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MSDS Material Safety Data Sheet
CAS

57-13-6
471-34-1

File Name: gemplers_com---1446.asp
                                                                                                MSDS1446
MATERIAL SAFETY DATA SHEET
Bird-X, Inc.
Product Name: Shake-Away庐

SECTION I - PRODUCT IDENTIFICATION and COMPANY INFORMATION
Shake-Away庐 Original Form Date: 4/2/04
Product Name:
Repellent Granules Last Revision Date: NA
Synonyms:
None Previous Revision Date: NA
CAS Number:
Mixture
Formula:
Not Applicable
Chemical Name:
Product produced from the application of garlic oil and a
Description: natural source of urea to calcium carbonate.
Contact: Bird-X, Inc.
Distributor Information:
Bird-X, Inc. Telephone: (800) 662-5021
300 N. Elizabeth St. Email: sales@bird-x.com
Chicago, IL 60607 Emergency: (800) 424-9300 (Chemtrec)
SECTION II - COMPOSITION/HAZARDOUS INGREDIENTS
OSHA ACGIH
Ingredient Name CAS No. PEL TWA OTHER
Garlic Oil NA None Established None Established N/A

Urea 57-13-6 None Established None Established N/A

Water N/A N/A N/A N/A

TWA = 15mg/m3 TWA = 10 mg/m3
Calcium Carbonate* 471-34-1 N/A

* Exposure limits are based upon non-asbestos/non-silica total nuisance dust standard.
Component Related Regulatory Information
This product does not contain hazardous materials.
SECTION III - PHYSICAL DATA
Boiling Point: Not Applicable % Volatile by Volume: Not Applicable
2.83 Evaporation Rate: Not Applicable
Specific Gravity:
(H2O = 1.0) (Butyl Acetate = 1.0)
Vapor Density: Not Applicable Insoluble
Solubility in Water (% by wt.):
Vapor Pressure: Not Applicable pH: Not Applicable
Appearance & Odor: White to gray-white granules with ammonia/garlic odor.
SECTION IV - FIRE & EXPLOSION DATA
Flash Point: Not Applicable N/A
Explosive Limit in Air (%)**:
Autoignition Temp: Not Applicable
NFPA Codes Fire Fighting Materials:
Health 0 Calcium Carbonate does not support combustion.
Reactivity 0 Use ABC Extinguisher to suppress any
Contact 1 - slight combustion of applied organics.
Flammability 0 Unusual Fire & Explosion Hazard: None
SECTION V - HEALTH EFFECTS DATA
1 of 3
MATERIAL SAFETY DATA SHEET
Bird-X, Inc.
Product Name: Shake-Away庐

Routes of Entry: Inhalation and dermal (skin contact) are the primary routes of exposure.
Signs & Symptoms The primary health hazard listed for this type of product is adverse skin reaction can
of Acute Exposure: occur from extended contact to granules.
Inhalation: Inhalation may cause coughing and sneezing. Nasal passages can become irritated by
repeated exposures.
Calcium carbonate granules can cause irritation or mechanical damage to the eye
Eye Contact:
surface.
Skin Contact: Extended skin contact to garlic oil can result in contact dermatitis or allergic skin
sensitivity. Allergic reactions to skin sensitivity can result in anaphylactic reaction.
Ingestion: Is not considered a route of entry under normal conditions of use.
Chronic Overexposure: Excessive ingestion of calcium carbonate can result in alkalosis and
hypercalcemia.
Chemical Listed as a Carcinogen or Potential Carcinogen:
The Shake- Away product does Not contain any NTP, IARC or OSHA listed carcinogens.
Toxicological Information: specific toxicological data for the materials used in the product are listed:
Acute Toxicity
Rabbit: Oral LD50: 5000 mg/kg, Subcutaneous LD50: 3000-9000 mg/kg
Cattle: Oral MDL50:600-1080 mg/kg
Urea: Guinea Pig: Intravenous LD50: 4800 mg/kg
Rat: Oral LD50: 5000mg/kg
Rat: LD50: Oral 30ml/kg
Rat: Oral 500mg/kg - liver & lung damage
Garlic Oil:
Rat: Oral 100 ml/kg - liver changes
Calcium Carbonate: Not toxic.
Chronic Toxicity
Data is mixed showing contradictory evidence as an experimental carcinogen in animal
Urea: studies.. Some animal study (mice) evidence that it is mutagenic at near lethal levels.
Hematologic effects observed in dog studies. Avoid ingestion by dogs.
Garlic Oil: Potential for asthma with prolonged inhalation of garlic dust or oil mist.
Calcium Carbonate: Not toxic.
SECTION VI - REACTIVITY DATA
Conditions Contributing to Instability: Stable under normal use conditions.
Incompatibility: Avoid contact with open flame and oxidizing agents..
Hazardous Decomposition Products: Thermal decomposition of urea and garlic oil produces irritating
fumes & toxic gases, including Carbon Monoxide, and oxides of Nitrogen and Sulfur.
Conditions Contributing to Polymerization: Not Applicable.
SECTION VII - PRECAUTIONS & SAFE HANDLING
Avoid
Eye Contact:
Avoid prolonged contact with the skin.
Skin Contact:
Avoid
Inhalation:
Avoid Contact
Oxidizing Agents:
Avoid
Open Flame:
Not a USDOT Hazardous Material or Canada Dangerous Good
Shipping Description:
Store away from open flame or other combustible materials.
Storage & Handling:
Eyes: Use goggles or safety glasses when spreading the material to avoid
Safety Equipment:
granules from entering the eyes.
2 of 3
MATERIAL SAFETY DATA SHEET
Bird-X, Inc.
Product Name: Shake-Away庐

Skin: Wear appropriate work gloves to protect skin from extended contact.
Inhalation: Depending upon material condition, wear NIOSH/MSHA approved
respirator to prevent inhalation when spreading the material.
SECTION VIII - EMERGENCY & FIRST AID PROCEDURES

Eye: Flush with water to remove granule particles. If irritation persists, get medical
attention.
Skin: If a rash or persistent irritation or dermatitis occurs, get medical attention.
Inhalation: Remove to fresh air. If irritation is persistent, severe coughing or breathing difficulties
occur, get medical attention.
Ingestion: Not a hazard under normal use of the product.

SECTION IX - SPILL/LEAK CLEAN-UP PROCEDURES
Transportation: The Shake-Away product is not a Hazardous Material as defined by USDOT.
Waste Disposal: The Shake-Away product neither a hazardous waste under the Resource Conservation
& Recovery Act (RCRA) nor a listed Hazardous Material under the Comprehensive
Environmental Response, Compensation and Liability Act (CERCLA). Dispose of
the waste material in an approved landfill in accordance with local, state and federal
regulations.
Spill Actions: Clean up the material using normal equipment. The Shake-Away product is NOT a
reportable substance under the USEPA and USDOT rules.

SECTION X - OTHER INFORMATION


Notice: The information and data herein are believed to be accurate and have been compiled from
sources believed to be reliable. However, no warranty, expressed or implied is given. It is the buyer's
responsibility to ensure that its activities comply with Federal, State and local laws. This information is
furnished for the purpose of compliance with the Occupational Safety & Health Act of 1970, and shall
not be used for any other purpose.




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END OF DOCUMENT




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