyl alcohol 100-51-6
Tetraethylene pentamine 112-57-2
N Amino ethyl piperazine 140-31-8
Tris(dimethylaminomethyl)phenol 90-72-2
NJ RTK Components : Proprietary Ingredient (Non- NJ TSRN# 51721300-5744P
hazardous)
Calcium Carbonate (Limestone) 1317-65-3
Nonylphenol 25154-52-3
Benzyl alcohol 100-51-6
Tetraethylene pentamine 112-57-2
7/14 000000004109
104200 804
Material Safety Data Sheet
DURATREM EP CURATIVE (PART A)
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
N Amino ethyl piperazine 140-31-8
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:
1333-86-4 Carbon Black
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 3 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
8/14 000000004109
104200 804
Material Safety Data Sheet
DURATREM EP PART B BASE
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : DURATREM EP PART B BASE
Product code : 104200 804
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
White. Liquid solution. Vapor may irritate respiratory tract. May cause nausea, headaches, and dizziness.
Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation Vapor may irritate respiratory tract. May cause nausea, headaches, and dizziness.
:
Eyes Direct contact may cause mild irritation. May cause temporary injury.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Prolonged or repeated exposure to epoxy resin can cause irritation to skin, eyes, skin sensitization, temporary
eye injury. Certain epoxy resins are reported to be mutagenic in some laboratory tests. Fillers are encapsulated
and not expected to be released from product under normal conditions of use.
Target Organs: Skin, Eye, Ingestion, Lung
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Bisphenol A Polyglycidyl Ether Resin 25068-38-6 > 60.0
Benzyl alcohol 100-51-6 10.0 - 30.0
Titanium dioxide 13463-67-7 5.0 - 10.0
Siloxanes and Silicones 67762-90-7 3.0 - 7.0
Amorphous silica 7631-86-9 1.0 - 5.0
9/14 000000004110
104200 804
Material Safety Data Sheet
DURATREM EP PART B BASE
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : 251 掳 484 掳
C, F
Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Smoke, fumes.Carbon monoxide and carbon dioxide can form.
products
Protective equipment for : Water may be used to cool containers to minimize pressure build-
firefighters up.Use accepted fire fighting techniques. Wear full firefighting
protective clothing, including self-contained breathing apparatus
(SCBA).
Fire and explosion conditions : Closed container, may burst when exposed to extreme heat.Empty
containers may contain ignitable vapors.Vapor concentrations in
enclosed areas may ignite explosively.Vapors may travel to sources of
ignition and flashback.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Store under dry warehouse conditions away from heat and all ignition sources. Store in a cool, well ventilated
area. Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed
when not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use
flame near container. Change soiled work clothes frequently. Clean hands thoroughly after handling.
10/14 000000004110
104200 804
Material Safety Data Sheet
DURATREM EP PART B BASE
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Chemical splash goggles.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use general ventilation and/ or local exhaust to reduce the airborne
contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Amorphous silica 7631-86-9 ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 0.8 mg/m3
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid solution
Color : White
Odor : Alcohol
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Specific Gravity : 1.24
11/14 000000004110
104200 804
Material Safety Data Sheet
DURATREM EP PART B BASE
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
% Volatile Weight : 12 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Epoxy curing agents.Amines and oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Benzyl alcohol, CAS-No.: 100-51-6
Acute oral toxicity (LD-50 oral) 1,580 mg/kg ( Mouse ) 1,940 mg/kg ( Rabbit ) 3,100 mg/kg (
Rat ) 1,230 - 3,100 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 200 - 300 mg/l for 8 h ( Rat ) 1,000 mg/l for 8 h ( Rat )
Amorphous silica, CAS-No.: 7631-86-9
Acute oral toxicity (LD-50 oral) 22,500 mg/kg ( Rat ) 22,500 mg/kg ( Rat ) 15,000 mg/kg (
Mouse )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Recycle or dispose of in compliance with local, provincial and federal regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
None present or none present in regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
12/14 000000004110
104200 804
Material Safety Data Sheet
DURATREM EP PART B BASE
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
Titanium dioxide 13463-67-7
Amorphous silica 7631-86-9
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : IIIB
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of:
< 5 g/l
Regulatory VOC (less water and : 149 g/l
exempt solvent)
VOC Method 310 : 12 %
U.S. State Regulations:
MASS RTK Components : Benzyl alcohol 100-51-6
Titanium dioxide 13463-67-7
Amorphous silica 7631-86-9
Penn RTK Components : Bisphenol A Polyglycidyl Ether Resin 25068-38-6
Benzyl alcohol 100-51-6
Titanium dioxide 13463-67-7
Siloxanes and Silicones 67762-90-7
Amorphous silica 7631-86-9
NJ RTK Components : Bisphenol A Polyglycidyl Ether Resin 25068-38-6
Benzyl alcohol 100-51-6
Titanium dioxide 13463-67-7
Siloxanes and Silicones 67762-90-7
Amorphous silica 7631-86-9
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:
None known.
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
13/14 000000004110
104200 804
Material Safety Data Sheet
DURATREM EP PART B BASE
Version 1. Print Date 03/16/2007
REVISION DATE: 02/26/2007
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
14/14 000000004110
104200 804
|