MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2000, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: CONSTRUCTION AND HOME IMPROVEMENT PRODS
TRADE NAME:
Spot and Stain Remover, Aerosol, 3573
ID NUMBER/U.P.C.:
70-0708-3942-1 00-51131-03573-7 70-0709-1960-3 00-51131-03573-7
ISSUED: April 10, 2000
SUPERSEDES: March 08, 1999
DOCUMENT: 08-7209-3
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1. INGREDIENT C.A.S. NO. PERCENT
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WATER................................... 7732-18-5 70.0 - 80.0
2-BUTOXYETHANOL......................... 111-76-2 10.0 - 20.0
BUTANE.................................. 106-97-8 5.0 - 10.0
PROPANE................................. 74-98-6 1.0 - 5.0
POLYOXYETHYLENE MONOOCTYLPHENYL ETHER... 9036-19-5 0.5 - 1.5
The components of this product are in compliance with the chemical
notification requirements of TSCA.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
2-BUTOXYETHANOL
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2. PHYSICAL DATA
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BOILING POINT:................. N/D
VAPOR PRESSURE:................ N/D
VAPOR DENSITY:................. > 1 Air=1
EVAPORATION RATE:.............. > 1 Ether=1
SOLUBILITY IN WATER:........... N/A
SPECIFIC GRAVITY:.............. 0.91 Water=1
PERCENT VOLATILE:.............. 99.0 %
pH:............................ 7.0
VISCOSITY:..................... N/A
MELTING POINT:................. N/D
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: Spot and Stain Remover, Aerosol, 3573
April 10, 2000 PAGE 2
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2. PHYSICAL DATA (continued)
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APPEARANCE AND ODOR:
Aerosol, A clear aerosol spray with a solvent odor.
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... 40.0 F TCC
FLAMMABLE LIMITS - LEL:........ 1.1 %
FLAMMABLE LIMITS - UEL:........ 10.6 %
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam, Alcohol-type foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head. Water may not
effectively extinguish fire; however, it should be used to keep fire-
exposed containers and surfaces cool and prevent explosive rupture.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 3 FIRE: 1 REACTIVITY: 0 AEROSOL STORAGE: 1
UNUSUAL REACTION HAZARD: none
OSHA FIRE HAZARD CLASS: Class IIIA Combustible Liquid
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Not applicable.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: Spot and Stain Remover, Aerosol, 3573
April 10, 2000 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Evacuate unprotected personnel from hazard area.
Place leaking containers in a well-ventilated area, preferrably in an
exhaust hood, if available, or outdoors.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator. Facility must
be capable of handling aerosol cans.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 227.5 gms/liter.
VOC Less H2O & Exempt Solvents: ca. 875 gms/liter.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity. U.S. EPA Hazardous Waste Number = D001
(Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: Spot and Stain Remover, Aerosol, 3573
April 10, 2000 PAGE 4
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear unvented goggles during operations in which
exposure is likely.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: butyl rubber, polyethylene/polyvinylidene chloride
(Saranex).
RECOMMENDED VENTILATION:
Use with appropriate local exhaust ventilation. Use in a well-
ventilated area. If exhaust ventilation is not adequate, use
appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne concentration
of contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator, full-face organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Wash hands after handling and before eating.
RECOMMENDED STORAGE:
Store in a cool place. Store away from heat. Store out of direct
sunlight. Keep container in well-ventilated area. Contents may be
under pressure, open carefully. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Aerosol container contains flammable gas under pressure. Do not
pierce or burn container, even after use.
HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0
PERSONAL PROTECTION: A
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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WATER................................ NONE NONE NONE NONE
2-BUTOXYETHANOL...................... 25 PPM TWA ACGIH Y
2-BUTOXYETHANOL...................... 25 PPM TWA OSHA Y
BUTANE............................... 800 PPM TWA ACGIH
BUTANE............................... 800 PPM TWA OSHA
PROPANE.............................. 1000 PPM TWA OSHA
PROPANE.............................. 2500 PPM TWA ACGIH
POLYOXYETHYLENE MONOOCTYLPHENYL
ETHER.............................. NONE NONE NONE NONE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: Spot and Stain Remover, Aerosol, 3573
April 10, 2000 PAGE 5
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- OSHA: Occupational Safety and Health Administration
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Moderate Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, itching, and dryness.
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
INHALATION:
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice)
and tenderness of upper abdomen.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: Spot and Stain Remover, Aerosol, 3573
April 10, 2000 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, muscular weakness,
incoordination, slowed reaction time, fatigue, blurred vision,
slurred speech, giddiness, tremors and convulsions.
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SECTION CHANGE DATES
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FIRE AND EXPL. SECTION CHANGED SINCE March 08, 1999 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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