PHOENIX INDUSTRIES INC -- HYDROCHLORIC ACID, 30-40%
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MSDS Safety Information
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FSC: 6810
NIIN: 00-222-9641
MSDS Date: 05/31/2000
MSDS Num: CKSFT
Product ID: HYDROCHLORIC ACID, 30-40%
MFN: 01
Responsible Party
Cage: 0YED2
Name: PHOENIX INDUSTRIES INC
Address: 1519 CHAMBERLAYNE PARKWAY
City: RICHMOND VA 23222
Info Phone Number: 804-264-5183
Emergency Phone Number: (804)264-5183
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Cage: 0YED2
Name: PHOENIX INDUSTRIES INC
Address: 1519 CHAMBERLAYNE PARKWAY
City: RICHMOND VA 23222
Phone: 804-264-5183/FAX: 264-5535
Contract Number: SP0450-00-M-SF83
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Item Description Information
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Item Manager: S9G
Item Name: HYDROCHLORIC ACID,TECHNICAL
Specification Number: O-H-765
Type/Grade/Class: NONE
Unit of Issue: BT
Quantitative Expression: 00000000005PT
UI Container Qty: 4
Type of Container: BOTTLE
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Ingredients
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Cas: 7647-01-0
RTECS #: MW4025000
Name: HYDROGEN CHLORIDE
% low Wt: 30.
% high Wt: 40.
OSHA PEL: C7 MG/M3;C5 PPM
ACGIH TLV: NOT ESTABLISHED
ACGIH STEL: C7.5 MG/M3;C5 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% low Wt: 60.
% high Wt: 67.
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Health Hazards Data
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LD50 LC50 Mixture: LD50-ORAL-RBT: 900 MG/KG (CONC HCL)
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
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IARC: YES
OSHA: NO
Effects of Exposure: INHALATION: CORROSIVE! INHALATION OF VAPORS CAN CAUSE
COUGHING, CHOKING, INFLAMMATION OF THE NOSE, THROAT & UPPER RESPIRATORY
TRACT & IN SEVERE CASES, PULMONARY EDEMA, CIRCULATORY FAILURE, &
DEATH. IN GESTION: CORROSIVE! SWALLOWING CAN CAUSE IMMEDIATE PAIN & BURNS
OF THE THROAT, ESOPHAGUS & GASTROINTESTINAL TRACT. MAY CAUSE NAUSEA,
VOMITING & DIARRHEA. SWALLOWING MAY BE FATAL. SKIN: CORROSIVE! CAN CAUSE
REDNESS, PAIN & SEVERE SKIN BURNS. CONCENTRATED SOLUTIONS CAUSE DEEP
ULCERS & DISCOLOR SKIN. EYE: CORROSIVE! VAPORS ARE IRRITATING & MAY
CAUSE DAMAGE TO THE EYE. CONTACT MAY CAUSE SEVER BURNS & PERMANENT EYE
DAMAGE.
Explanation Of Carcinogenicity: IARC CATEGORY: 3
Signs And Symptions Of Overexposure: INHALATION: CORROSIVE! INHALATION OF
VAPORS CAN CAUSE COUGHING, CHOKING, INFLAMMATION OF THE NOSE, THROAT &
UPPER RESPIRATORY TRACT & IN SEVERE CASES, PULMONARY EDEMA, CIRCULATORY
FAILURE, & DEATH. IN GESTION: CORROSIVE! SWALLOWING CAN CAUSE IMMEDIATE
PAIN & BURNS OF THE THROAT, ESOPHAGUS & GASTROINTESTINAL TRACT. MAY
CAUSE NAUSEA, VOMITING & DIARRHEA. SWALLOWING MAY BE FATAL. SKIN:
CORROSIVE! CAN CAUSE REDNESS, PAIN & SEVERE SKIN BURNS. CONCENTRATED
SOLUTIONS CAUSE DEEP ULCERS & DISCOLOR SKIN. EYE: CORROSIVE! VAPORS ARE
IRRITATING & MAY CAUSE DAMAGE TO THE EYE. CONTACT MAY CAUSE SEVER BURNS
& PERMANENT EYE DAMAGE.
Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING SKIN DISORDERS
OR EYE DISEASE MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS SUBSTANCE.
First Aid: INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, OXYGEN. GET MEDICAL ATTENTION
IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING! GIVE LARGE QUANTI TIES OF
WATER OR MILK IF AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY FLUSH SKIN WITH PLENTY WATER
FOR AT LEAST 15 MINUTES WHILE REMOVING CON TAMINATED CLOTHING & SHOES.
WASH CLOTHING & CLEAN SHOES BEFORE REUSE. GET MEDICAL ATTENTION
IMMEDIATELY. EYE: IMMEDIATELY FLUSH WITH PLENTY WATER FOR AT LEAST 15 MINS,
LIFTING LOWER & EYELIDS OCCASION ALLY. GET MEDICAL ATTENTION IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE
PPE. ISOLATE HAZARD AREA. KEEP UNNECESSARY & UNPROTECTED PERSONNEL FROM
ENTERING. CONTAIN & RECOVER LIQUID WHEN POSSIBLE. NEUTRALIZE WITH
ALKALINE MAT ERIAL (SODA ASH, LIME), THEN ABSORB WITH AN INERT MATERIAL
(E.G., VERMICULITE, DRY SAND, EARTH), & PLACE IN A CHEMICAL WASTE
CONTAINER. DO NOT USE COMBUSTIBLE MATERIALS. DO NOT FLUSH TO SEWER.
Neutralizing Agent: NEUTRALIZE WITH ALKALINE MATERIAL (SODA ASH, LIME),
Waste Disposal Methods: WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING
SHOULD BE HANDLED HAZARDOUS & SENT TO RCRA APPROVED WASTE FACILITY.
PROCESSING, USE OR CONTAMINATION OF PRODUCT MAY CHANGE WASTE MANAGEMENT
OPTIONS. STATE & LOCAL DISPOSAL REGULATIONS DIFFER FROM FEDERAL DISPOSAL
REGULATIONS. DISPOSE OF CONTAINER & UNUSED CONTENTS I/A/W FEDERAL, STATE
REQUIREMENTS.
Handling And Storage Precautions: STORE IN A COOL, DRY, VENTILATED STORAGE AREA
WITH ACID RESISTANT FLOORS & GOOD VENTILATION. PROTECT FROM PHYSICAL
DAMAGE. KEEP OUT OF DIRECT SUNLIGHT & AWAY FROM HEAT, WATER, INCOMPATIBLE
MATERIALS. DO NOT WASH OUT CONTAINER & USE IT FOR OTHER PURPOSES.
Other Precautions: WHEN DILUTING, ACID SHOULD ALWAYS BE ADDED SLOWLY TO WATER
& IN SMALL AMOUNTS. NEVER USE HOT WATER. NEVER ADD WATER TO ACID AS THIS
CAN CAUSE UNCONTROLLED BOILIING & SPLASHING. WHEN OPENING METAL CONT
AINERS, USE NON-SPARKING TOOLS BECAUSE OF POSSIBILITY OF HYDROGEN GAS BEING
PRESENT. EMPTY CONTAINER MAY CONTAIN RESDUE.
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Fire and Explosion Hazard Information
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Extinguishing Media: IF INVOLVED IN A FIRE, USE WATER SPRAY. NEUTRALIZE WITH
SODA ASH OR SLAKED LIME.
Fire Fighting Procedures: WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE
PRESSURE DEMAND OR OTHER PRESSURE MODE. STRUCTURAL FIREFIGHTER'S PROTECTIVE
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CLOTHI NG IS INEFFECTIVE FOR FIRES INVOLVING HYDROCHLORIC ACID. STAY AWAY
FROM ENDS OF TANKS. COOL TANKS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard: NOT CONSIDERED TO BE AN EXPLOSION HAZARD.
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Control Measures
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Respiratory Protection: IF EXPOSURE LIMIT IS EXCEEDED, USE FULL FACEPIECE
RESPIRATOR WITH ACID GAS CARTRIDGE FOR N UP TO 50 TIMES EXPOSURE LIMIT OR
MAXIMUM USE THE APPROPRIATE REGULATORY AGENCY OR RESPIRATOR SUPPLIER RECOMME
NDS. IN EMERGENCIES OR INSTANCES WHERE EXPOSURE LEVELS ARE NOT KNOWN, USE A
POSITIVE PRESSURE, AIR SUPPLIED RESPIRATOR.
Ventilation: A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP
EMPLOYEE EXPOSURE BELOW THE AIRBORNE EXPOSURE LIMITS. LOCAL EXHAUST
VENTILATION PREFERRED.
Protective Gloves: USE RUBBER OR NEOPRENE GLOVES
Eye Protection: USE CHEMICAL SAFETY GOGGLES &/OR FULL FACE SHIELD WHERE
SPLASHING IS POSSIBLE.
Other Protective Equipment: WEAR IMPERVIOUS BOOTS, APRON, COVERALLS AS NEEDED
IN AREAS OF UNUSUAL EXPOSURE TO PREVENT SKIN CONTACT.
Supplemental Safety and Health: CHRONIC EXPOSURE: LONG TERM EXPOSURE TO
CONCENTRATED VAPORS MAY CAUSE EROSION OF TEETH. LONG TERM EXPOSURES SELDOM
OCCUR DUE TO CORROSIVE PROPERTIES OF THE ACID.
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Physical/Chemical Properties
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HCC: C1
Boiling Point: =53.C, 127.4F
B.P. Text: AZEOTROPE @ 109C
Melt/Freeze Pt: =-74.C, -101.2F
Vapor Pres: 190@25C(77F)
Spec Gravity: 1.17 (RANGE 1.15-1.19)
PH: 0.1 @ 1.0 N
Solubility in Water: INFINITE IN WATER W/SLIGH
Appearance and Odor: COLORLESS, FUMING LIQUID. PUNGENT ODOR OF HYDROGEN
CHLORIDE.
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Reactivity Data
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Stability Indicator: N/P & FORMALDEHYDE.
Stability Condition To Avoid: STABLE UNDER ORDINARY CONDITIONS OF USE AND
STORAGE. CONTAINERS MAY BURST WHEN HEATED. AVOID HEAT, DIRECT SUNLIGHT.
Materials To Avoid: CONCENTRATED HYDROCHLORIC ACID IS INCOMPATIBLE WITH &
HIGHLY REACTIVE WITH STRONG BASES, METALS, METAL OXIDES, HYDROXIDES, AMINES,
& OTHER ALKALINE MATERIALS. INCOMPATIBLE WITH MATERIALS SUCH AS CYANIDES,
SULFIDES, SULFITES
Hazardous Decomposition Products: EMITS TOXIC HYDROGEN CHLORIDE FUMES & WILL
REACT WITH WATER OR STEAM TO PRODUCE HEAT & TOXIC & CORROSIVE FUMES. THERMAL
OXIDATIVE DECOMPOSITION PRODUCES TOXIC CHLORINE FUMES & EXPLOSIVE HYDROGEN
GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: INHALATION RAT LC50: 3124 PPM/1H; ORAL RABBIT LD50:
900 MG/KG (HCL CONCENTRATED); INVESTIGATED AS TUMORIGEN, MUTAGEN,
REPRODUCTIVE EFFECTOR.
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Ecological Information
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Ecological: ENVIRONMENTAL FATE: WHEN RELEASED TO SOIL, MATERIAL IS NOT EXPECTED
TO BIODEGRADE. WHEN RELEASED TO SOIL, MAY LEACH INTO GROUNDWATER.
ENVIRONMENTAL TOXICITY: MATERIAL IS EXPECTED TO BE TOXIC TO AQUATI C LIFE.
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MSDS Transport Information
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Transport Information: DOT & ICAO: HYDROCHLORIC ACID, 8, UN1789, PG II
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Regulatory Information
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Sara Title III Information: SARA 302: TPQ = 500 LB (HYDROGEN CHLORIDE
ANHYDROUS), EHS RQ = 5000 LB
Federal Regulatory Information: CERCLA RQ = 5000 LB
State Regulatory Information: NOT PROVIDED
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Other Information
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Transportation Information
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Responsible Party Cage: 0YED2
Trans ID NO: 154445
Product ID: HYDROCHLORIC ACID, 30-40%
MSDS Prepared Date: 05/31/2000
Review Date: 08/11/2000
MFN: 1
Net Unit Weight: 6 LB
Multiple KIT Number: 0
Unit Of Issue: BT
Container QTY: 4
Type Of Container: BOTTLE
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Detail DOT Information
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DOT PSN Code: HJG
DOT Proper Shipping Name: HYDROCHLORIC ACID
Hazard Class: 8
UN ID Num: UN1789
DOT Packaging Group: II
Label: CORROSIVE
Special Provision: A3,A6,B3,B15,N41,T9,T27
Packaging Exception: 154
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 1 L
Max Qty Cargo: 30 L
Vessel Stow Req: C
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Detail IMO Information
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IMO PSN Code: IEX
IMO Proper Shipping Name: HYDROCHLORIC ACID
IMDG Page Number: 8183
UN Number: 1789
UN Hazard Class: 8
IMO Packaging Group: II/III
Subsidiary Risk Label: -
EMS Number: 8-03
MED First Aid Guide NUM: 700
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Detail IATA Information
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IATA PSN Code: NPG
IATA UN ID Num: 1789
IATA Proper Shipping Name: HYDROCHLORIC ACID
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 809
Max Quant Pass: 1L
Max Quant Cargo: 30L
Packaging Note Cargo: 813
Exceptions: A3
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Detail AFI Information
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AFI PSN Code: NPG
AFI Proper Shipping Name: HYDROCHLORIC ACID, SOLUTION
AFI Hazard Class: 8
AFI UN ID NUM: UN1789
AFI Packing Group: II
Special Provisions: P4, A3, A6, N41
Back Pack Reference: A12.3
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HAZCOM Label
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Product ID: HYDROCHLORIC ACID, 30-40%
Cage: 0YED2
Company Name: PHOENIX INDUSTRIES INC
Street: 1519 CHAMBERLAYNE PARKWAY
City: RICHMOND VA
Zipcode: 23222
Health Emergency Phone: (804)264-5183
Label Required IND: Y
Date Of Label Review: 08/11/2000
Status Code: A
Year Procured: 2000
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: POISON! DANGER!. CORROSIVE. LIQUID & MIST CAUSE
SEVERE BURNS TO BODY TISSUE. MAY BE FATA IF SWALLOWED OR INHALED. INHALATION
CAUSES LUNG DAMAGE. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT BREATHE
VAPOR OR MIST. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
STORE IN TIGHTLY CLOSED CONTAINER. REMOVE & WASH CONTAMINATED CLOTHING
PROMPTLY. IN CASE OF CONTACT: FLUSH EYES/SKIN WITH PLENTY WATER FOR AT LEAST
15 MINUTES. REMOVE CLOTHING. DO NOT INDUCE VOMITING.GIVE LARGE QUANTITIES OF
WATER. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. IF INHALED MOVE TO FRESH
AIR. IF NOT BREATHI NG GIVE CPR.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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