PRODUCT SAFETY DATA SHEET
Print date: 08 Mar 2007
1. PRODUCT AND COMPANY IDENTIFICATION
Item Number / Product code: 0100746
Product name:
ZUD餂? HEAVY DUTY CLEANSER (POWDER)
Validation / Revision Date: 08 March 2007
EPA Identifier: Not applicable.
Formula Number: 1107-180 (0100746)
UPC Number and Size: 62338-00710 (6 oz.)
62338-00750 (16 oz.)
Product Description: Heavy duty powder cleanser for use on non-porous surfaces such as porcelain, ceramic
cookware, stainless steel, aluminum, chrome, pewter, brass, bronze and copper.
Manufacturer: Reckitt Benckiser North America, Inc.
Morris Corporate Center IV
399 Interpace Parkway (P.O. Box 225)
Parsippany, New Jersey 07054-0225
Emergency telephone number: 1-800-228-4722 (U.S.)
Transportation Emergencies: 1-800-424-9300 (U.S. & Canada) CHEMTREC
Outside the U.S. and Canada (North America), call: 703-527-3887
2. COMPOSITION / INFORMATION ON INGREDIENTS
Components: Wt % ACGIH: OSHA:
OXALIC ACID, DIHYDRATE 5-10 1 mg/m3 TWA (TLV); 2 mg/m3 STEL 1 mg/m3 TWA (PEL)
6153-56-6
PUMICE 15-20 None None
1332-09-8
Product code: 0100746 Page 1 of 7
Product name: ZUD餂? HEAVY DUTY CLEANSER
(POWDER)
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: EYE AND SKIN IRRITANT.
HARMFUL IF SWALLOWED!
DO NOT get in eyes, on skin or on clothing.
DO NOT ingest.
May be a respiratory irritant. Avoid breathing dust. Use in a well-ventilated area.
Wash hands with soap and water after handling.
DO NOT use with chlorine bleach or other household cleaner products as toxic fumes may result.
Contains Calcium Sulfate Dihydrate and Oxalic Acid.
KEEP OUT OF REACH OF CHILDREN
4. FIRST AID MEASURES
Inhalation: Move to fresh air. If symptoms persist, call a physician.
Skin contact: If on skin, wash the product off with soap and water. If irritation develops, seek the care of a
physician.
Eye contact: In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of
water. Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation
occurs or persists, get medical attention.
Ingestion: If swallowed, rinse mouth and drink a glass of water. If symptoms persist, get medical
attention. Never give an unconscious person anything to ingest.
Notes to physician: Contains Calcium Sulfate Dihydrate and Oxalic Acid.
Aggravated Medical Conditions: May aggravate pre-existing upper respiratory and lung diseases (Bronchitis, Emphysema and
Asthma).
May aggravate pre-existing skin diseases (Rashes and Dermatitis).
5. FIRE-FIGHTING MEASURES
Flash point: Not applicable (Powder).
Flammability Limits in Air:
Lower: No information available.
Upper: No information available.
Autoignition temperature: No information available.
Suitable extinguishing media: As suitable for surrounding fire.
Extinguishing media which must not No information available.
be used for safety reasons:
Specific hazards: Contains Calcium Sulfate Dihydrate and Oxalic Acid.
Unusual hazards: Oxalic Acid may generate Formic Acid and Carbon Monoxide under
fire conditions.
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus, pressure-
demand, MSHA / NIOSH (approved or equivalent) and full
protective gear.
Specific methods: Standard procedure for chemical fires.
Product code: 0100746 Page 2 of 7
Product name: ZUD餂? HEAVY DUTY CLEANSER
(POWDER)
NFPA: Health: 2 Flammability: 0 Instability: 0
HMIS: Health: 2 Flammability: 0 Reactivity: 0
Key: Personal Protection Index = B.
(Also see Sections 3 & 8)
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Ensure adequate ventilation.
Environmental precautions: Do not allow material to contaminate ground water system.
Methods for cleaning up: Small spills: Sweep up, minimizing airborne dust. Place into a paper or plastic bag and discard
in dry trash. Remaining spill residues of dust may be wiped up with a wet paper towels or
flushed into sink or sanitary sewer.
Large spills:
Wear rubber gloves and appropriate eye protection.
Appropriate dust particle face masks, supplied air or self-contained breathing apparatus
(SCBA) is required to be worn by all emergency responders and clean-up personnel.
Large spills: Collect with a minimum of dust, place in a suitable container for disposal
according to local, state, provincial and federal regulations.
7. HANDLING AND STORAGE
Handling: WARNING: EYE AND SKIN IRRITANT!
Use with adequate ventilation.
For occupational exposures wear appropriate eye and skin protection where the potential for
splashing exists.
Use only as directed!
Read container label instructions carefully.
Safe handling advice: Avoid dust formation.
Use only in well-ventilated areas.
Do not breathe dust.
Storage: Store containers in an upright position in a cool, dry area, inaccessable to small children and
pets.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures For occupational exposures, ensure adequate ventilation.
to reduce exposure:
Personal Protective Equipment
Respiratory protection: None required under normal use conditions.
Use in a well-ventilated area.
In case of insufficient ventilation wear suitable respiratory equipment.
Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid
inhalation of airborne particles (dust) generated by this product during a spill or other clean-up
operations.
Product code: 0100746 Page 3 of 7
Product name: ZUD餂? HEAVY DUTY CLEANSER
(POWDER)
Hand protection: Skin irritant.
Wear impervious gloves where the potential for contact with the powder is possible.
Emergency responders should wear impermeable gloves.
Skin and body protection: Usual safety precautions while handling the product will provide adequate protection against
injury or irritation. Follow product label instructions.
Eye protection: Eye irritant.
Avoid contact with eyes.
Appropriate eye protection such as: Safety glasses with side shields, chemical goggles or full
face shield for occupational exposures.
Emergency responders should wear full eye and face protection.
Hygiene measures: Avoid contact with skin, eyes and clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Powder.
Appearance: Free flowing wettable powder.
Colour: Off-white.
Odour: None.
pH: 1.5 - 2.5 (3% aqueous slurry)
Flash point: Greater than 93潞 C (>200潞 F)
Specific gravity: No information available.
Density: 0.72 - 0.88 g/cc
Vapour pressure: Not determined.
Solubility: Practically insoluble.
Explosion limits:
- upper: No data available.
- lower: No data available.
10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.
Polymerization: Hazardous polymerisation does not occur.
Hazardous decomposition products: Oxalic acid may generate formic acid and carbon monoxide under
fire conditions.
Materials to avoid: Do not mix with chlorine bleach or other cleaning agents.
Conditions to avoid: Store away from excessive heat and moisture.
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information:
Product Information
LC50/inhalation/4h/rat = No information available.
LD50/dermal/rabbit = No information available.
LD50/oral/rat = No information available.
Local effects
Skin irritation: Skin irritant.
Product code: 0100746 Page 4 of 7
Product name: ZUD餂? HEAVY DUTY CLEANSER
(POWDER)
Eye irritation: Eye irritant.
Inhalation Avoid breathing airborne dust.
Ingestion May be harmful if swallowed. See Section 4 for First Aid instructions.
Sensitization Not expected to be a skin sensitiser.
Chronic toxicity: No information available.
Specific effects
Carcinogenic effects: Not listed as carcinogenic by OSHA, NTP or IARC.
Mutagenic effects: No information available.
Reproductive toxicity: No information available.
Target organ effects: No information available.
Information is based on data on the components and the toxicology of similar products.
12. ECOLOGICAL INFORMATION
Product Information
Aquatic toxicity: No information available.
Component Information:
OXALIC ACID, DIHYDRATE
6153-56-6 (5-10)
Ecotoxicity: = 1350 mg/L LC50 mosquito fish static
= 4000 mg/L LC50 bluegill static
Other information:
Ozone depletion potential; ODP; (R-11 = 1) = No information available.
Global warming potential (GWP) = No information available.
Additional ecological information: No information available.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused Dispose of in accordance with local regulations.
products:
Contaminated packaging: Empty container can be disposed of as household trash or rinsed and recycled where
appropriate.
Waste Disposal: Small amounts of powder waste: Wipe up with a wet paper towel and discard absorbed
material in trash collection and flush waste residue to sink or sanitary sewer.
Wear appropriate personal protective equipment when cleaning or handling waste material.
Avoid creating airborne dust during the clean-up operations. Use HEPA filtered Vacuum or wet
cleaning operations.
Large amounts of powder waste: Dispose of in accordance with local, state, provincial and
federal regulations.
14. TRANSPORT INFORMATION
UN / Id No: Not applicable
Product code: 0100746 Page 5 of 7
Product name: ZUD餂? HEAVY DUTY CLEANSER
(POWDER)
DOT:
Classification: Not a DOT regulated material. (United States)
Proper shipping name: Not applicable.
U.S. DOT - Hazard Class: Not applicable.
Subsidiary risk: Not applicable.
Packing Group: Not applicable.
DOT RQ (lbs): Not applicable.
ERG No: Not applicable.
TDG (Canada):
Classification: Not regulated under TDG
Proper shipping name: Not applicable.
Status: Not applicable.
Packing Group: Not applicable.
IMDG / IMO
Classification: Not regulated under IMDG
Proper shipping name: Not applicable.
Class: Not applicable.
Subsidiary Risk: Not applicable.
Packing group: Not applicable.
IMDG page: Not applicable.
Marine pollutant: Not applicable.
EMS: Not applicable.
MFAG: See Guide.
ADR / RID
Classification: Not applicable.
Proper shipping name: Not applicable.
Class: Not applicable.
Subsidiary risk: Not applicable.
Packing Group: Not applicable.
ADR/RID-labels: Not applicable
Hazard Identification Number: Not applicable.
CEFIC Tremcard No: Not applicable.
ICAO / IATA:
Classification: Not regulated under ICAO / IATA
Proper shipping name: Not applicable.
Class: Not applicable.
Subsidiary Risk: Not applicable
Packing Group: Not applicable.
Maximum quantity Not applicable.
15. REGULATORY INFORMATION
Components: PICCS: TSCA: DSL: NDSL: ENCS: CHINA: AICS: EINECS-No
OXALIC ACID, DIHYDRATE Present Present 205-634-3
U.S. Regulations:
Components: OXALIC ACID, DIHYDRATE - 6153-56-6
NJRTK: Not Listed.
California Proposition 65 - None.
CERCLA/SARA 313: None
Components: PUMICE - 1332-09-8
NJRTK: Not Listed.
Product code: 0100746 Page 6 of 7
Product name: ZUD餂? HEAVY DUTY CLEANSER
(POWDER)
California Proposition 65 - None.
CERCLA/SARA 313: None
Canada
WHMIS hazard class: Not determined.
16. OTHER INFORMATION
National Fire HMIS (U.S.A.): Health Hazard 2
Protection Fire Hazard 0
Association (U.S.A.): Reactivity 0
Personal Protection B
Reason for revision: This is a new formulation of an existing product.
Additional advice: This product should only be used as directed on the label and for the purpose intended.
Prepared by: Reckitt Benckiser (U.S.) Inc.
Product Safety Department
1 Philips Parkway
Montvale, New Jersey 07646-1810 USA.
Phone: 201-573-6391
FAX: 201-476-7770.
Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither
the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
Product code: 0100746 Page 7 of 7
Product name: ZUD餂? HEAVY DUTY CLEANSER
(POWDER)
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