Material Safety Data Sheet
Print Date: 04/07/2006 Revision Number: 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product name:
Airwick餂? Freshmatic Automatic Spray (US)
Product Description: Automatic Aerosol Spray
Product Identifier: Various fragrances: - Sparkling Citrus, Lavender, Harvest Spice (Traditions), Papaya
& Mango, Fresh Waters
Item Number: 0033759 - Lavender
0033754 - Citrus
0033861 - Traditions
0051262 - Papaya & Mango
0065091 - Fresh Waters
Formula Number: Lavender - 987-58A
Citrus - 987-58B
Traditions - 987-77
Papaya & Mango - 987-86a
Fresh Waters - 987-107A
Validation Date: 03/21/2006
UPC Number and Size: 62338-779670-7 Lavender Starter; 62338-7961-4 Lavender Refill
62338-77964-5 Citrus Starter; 62338-77965-2 Citrus Refill
62338-78283 Traditions Starter; 62338-78284 Traditions Refill
62338-78620 Papaya & Mango Starter
62338-79553-9 Fresh Waters Refill
Synonyms: Airwick庐 Automatic Spray
Chemical characterisation: Aerosol Air Freshener
Manufacturer: Reckitt Benckiser, Inc.
Morris Corporate Centre IV
399 Interpace Parkway (P.O. Box 225)
Parsippany, N.J. 07054-0225
Emergency telephone number: 1-800-228-4722 (US)
Transportation Emergencies: 1-800-424-9300 (U.S. & Canada) CHEMTREC
Outside the U.S. and Canada (North America) Chemtrec call:703-527-3887
2. COMPOSITION/INFORMATION ON INGREDIENTS
Exposure limits
Components CAS-No Weight % ACGIH: OSHA:
PROPELLANT BLEND 152 A HFC 75-37-6 30 - 40% None
Isobutane 75-28-5 20 - 30% 800ppm TWA / 1900 None
mg/m3
Fragrance 00-00-0 1 - 5% None
Isopar M Solvent 64742-47-8 30 - 40% None
Product code: SMART 3 Page 1 of 7
Product name: Airwick餂? Freshmatic Automatic
Spray (US)
3. HAZARDS IDENTIFICATION
Emergency Overview
鈥? KEEP OUT OF REACH OF CHILDREN
鈥? DANGER:FLAMMABLE
鈥? EYE IRRITANT
鈥? May be harmful or fatal if swallowed
鈥? Prolonged or frequent use may produce an allergic reaction in some individuals.
鈥? Do not expose to heat or store at temperatures above 50 掳C (120掳F) as container may burst.
鈥? DO NOT PUNCTURE OR INCINERATE CONTAINER.
鈥? Contents under pressure
鈥? WARNING IRRITANT!
鈥? DANGER FLAMMABLE! Vapors may travel to a source and flash back
Physico-chemical Extremely flammable.
properties:
Contains: petroleum solvent, propellants and fragrance oils.
KEEP OUT OF REACH OF CHILDREN
4. FIRST AID MEASURES
Skin contact: After contact with skin, wash immediately with plenty of water. If skin irritation
persists, call a physician
Ingestion: Rinse mouth with water and drink afterwards plenty of water. DO NOT INDUCE
VOMITING!
Eye contact: Rinse immediatiely with plenty of water, also under the eyelids for at least 15
minutes. If symptoms develop or persist seek medical advice.
Notes to physician: No information available.
Aggravated Medical Conditions: NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling
aerosol products may be harmful or fatal. Help stop inhalation abuse. For
information visit www.inhalant.org.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: Foam. Dry powder. Water. Water spray.
Extinguishing media which must not be used for safety No information available.
reasons:
Specific hazards: Extremely flammable. All aerosols are pressurised products
and will eventually burst if exposed to very high
temperatures, or if involved in a fire. They will then release
the propellant gas which is extremely flammable (152 A
HFC).
Unusual hazards: Move containers away from fire if possible and safe to do so.
Use water spray to cool fire exposed containers. Provide
shielding for personnel exposed to venting, rupturing or
bursting containers.
Special protective equipment for firefighters: Wear self contained breathing apparatus for fire fighting if
necessary.
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SMART 3 Airwick餂? Freshmatic Automatic Spray (US)
Specific methods: No information available.
Flash point: Aerosol product - Not applicable.
Autoignition temperature: No information available.
Flammability Limits in Air:
- lower No information available
- upper No information available
NFPA: Health: 2 Flammability: 3 Instability: 0
HMIS: Health: 2 Flammability: 3 Physical Hazard: 0
Key:
See also section 3
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Ensure adequate ventilation.
Environmental precautions: Do not allow material to contaminate ground water system.
Methods for cleaning up: Eliminate all sources of ignition and ventilate the area with equipment rated for use in
flammable environments. Small spillages of up to 1 litre (0.26 gallon) may be
cleaned up with a mop or an absorbant cloth. Medium spills of up to 5 litres (1.32
gallons) should be absorbed with sand, earth, sawdust or other inert material and
transferred to a suitable container for disposal.
7. HANDLING AND STORAGE
Handling: No special technical protective measures required.Pressurised container: protect
from sunlight and do not expose to temperatures exceeding 50潞C (120潞F). Do not
pierce or burn after use. Keep away from all sources of ignition. Fires involving
aerosols with flammable contents are severe and can spread quickly. Warehouses
or stores containing aerosols should therefore be separated from other areas by a
fire resistant construction. Stores should be well ventilated. The natural ventilation in
a large open warehouse building will normally be suitable. Do not spray on a naked
flame or any other incandescent material. KEEP OUT OF REACH OF CHILDREN.
Storage: Store in original container in areas inaccessable to small children and pets.Store in a
secure, cool location, inaccessable to children.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
-
-
Engineering measures to reduce exposure: Ensure adequate ventilation.
Personal protective equipment
Respiratory protection: Self-contained breathing apparatus (SCBA).
Hand protection: None required under normal use conditions. Emergency responders should wear
impermeable gloves.
Skin and body protection: None required under normal use conditions.
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SMART 3 Airwick餂? Freshmatic Automatic Spray (US)
Eye protection: Avoid contact with eyes Emergency responders should wear full eye and face
protection.
Hygiene measures: Washing with soap and water after use is recommended as good hygienic practice to
prevent possible eye irritation from hand contact.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Appearance: Aerosol.
Colour: No information available.
Odour: No information available.
pH: No information available.
Autoignition temperature: 32
Specific Gravity: Specific Gravity:
Density: No information available.
Bulk density: No information available.
Vapor density: not determined.
Vapour pressure: not determined.
Solubility: No information available.
VOC Content(%): No information available.
Explosion limits:
- upper: no data available.
- lower: no data available.
10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.
polymerization: Hazardous polymerisation does not occur.
Hazardous decomposition Oxides of carbon and unknown organic compounds.
products:
Materials to avoid: Do not mix with other household chemicals
Conditions to avoid: Keep away from open flames, hot surfaces and sources of ignition. Pressurised
container. Protect from sunlight and do not expose to temperatures exceeding 50潞C
(120潞F). Extremes of temperatures can occur in cars and near ovens and fireplaces.
Do not place in contact with hot surfaces or near naked flames. Do not pierce or
burn after use. Do not spray on a naked flame, onto or near a fire, or any
incandescent material such as an electric fire. Do not expose to temperatures above
50潞C (120潞F).
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information
Product Information
LC50/inhalation/4h/rat = No information available.
LD50/dermal/rabbit = No information available.
LD50/oral/rat = No information available.
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SMART 3 Airwick餂? Freshmatic Automatic Spray (US)
Local effects
Skin irritation: None expected during normal conditions of use.
Eye irritation: None expected during normal use. May cause eye irritation upon direct contact with
eyes
Inhalation NOTE TO PARENTS: Intentional misuse by deliberately concentrating and inhaling
aerosol products may be harmful or fatal.
Ingestion Health injuries are not known or expected under normal use
sensitisation Not expected to be a skin sensitiser
Chronic toxicity: No information available
Specific effects
carcinogenic effects: Not listed as carcinogenic by OSHA, NTP or IARC
mutagenic effects: No information available
Reproductive toxicity: No information available
Target Organ Effects: No information available
Information is based on data on the components and the toxicology of similar products
12. ECOLOGICAL INFORMATION
Product Information
Mobility: not applicable.
Bioaccumulative potential: not applicable.
Ecotoxicity effects: no data available.
Aquatic toxicity: No information available.
Component Information
PROPELLANT BLEND 152 A HFC
Ecotoxicity: No test data on the actual product
Isobutane
Ecotoxicity: No test data on the actual product
Fragrance
Ecotoxicity: No test data on the actual product
Isopar M Solvent
Ecotoxicity: No test data on the actual product
Other information
Ozone depletion potential; ODP; (R-11 = 1) = No information available.
Global warming potential (GWP) = No information available.
Additional ecological information: Information given is based on data on the components and
the ecotoxicology of similar products.
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SMART 3 Airwick餂? Freshmatic Automatic Spray (US)
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products: Dispose of in accordance with local regulations.
Contaminated packaging: not applicable.
14. TRANSPORT INFORMATION
UN/ID No: UN 1950
DOT:
Transport Regulation Logo:
Classification: UN 1950, Aerosols, Class 2.1, Limited Quantity
Re-classed as Consumer Commodity ORM-D
Proper shipping name: Consumer Commodity
U.S. DOT - Hazard Class: Not applicable
Subsidiary Risk: Not applicable
Packing group: Not applicable
DOT RQ (lbs): Not applicable
ERG No: 126
TDG (Canada):
Classification: Not regulated under TDG
Proper Shipping Name: Consumer Commodity/Limited Quantity/LTD.QTY
Status: Not applicable
Packing group: Not applicable
IMDG/IMO
Classification: UN 1950, Aerosols, Class 2.1, Limited Quantity
Proper Shipping Name: Aerosols
Class: 2
Subsidiary Risk: Not applicable
Packing group: Not applicable
IMDG page: See IMDG Code
Marine pollutant: Not applicable.
EmS: F-D, S-U
MFAG: Not applicable.
Maximum quantity: See DG List
ADR/RID
Classification: Not applicable
Proper Shipping Name: Not applicable
Class: Not applicable.
Subsidiary Risk: Not applicable
Packing group: Not applicable
ADR/RID-Labels: Not applicable
HIN: Not applicable
CEFIC Tremcard No: Not applicable
ICAO/IATA:
Classification: UN 1950, Aerosols, Flammable, Class 2, Limited Quantity
or Consumer Commodity, ID 8000 if acceptable to airline.
Proper Shipping Name: Aerosols, Flammable/Consumer Commodity
Class: 2.1 (9 if shipped as a Consumer Commodity)
Subsidiary Risk: Not applicable
Packing group: Not applicable
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SMART 3 Airwick餂? Freshmatic Automatic Spray (US)
Maximum quantity: See DG List
15. REGULATORY INFORMATION
International Inventories
PICCS: TSCA: DSL: NDSL: ENCS: CHINA: AICS: EINECS-No
Components
Present Effective Present 2-86 Present Present 200-866-1
PROPELLANT BLEND 152 A
4/13/89,
HFC Sunset
12/19/95
Present
Present Present Present 2-4 Present Present 200-857-2
Isobutane
Category of
Fragrance
Danger:
Present Present Present Present Present 265-149-8
Isopar M Solvent
U.S. Regulations:
75-37-6 (30 - 40%)
NJRTK: sn 0715
75-28-5 (20 - 30%)
NJRTK: sn 1040
Canada
WHMIS hazard class:
not determined.
16. OTHER INFORMATION
National Fire HMIS (U.S.A.):
Protection
Association
(U.S.A.):
Flammability rating: 3, per NFPA 30B
Reason for revision: Not applicable.
Additional advice: Consult your supplier if the material is to be used for special applications such as in
the food industry or for hygiene, medical or surgical end-use.
Prepared By: Reckitt Benckiser
Regulatory, Safety & Environmental Services Homecare
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier
nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee
that these are the only hazards that exist.
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SMART 3 Airwick餂? Freshmatic Automatic Spray (US)
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