MAGNESIUM SULFATE
MSDS Number: M0234 --- Effective Date: 10/29/01
1. Product Identification
Synonyms: Magnesium sulfate (1:1) heptahydrate; Epsom salts; sulfuric acid, magnesium salt
(1:1), heptahydrate; Magnesium sulfate, 7- hydrate
CAS No.: 7487-88-9 (Anhydrous) 10034-99-8 (heptahydrate)
Molecular Weight: 246.47
Chemical Formula: MgSO4.7H2O
Product Codes: J.T. Baker: 2500, 2503, 2504, 2505, 5588
Mallinckrodt: 4200, 5691, 6046, 6066, 7778
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------ ---------
Magnesium Sulfate Anhydrous 7487-88-9 99 - 100% Yes
3. Hazards Identification
Emergency Overview
--------------------------
CAUTION! MAY BE HARMFUL IF SWALLOWED.
J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 1 - Slight
Flammability Rating: 0 - None
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Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT
Storage Color Code: Orange (General Storage)
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Potential Health Effects
----------------------------------
Inhalation:
Dust may be slightly irritating. Sore throat or coughing may occur.
Ingestion:
Since magnesium salts are slowly absorbed, abdominal pain, vomiting and diarrhea may be the
only symptoms. However, if elimination is blocked by bowel blockage or other reasons, CNS
depression, lack of reflexes, hypocalcemia (deficiency of calcium in the blood) may occur.
Skin Contact:
No adverse effects expected but may cause minor skin irritation.
Eye Contact:
No adverse effects expected but dust may cause mechanical irritation.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.
4. First Aid Measures
Inhalation:
Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical
advice.
Skin Contact:
Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get
medical attention if irritation develops or persists.
Eye Contact:
Wash thoroughly with running water. Get medical advice if irritation develops.
Note to Physician:
IV administration of calcium gluconate will partially reverse the effects of acute magnesium
toxicity. Ventricular support with calcium chloride infusion and mannitol forced diuresis has also
been successful.
5. Fire Fighting Measures
Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
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Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
Use protective clothing and breathing equipment appropriate for the surrounding fire.
6. Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in
Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet
sweeping may be used to avoid dust dispersal.
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical
damage. Isolate from incompatible substances. Containers of this material may be hazardous when
empty since they retain product residues (dust, solids); observe all warnings and precautions listed
for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
None established.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as
possible. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the
ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent
edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to dust or mist is apparent and engineering controls are not
feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles
(e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For
emergencies or instances where the exposure levels are not known, use a full-face
positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect
workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance:
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Transparent crystals, or white powder.
Odor:
Odorless.
Solubility:
Very soluble in water.
Density:
1.67 g/ml @ 4C
pH:
Aqueous solution is neutral or slightly acid.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
Not applicable.
Melting Point:
1124C (2055F) Decomposes. Loses all waters of hydration @ 250C (482F)
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage. Loses some moisture on exposure to dry air at
room temperatures.
Hazardous Decomposition Products:
Oxides of sulfur and the contained metal.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Ethoxy ethyl alcohols, arsenates, phosphates, tartrates, lead, barium, strontium, and calcium
Conditions to Avoid:
Heat, moisture, incompatibles.
11. Toxicological Information
No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated
as a mutagen, reproductive effector.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Magnesium Sulfate Anhydrous No No None
(7487-88-9)
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12. Ecological Information
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and
approved waste disposal facility. Processing, use or contamination of this product may change the
waste management options. State and local disposal regulations may differ from federal disposal
regulations. Dispose of container and unused contents in accordance with federal, state and local
requirements.
14. Transport Information
Not regulated.
15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Magnesium Sulfate Anhydrous (7487-88-9) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Magnesium Sulfate Anhydrous (7487-88-9) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Magnesium Sulfate Anhydrous (7487-88-9) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Magnesium Sulfate Anhydrous (7487-88-9) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No
Reactivity: No (Pure / Solid)
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Australian Hazchem Code: No information found.
Poison Schedule: No information found.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.
16. Other Information
NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0
Label Hazard Warning:
CAUTION! MAY BE HARMFUL IF SWALLOWED.
Label Precautions:
Keep container closed.
Wash thoroughly after handling.
Label First Aid:
If swallowed, give several glasses of water to drink to dilute. If large amounts were swallowed, get
medical advice.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 1, 8.
Disclaimer:
*************************************************************************************
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes
no representation as to its comprehensiveness or accuracy. This document is intended only as
a guide to the appropriate precautionary handling of the material by a properly trained
person using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular purpose.
MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES,
EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY
WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE
WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT
TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT
BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE
OF OR RELIANCE UPON THIS INFORMATION.
*************************************************************************************
Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)
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