MATERIAL SAFETY DATA SHEET
3735 GREEN ROAD TELEPHONE: (216)292-5000 EMERGENCIES: (216)765-6727 8:30-5:00 EST
BEACHWOOD, OHIO 44122-8068 AFTER HOURS: CHEMTREC (800)424-9300
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SECTION 1
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Order Code: DEV705 805
Product Name: TREMPRO 670 LV PART A
Chemical Name: POLYURETHANE POLYMER
Chemical Family:
Product Code: DEV-705 Date Prepared: 04-AUG-05
MSDS Preparer: R. A. MIKOL Replaces Date: 04-MAY-05
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Section 2 - Molecular Composition
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Common Name and Chemical Name Weight % CAS Number
Exposure Limits
POLYURETHANE POLYMER 65.0-75.0 Trade Secret
OSHA:TWA - STEL -
ACGIH:TWA - STEL -
2,2,4, TRIMETHYL-1,3 PENTANEDIOL ISOBUTYRATE 10.0-20.0 6846-50-0
OSHA:TWA - STEL -
ACGIH:TWA - STEL -
PROPYLENE CARBONATE 10.0-20.0 108-32-7
OSHA:TWA - STEL -
ACGIH:TWA - STEL -
ISOPHORONE DIISOCYANATE 0.1-0.5 4098-71-9
OSHA:TWA 0.005ppm STEL 0.020ppm (skin)
ACGIH:TWA 0.005ppm STEL - (skin)
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Section 3 - Hazards Identification
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Emergency Overview:
Clear liquid. Can cause headache, irritation, nausea, drowsiness,
stupor, coughing spell and allergic respiratory sensitization. If inhaled,
leave to breathe fresh air. Should be observed by physician immediately if
overexposure is severe.
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Potential Hlth Effect/Rte of Entry:
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Inhalation:
Can cause headache, irritation, nausea, drowsiness, stupor, coughing spell
and allergic respiratory sensitization.
Eyes:
Can cause severe irritation, reversible corneal damage.
Ingestion:
May cause gastrointestinal irritation. Aspiration during swallowing or
vomiting may cause lung damage and can be fatal.
Skin:
Can cause irritation, sensitization, dermatitis. Can be absorbed through
skin.
Aggravated Medical Conditions:
Pre-existing eye, skin and respioratory disorders may be aggravated by
exposure.
Acute Health Effects:
See effects described above.
Chronic Health Effects:
Overexposure to isocyanate can cause a decrease in lung function. Skin and
respiratory sensitization is possible. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and
nervous system damage. Intentional misuse by deliberately concentrating and
inhaling contents may be harmful or fatal.
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Section 4 - First Aid Measures
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Inhalation:
Leave area to breathe fresh air. Avoid further overexposure. If symptoms
persist, get medical attention immediately.
Eyes:
Flush immediately with running water for 15 minutes, lifting the upper and
lower lids occasionally. Get medical attention immediately.
Ingestion:
Get medical attention immediately.
Wash area of contact thoroughly with hand cleaner followed by soap and
water. If irritation, rash or other disorders develop, get medical
attention immediately.
Notes to Physician: N/A
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Section 5 - Fire Fighting Measures
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Flash Point: >250F
Method: SETA
Lower Flammability Limit: 4.7% (SOLVENT)
Upper Flammability Limit: 21% (SOLVENT)
Autoignition Temperature: 800F
Extinguishing Media:
If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Fire and Explosion Hazards:
Never use welding or cutting torch on or near container (even empty).
Product, residue or vapor may ignite. See Section 7 for additional
precautions.
Special Fire Fighting Procedures:
During a fire, personnel at the scene are to prevent exposure to fumes
using accepted fire fighting techniques.
Fire Fighting Equipment: N/A
Other Precautions:
Hydrocyanic acid, oxides of nitrogen can form.
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Section 6 - Accidental Release Measures
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Release Response Overview:
Remove sources of ignition immediately. Ventilate to reduce the airborne
contaminant concentration below the exposure limit in Section 2 of the
MSDS. Absorb spill in sand, earth or other suitable material. Transfer to
appropriate container for disposal.
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Section 7 - Handling and Storage
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Handling and Storage Precautions:
Store under normal warehouse conditions. Prevent inhalation of vapor,
ingestion, and contact with skin and eyes. Keep container closed when not
in use. Precautions also apply to emptied containers. Change soiled
workclothes frequently. Clean hands thoroughly after handling. Precautions
also apply to emptied containers. Personal protective equipment must be
worn during maintenance or repair of contaminated mixer, reactor, or other
equipment.
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Section 8 - Exposure Controls/Personal Protection
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Respiratory:
Wear appropriate, properly fitted NIOSH/MSHA approved respirator when
airborne contaminant level(s) exceed exposure limits indicated in Section
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2. Select positive pressure supplied air respirator (TC19C or equivalent)
for isocyanates.
Skin:
Protect hands with rubber or other suitable gloves.
Eyes:
Chemical splash goggles.
Face:
Face shield is recommended.
Engineering:
Use local exhaust when the general ventilation is not sufficient to keep
the airborne contaminant concentration below the exposure limit in Section
2 of the MSDS.
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Section 9 - Physical and Chemical Properties
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Odor/Appearance: SOLVENT/CLEAR LIQUID
Color: CLEAR
Physical State: LIQUID
pH: NOT APPLICABLE
Vapor Pressure: .02MMHG@68F(SOLVENT)
Vapor Density: HEAVIER THAN AIR
Boiling Point: 468F (SOLVENT)
Melting Point: NOT APPLICABLE
Freezing Point: NOT DETERMINED
Solubility in Water: CURES
Specific Gravity: 1.008
% Volatile Weight: 15.0
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Section 10 - Reactivity/Stability
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Stability:
Stable
Incompatible Products:
Avoid contact with water, amines, bases, oxidizers, alcohols.
Conditions to Avoid Polymerization:
Hazardous polymerization will not occur.
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Section 11 - Toxicological Information
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Eyes: SEE SECTION 3
Ingestion: " " "
Inhalation: " " "
Skin: " " "
Subchronic: " " "
Chronic: " " "
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Section 12 - Ecological Information
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Ecotoxicological Data: N/A
Chemical Fate: N/A
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Section 13 - Disposal Considerations
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RCRA Class: N/A
Disposal Method:
Dispose of in compliance with federal, state and local regulations.
EPA Reportable Quantities
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N/A
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Section 14 - Transportation Data
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DOT Shipping Name: NOT REGULATED
DOT Hazard Class:
DOT Label:
UN/NA Number:
Packing Group:
Special Provisions:
Packaging
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Exceptions:
Non-Bulk:
Bulk:
Quantity Limitations
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Passenger Aircraft or Railcar:
Cargo Aircraft:
Vessel Stowage Requirements
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Vessel Stowage:
Other Stowage:
Transportation Notes: N/A
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Section 15 - Regulatory Information
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TSCA Status: On the TSCA Inventory
OSHA Status: Considered hazardous based on the following criteria:
Irritant
Sensitizer
Target Organs
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Lung
Skin
Eye
OSHA Hazardous Components CAS Number
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* PROPYLENE OXIDE (METHYL OXIRANE) 75-56-9
ISOPHORONE DIISOCYANATE 4098-71-9
* - CHEMICAL IS LISTED AS AN IARC, NTP, OSHA, or ACGIH CARCINOGEN
Compliance Quantities
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N/A
SARA 311 Ratings
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Immediate Health Hazard: Y
Delayed Health Hazard: Y
Fire Hazard: N
Reactivity Hazard: N
Sudden Release of Pressure Hazard: N
SARA 313 Ingredients CAS Number
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PROPYLENE OXIDE (METHYL OXIRANE) (<0.0005%) 75-56-9
ISOPHORONE DIISOCYANATE 4098-71-9
Proposition 65 Ingredients
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Chemicals known to the State of California to cause cancer,
birth defects and/or other reproductive harm. CAS Number
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Order Code: DEV705 805
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PROPYLENE OXIDE (METHYL OXIRANE) (< 0.0005%) 75-56-9
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Section 16 - Other Information
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FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN.
THE HAZARD INFORMATION HEREIN IS OFFERED SOLELY FOR THE CONSIDERATION
OF THE USER, SUBJECT TO HIS OWN INVESTIGATION OF COMPLIANCE WITH APPLICABLE
REGULATIONS, INCLUDING THE SAFE USE OF THE PRODUCT UNDER EVERY FORESEEABLE
CONDITION.
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