SAFE Marine Europe
NANOTECHNOLOGIES
24-Nov-05 鈥? Ver. 1.2
MATERIAL SAFETY DATA SHEET (MSDS)
Area: Europe
EpoSolve SAFE
Product Line: Marine
Universal thinner for SAFE products
Protective
1
IDENTIFICATION OF
Preparation/Product Name EpoSolve SAFE
THE PREPARATION Product Code EPS
AND THE COMPANY Intended use See Technical Data Sheet (for professional use only)
Application Method See Technical Data Sheet
Company Name SAFE Marine Nanotechnologies
Via Casilina 246 (Km. 68,300)
03013 Ferentino (FR) - Italy
Telephone No. +39 0775 393068
Fax No. +39 0775 396828
Emergency Telephone No. +44 191 28 64 488 (UK National Poison Centre)
+39 010 352808 (ITA Poison Centre - Genova "S. Martino")
+39 02 66101029 (ITA Poison Centre - Milano "Niguarda")
+39 06 3054343 (ITA Poison Centre - Roma "Gemelli")
2
COMPOSITION
This product contains the following substances that present a health hazard within the meaning of
AND INFORMATION the Dangerous Substances Directive 67/548/EEC and the Chemicals (Hazard Information and
ON INGREDIENTS Packaging for Supply) Regulations 1999 (2) or have occupational exposure limits detailed in
EH40.
Chemical name CAS no. EC Number % Classification (*)
Solvent naphtha (pet.), light aromatic 64742-95-6 649-356-00-4 50-100 T R45 R65
Acetone 67-64-1 606-001-00-8 0-30 F Xn R11 R20
Toluene 108-88-3 601-021-00-3 0-20 F Xi R11 R36 R66
R67
* The full texts of the phrases are shown in section 16.
3
HAZARD
R11 Highly flammable
IDENTIFICATION R45 May cause cancer
OF THE PRODUCT R65 Harmful: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking
R20 Harmful by inhalation
R36 Irritating to eyes
4
General - In all cases of doubt, or when symptoms persist, seek medical attention. Never give
FIRST AID
anything by mouth to an unconscious person.
MEASURES
Inhalation - Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration/oxygen by trained personnel.
Don鈥檛 give anything by mouth. If unconscious, place in recovery position and seek medical advice.
Eye Contact - Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek medical attention.
Skin Contact - Remove contaminated clothing. Wash skin thoroughly with soap and water or use
a recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion - If accidentally swallowed obtain immediate medical attention. Keep at rest. The
decision to induce vomiting should be taken by a Doctor.
SAFE MARINE
5
FIRE-FIGHTING
Recommended extinguishing media: alcohol resistant foam, CO虏 powder, water spray. Water jet
MEASURES not recommended.
Note: fire will produce dense black smoke. Decomposition products may be hazardous to health.
Avoid exposure and use breathing apparatus as appropriate. Cool closed containers exposed to fire
by spraying with water. Do not allow run off water and contaminants to enter drains or waterways.
6
ACCIDENTAL
Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In
RELEASE MEASURES case of a major spill or spillage in a confined space evacuate the area and check that solvent vapor
levels are below the Lower Explosive Limit before re - entering. Ventilate the area and avoid
breathing vapors. Take the personal protective measures listed in section 8. Contain and absorb
spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed containers
outside buildings and dispose of according to the Waste Regulations. (See section 13). Clean,
preferably with a detergent. Do not use solvents. Do not allow spills to enter drains or
watercourses. If drains, sewers, streams or lakes are contaminated, inform the local water company
immediately. In the case of contamination of rivers, streams or lakes the Environmental Protection
Agency should also be informed.
7
HANDLING AND
Handling - This product contains solvents. Solvent vapors are heavier than air and may spread
STORAGE along floors. Vapors may form explosive mixtures with air. Areas of storage, preparation and
application should be ventilated to prevent the creation of flammable or explosive concentrations
of vapor in air and avoid vapor concentrations higher than the occupational exposure limits.
In Storage - Handle containers carefully to prevent damage and spillage. Naked flames and
smoking should not be permitted in storage areas. It is recommended that fork lift trucks and
electrical equipment are protected to the appropriate standard.
In Use - Avoid skin and eye contact. Avoid inhalation of vapors and spray mists. Observe label
precautions. Use personal protection as shown in section 8. Smoking, eating and drinking should
be prohibited in all preparation and application areas. Never use pressure to empty a container;
containers are not pressure vessels. All sources of ignition (hot surfaces, sparks, open flames etc)
should be excluded from areas of preparation and application. All electrical equipment (including
torches) should be protected (Ex) to the appropriate standard. The product may charge
electrostatically. Always use earthing leads when pouring solvents and transferring product.
Operators should wear clothing which does not generate static electricity (at least 60% natural
fiber) and antistatic footwear; floors should be of conducting type.
Storage - Store in a well ventilated, dry place away from sources of heat and direct sunlight. Store
on concrete or other impervious floor, preferably with bundling to contain any spillage. Do not
stack more than 3 pallets high. Keep container tightly closed. Containers which are opened must be
carefully resealed and kept upright to prevent leakage. Keep in the original container or one of the
same material. Prevent unauthorized access. The requirements of the Highly Flammable Liquids
and Liquefied Petroleum Gases Regulations apply if the flashpoint is between 21掳C and 32掳C.
8
EXPOSURE CONTROL
Engineering Measures - Provide adequate ventilation. Where reasonably practicable this should
& PERS. PROTECTION be achieved by the use of local exhaust ventilation and good general extraction. If these are not
sufficient to maintain concentrations of particulates and any vapor below occupational exposure
limits suitable respiratory protection must be worn.
Exposure Limits - The following occupational exposure limits have been established by the
Health and Safety Executive as published in EH40.
Material Short term (15 min. ave.) Long term (8hr time weighted average)
ppm mg/m鲁 ppm mg/m鲁
Acetone 1500 3620 750 1810 S
Toluene 150 574 50 191 S+
MATERIAL SAFETY DATA SHEET Page 2 www.safenanotech.com
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SAFE MARINE
(M) Maximum Exposure Limit
(S) Occupational Exposure Standard
(R) Suppliers Recommended Limit
(+) There is a risk of absorption through unbroken skin.
Respiratory Protection - When concentrations exceed the exposure limits shown above workers
must wear appropriate respirators approved in accordance with Directive 89/656/EEC and the
Personal Protection Equipment Regulations.
Eye Protection - Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against
the splash of liquids. Eyewear should comply with British Standard 2092.
Hand Protection 鈥? Nitrile rubber gloves should be worn during mixing and application.
Skin Protection - Overalls which cover the body, arms and legs should be worn. Skin should not
be exposed. Barrier creams may help to protect areas which are difficult to cover such as the face
and neck. They should however not be applied once exposure has occurred. Petroleum jelly based
types such as Vaseline should not be used. All parts of the body should be washed after contact.
9
PHYSICAL AND
Physical State Liquid
CHEMICAL Flash Point (deg C) 15
PROPERTIES Viscosity (cSt) 4
Specific Gravity 0.887
Vapor Density Heavier than air
Lower Explosive Limit (LEL) 1.10
Solubility in Water Immiscible
RAQ - to ventilate to 10% of LEL (m 鲁/l) 137
10
STABILITY AND
Stable under recommended storage and handling conditions (see section 7). When exposed to high
REACTIVITY temperatures may produce hazardous decomposition products such as carbon monoxide, carbon
dioxide, oxides of nitrogen and smoke. Keep away from oxidizing agents, strongly alkaline and
strongly acidic materials in order to avoid possible exothermic reactions.
11
TOXICOLOGICAL
There are no data available on the product itself. Exposure to vapor concentrations from the paint
INFORMATION components in excess of the stated occupational exposure limits may result in adverse health
effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue,
muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or
prolonged contact with the preparation may cause removal of natural fat from the skin resulting in
dryness, irritation and possible non-allergic contact dermatitis. Paint components may also be
absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with
possible reversible damage.
12
ECOLOGICAL
There is no data available on the product itself. The product should not be allowed to enter drains
INFORMATION or water courses.
13
DISPOSAL
Do not allow into drains or water courses. Wastes and empty containers should be disposed of in
CONSIDERATIONS accordance with regulations made under the Control of Pollution Act, the Environmental
Protection Act, or the European Waste Catalogue, whatever applies. Using information provided in
this data sheet advice should be obtained from the Waste Regulation Authority, if the special waste
regulations apply.
MATERIAL SAFETY DATA SHEET Page 3 www.safenanotech.com
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SAFE MARINE
14
TRANSPORT
Transport only in accordance with the following regulations:
INFORMATION
Regulatory UN num. Ship. name Class Packing gr. Label Additional Info
ADR/RID 1263 Paint r.m. 3 III Hazard id. N掳: 31 (C)
IMDG 1263 Paint r.m. 3.3 III Ems 3-05, Marine Poll.: Yes
IATA-DGR 1263 Paint r.m. 3 III -
15
REGULATORY
In accordance with EC Directive 88/379/EEC and the Chemicals (Hazard Information and
INFORMATION Packaging for Supply) Regulations SI /3247/1994 this product is labeled as follows:
Danger Indication Toxic, Highly Flammable
Hazard symbol(s)
Toxic Highly Flammable
Contains
Safety Phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice
S24 Avoid contact with skin.
S43 In case of fire use alcohol resistant foam, CO虏 powder, water spray.
Water jet not recommended.
S37 Wear suitable gloves
S61 Avoid release to the environment. Refer to special instructions/Safety
data sheets.
Risk Phrases
R11 Highly flammable
R45 May cause cancer
R65 Harmful: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking
R20 Harmful by inhalation
R36 Irritating to eyes
Additional Warning Phrases - Contains epoxy constituents. See information supplied by the
manufacturer. This information is provided by the present Safety Data Sheet.
16
OTHER
The information on this MSDS is based upon the present state of our knowledge and on current
INFORMATION EEC and national laws.
The product should not be used for purposes other than shown in the product data sheet without
first obtaining written advice. It is always the responsibility of the user to take all necessary steps
to meet the demands of applicable legislation. The information in this Health & Safety Data Sheet
is required pursuant to Directive 91/155/EEC and the Chemicals (Hazard Information & Packaging
for Supply) Regulations 1994. The full text of the R phrases appearing in section 2 is:
R11 Highly flammable.
R20 Harmful by inhalation.
R36 Irritating to eyes.
R45 May cause cancer.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapors may cause drowsiness and dizziness.
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SAFE MARINE
Your attention is drawn to the disclaimer on the Product Data Sheet with which this Safety Data
Sheet and the package labeling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from Safe Marine Nanotechnologies on request or from
www.safenanotech.com.
MATERIAL SAFETY DATA SHEET Page 5 www.safenanotech.com
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