Material Safety Data Sheet
TREMCO 830 CLEAR
Version 1.3 Print Date 07/31/2007
REVISION DATE: 07/30/2007
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : TREMCO 830 CLEAR
Product code : 985800 320
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Sealant
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Clear. Non-sag gunnable paste. May cause nausea, headaches, and dizziness. May cause drowsiness,
weakness, and fatigue. May cause moderate irritation to the respiratory system. Leave area to breathe fresh
air. Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and
:
fatigue. May cause moderate irritation to the respiratory system.
Eyes Direct contact may cause mild irritation. Direct contact may cause temporary redness and
:
discomfort.
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal
:
irritation, nausea, and vomiting.
Skin May cause mild irritation.
:
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Prolonged or repeated exposure to xylene may cause defatting, drying, and irritation of the skin, dermatitis,
central nervous system (CNS) effects, heart muscle sensitization and arrhythmia, hearing loss, and brain, liver,
kidney damage. Xylene overexposure may affect fetal development. The International Agency for Research on
Cancer (IARC) has evaluated ethylbenzene and classified it as a possible human carcinogen (Group 2B) based
on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in
exposed humans. Fillers are encapsulated and not expected to be released from product under normal
conditions of use.
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Xylene 1330-20-7 15.0 - 40.0
Styrene-(ethylene-butylene)-styrene
NJ TSRN# 51721300-5027P 15.0 - 40.0
block polymer
Hydrocarbon resin 9011-11-4 10.0 - 30.0
Hydrogenated hydrocarbons 69430-35-9 10.0 - 30.0
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Material Safety Data Sheet
TREMCO 830 CLEAR
Version 1.3 Print Date 07/31/2007
REVISION DATE: 07/30/2007
Polybutene 9003-29-6 7.0 - 13.0
Ethylbenzene 100-41-4 5.0 - 10.0
Styrene-isoprene rubber 68648-89-5 5.0 - 10.0
Polystyrene, hydrogenated 68441-35-0 3.0 - 7.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not available.
Burning rate : Flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Vapors may travel to sources of ignition and flashback.Empty containers
may contain ignitable vapors.Vapor concentrations in enclosed areas
may ignite explosively.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area. Use non-
sparking tools. Scrape up and transfer to appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents
in one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change
soiled work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep
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Material Safety Data Sheet
TREMCO 830 CLEAR
Version 1.3 Print Date 07/31/2007
REVISION DATE: 07/30/2007
container closed when not in use. Since emptied containers retain product residue and vapor, observe
precautions even after container is emptied. Store under dry warehouse conditions away from heat and all
ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Follow respirator manufacturer's directions for respirator use.Wear
appropriate, properly fitted NIOSH/MSHA approved organic vapor or supplied
air respirator when airborne contaminant level(s) are expected to exceed
exposure limits indicated on the MSDS. Follow manufacturer's directions for
respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Xylene 1330-20-7 ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm
OSHA PEL: 435 mg/m3
Ethylbenzene 100-41-4 ACGIH TWA: 100 ppm
ACGIH STEL: 125 ppm
OSHA PEL: 435 mg/m3
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Non-sag gunnable paste
Color : Clear
Odor : Aromatic
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Insoluble
Specific Gravity : 1.01
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Material Safety Data Sheet
TREMCO 830 CLEAR
Version 1.3 Print Date 07/31/2007
REVISION DATE: 07/30/2007
% Volatile Weight : 35 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 4,300 mg/kg ( Rat ) 1,590 mg/kg ( Mouse ) 6,670 mg/kg (
Rat ) 3,523 - 8,600 mg/kg ( Rat ) 5,627 mg/kg ( Mouse )
Acute inhalation toxicity (LC-50) 6,350 mg/l for 4 h ( Rat ) 3,907 mg/l for 6 h ( Mouse ) 8,000
mg/l for 4 h ( Rat )
Ethylbenzene, CAS-No.: 100-41-4
Acute oral toxicity (LD-50 oral) 5,460 mg/kg ( Rat ) 3,500 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 17,800 mg/kg ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Subject to hazardous waste treatment, storage and disposal requirements under
RCRA. Dispose of in a contained chemical landfill in compliance with federal, state
and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (Contains Xylene), 4.1, UN3175, PG II
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Xylene 1330-20-7
Ethylbenzene 100-41-4
SARA 311/312 Hazards : Acute Health Hazard
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Material Safety Data Sheet
TREMCO 830 CLEAR
Version 1.3 Print Date 07/31/2007
REVISION DATE: 07/30/2007
OSHA Hazardous Components :
Xylene 1330-20-7
Ethylbenzene 100-41-4
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 358 g/l
exempt solvent)
VOC Method 310 : 35 %
U.S. State Regulations:
MASS RTK Components : Xylene 1330-20-7
Ethylbenzene 100-41-4
Penn RTK Components : Xylene 1330-20-7
Styrene-(ethylene-butylene)-styrene block NJ TSRN# 51721300-5027P
polymer
Hydrocarbon resin 9011-11-4
Hydrogenated hydrocarbons 69430-35-9
Polybutene 9003-29-6
Ethylbenzene 100-41-4
Styrene-isoprene rubber 68648-89-5
Polystyrene, hydrogenated 68441-35-0
NJ RTK Components : Xylene 1330-20-7
Styrene-(ethylene-butylene)-styrene block NJ TSRN# 51721300-5027P
polymer
Hydrocarbon resin 9011-11-4
Hydrogenated hydrocarbons 69430-35-9
Polybutene 9003-29-6
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:
100-41-4 Ethylbenzene
108-88-3 Toluene
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 3 0 = Minimum
1 = Slight
Flammability 3
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
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Material Safety Data Sheet
TREMCO 830 CLEAR
Version 1.3 Print Date 07/31/2007
REVISION DATE: 07/30/2007
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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