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MSDS Material Safety Data Sheet
CAS

64742-94-5
91-20-3

File Name: sandybrae_com---msds_orange_drhf.asp
                         MATERIAL SAFETY DATA SHEET

For Chemicals, Coatings and Related Materials
"Essentially similar" to form OSHA-20

REVISED 05/15/2006

MANUFACTURER

NAME SANDY BRAE LABORATORIES, INC. EMERGENCY TELEPHONE NUMBERS:
ADDRESS: 119A Sandy Drive MEDICAL OR CHEMTREC (24 HRS)
Newark, DE 19713 800-424-9300
INFORMATION: 302-456-0446



SECTION I - PRODUCT INFORMATION


PRODUCT NAME: UNISOL庐 Liquid Orange DRHF H M I S HAZARD CODES
DESCRIPTION: Orange dye concentrate Health: 1 (Slight)
CLASS: Liquid Flammability: 1 (Slight)
Reactivity: 0 (Minimal)
Personal Protective Equipment: B



SECTION II - INGREDIENTS

INGREDIENT PERCENT* C.A.S. VAPOR PRESSURE
o
MATERIAL DESCRIPTION BY WEIGHT REGISTRY NO. LEL mmHg @ 100 F

Petroleum Hydrocarbon 48.0 64742-94-5 1.8 1.6
Naphthalene 0.4%Max 91-20-3 N/A N/A
Colorant 52.0 Proprietary N/A N/A

*Percentages are approximate and DO NOT constitute a specification
This product is not hazardous as defined in 29 CFR1910.1200




SECTION III - PHYSICAL DATA

BOILING RANGE: N/A FREEZING POINT: < 10F
VAPOR PRESSURE: Below 0.1 @ 100F VAPOR DENSITY: 4.7
SPECIFIC GRAVITY: 1.0 - 1.1 H2O SOLUBILITY: Insoluble
EVAPORATION RATE: Negligible (relative to n-butyl acetate) % VOLATILE BY VOLUME: Zero
APPEARANCE AND ODOR: Dk. orange, almost odorless liquid POUR POINT ASTM D97: <-40F
N-OCTANOL/WATER PARTITION COEFFICIENT: Log Pow expected to be greater than 3


Page 1
SECTION IV - FIRE AND EXPLOSION DATA


FLASH POINT: >200F EXPLOSIVE LIMITS: LEL UEL(% V IN AIR)
METHOD USED: Pensky-Martin ASTM D93 1.8% 11.8%

FLAMMABILITY CLASSIFICATION:
OSHA: Non-Combustible
DOT: Non-Combustible Liquid. Not Regulated

EXTINGUISHING MEDIA: Use water spray to cool fire exposed surfaces and to protect personnel.
Isolate "fuel" supply from fire. Use foam, dry chemical or water spray to extinguish fire. Avoid
spraying water directly into storage containers due to danger of boiling over.

SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH-MSHA approved self-contained breathing
apparatus. Wear impervious clothing. Use water spray to cool and protect exposed
material or overheated containers. Take care not to spread fire with water.



SECTION V - TOXICOLOGICAL INFORMATION

See Section VI No additional information is available



SECTION VI - HEALTH HAZARD DATA

EFFECTS OF OVEREXPOSURE:

PRIMARY ROUTE(S) OF EXPOSURE/ENTRY: Eye contact, skin contact, inhalation, ingestion.

EYES Vapors may irritate the eyes. Liquid is irritating and potentially
damaging to the eyes.

SKIN Liquid may irritate and dry the skin. Prolonged contact may lead
to burns and blisters and may aggravate dermatitis.

INHALATION Vapors may irritate the respiratory tract. May lead to headache,
dizziness, nausea, vomiting and unconsciousness. High vapor
concentrations are anesthetic and may have other central
nervous system effects including death.

INGESTION May lead to headache, dizziness, nausea and abdominal pain.

CHRONIC EFFECTS This product contains naphthalene. The International Agency
for Research on Cancer evaluated naphthalene and concluded that
there was sufficient evidence for carcinogenicity in experimental
animals, but inadequate evidence for cancer in exposed humans.
Accordingly, IARC classified naphthalene as a possible human
Carcinogen (Group 2B).
Page 2
SECTION VI - HEALTH HAZARD DATA (CON'T)


Ecotoxicological data have not been determined specifically for
ECOLOGICAL INFORMATION
this product. Information given is based on a knowledge of the
components and the ecotoxicology of similar products.

MOBILITY Liquid under most environmental conditions. Floats on water. If it
enters soil, it will absorb to soil particles and will not be mobile.

DEGRADABILITY Not established

BIOACCUMULATION Has the potential to bioaccumulate

ECOTOXICITY Not established. Insoluble in water.



SECTION VII - EMERGENCY AND FIRST AIR PROCEDURES

EYE CONTACT: Immediately flush with large amounts of water for 10-15 minutes. SEEK PROMPT
MEDICAL ATTENTION !!!

SKIN CONTACT: Promptly remove all contaminated clothing, shower if necessary. Remove
from skin with proprietary water less hand cleaner or cold cream. Discard
contaminated clothing and shoes.

INHALATION: If dizzy, drowsy or overcome, remove to fresh air. If breathing has stopped,
apply artificial respiration. GET MEDICAL ATTENTION AS SOON AS POSSIBLE !!!

INGESTION: DO NOT INDUCE VOMITING!! GET MEDICAL ATTENTION IMMEDIATELY!!



SECTION VIII - REACTIVITY DATA

STABILITY: Stable
CONDITIONS TO AVOID: Extreme heat, open flames or sparks
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents, strong reducing agents,
Acids
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of Carbon, Oxides of Nitrogen
HAZARDOUS POLYMERIZATION: Will not occur
POLYMERIZATION CONDITIONS TO AVOID: Material not known to polymerize




Page 3
SECTION IX - REGULATORY INFORMATION

This MSDS is in compliance with the OSHA Hazard Communication Standard 29CFR1910.1200.
This MSDS has also been prepared to be in compliance with the Commonwealth of
Pennsylvania's Right-to-Know regulations for chemical manufacturers and should satisfy many
other state Right-to-Know laws.
The chemical ingredient reporting rules for Pennsylvania are more detailed than OSHA regulations
and this MSDS lists the common chemical name and CAS number in Section II for:

Specifically hazardous ingredient >0.01% (OSHA is >0.1%)
Hazardous ingredient >1.0% (OSHA is the same)
Nonhazardous ingredient >3.0% (OSHA does not regulate)

PROPRIETARY entered in the CAS number column declares that the exact identity of the
ingredient(s) listed is proprietary information to United Color Manufacturing, Inc. and/or to our
suppliers. Percentages of ingredients are approximate values for the purpose of hazard and
SARA determination by the product's uses and are not necessarily exact specifications.

DOT Shipping Description: Not Regulated
SARA TITLE II: This product does not contain any Section 313 reportable
Ingredients.
TSCA: All components are in complianced with TSCA Inventory
EINECS: All components in compliance.
DSL: All components registered. Classified as D2B under WHMIS. This
product contains no hazardous materials.
EC CLASSIFICATION: Classified as non-combustible under EC criteria as per DOT
Regulations in SECTION IV.
CERCLA: If this product is accidently spilled, the incident is not subject to
the provisions of the Comprehensive Environmental Response
Compensation And Liability Act (CERCLA).


SECTION X - SPILL OR LEAK PROCEDURES

STEPS FOR MATERIAL SPILLAGE: Remove all sources of ignition (flame, hot surfaces and any
producers of electrical, static or frictional sparks). Wear
appropriate protective clothing (See Section XI). Ventilate area
and try to contain spill by diking with sand or other absorbent
material. Collect spill for disposal be scooping up liquids (if a
large spill) and absorbing with sand or other approved absorbent
materials and dispose of in accordance with local, state and
federal regulations.

WASTE DISPOSAL METHODS: Dispose of in accordance with local, state and federal
regulations.




Page 4
SECTION XI - SPECIAL PROTECTION INFORMATION



RESPIRATORY PROTECTION: OSHA/NIOSH approved self-contained breathing apparatus or
vapor cartridge respirator. (Must be worn if PEL & TLV levels are
exceeded)

VENTILATION: Provide adequate cross air ventilation to keep dust and/or vapor
levels below the PEL & TLV values. (See: Section V)

PROTECTIVE GLOVES: Impervious gloves (rubber or neoprene) to avoid direct skin
contact.

EYE PROTECTION: Splash proof safety goggles

OTHER PROTECTIVE EQUIPMENT: Eyewash station, emergency shower.



SECTION XII - SPECIAL PRECAUTIONS



HANDLING AND SPECIAL PRECAUTIONS:
Overheating may cause container to rupture. Use explosion-proof electrical equipment
Container must be kept closed and ventilation provided to prevent vapor concentration
buildup. Store in a cool, dry place. Do not breathe vapor of get liquid in eyes or on skin or
clothing. Keep away from heat or sources of ignition.

OTHER PRECAUTIONS:
Check all containers for leaks. Wear protective clothing as in Section XI. Avoid prolonged
breathing of vapors of contact with skin. Ensure that all equipment is grounded to prevent
static discharge. Containers of this material may be hazardous when emptied due to solid
or vapor residue. All hazard precautions given in this data sheet must be observed for
empty containers.

SECTION XIII - CONTACT INFORMATION

TECHNICAL CONTACT PERSON: Robert Spring

TECHNICAL CONTACT NUMBER: Telephone 302-456-0446
Fax 302-456-0441


SECTION XIV - Transportation
This material is not a DOT hazardous material. See section IX, 鈥淒OT Shipping Description鈥?.



Page 5

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