**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-36-7 |N,N-Diethylethylenediamine | >98 | 202-844-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 21 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin. Causes severe burns.
Potential Health Effects
Eye:
Causes severe eye irritation and possible burns.
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Use dry chemical, carbon dioxide, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Do not ingest or inhale. Discard contaminated shoes. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Use only with
adequate ventilation. Keep away from heat, sparks and flame.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 100-36-7:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: ammonia-like
pH: Not available.
Vapor Pressure: 0.4 mbar @ 20 deg C
Viscosity: Not available.
Boiling Point: 145 - 147 deg C @ 760 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 30 deg C ( 86.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: .8270g/cm3
Molecular Formula: C6H16N2
Molecular Weight: 116.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, electrical sparks, exposure to flame.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, carbon dioxide, acid
anhydrides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-36-7: KV3500000
LD50/LC50:
CAS# 100-36-7: Oral, rat: LD50 = 2830 mg/kg; Skin, rabbit: LD50 =
820 uL/kg.
Not available.
Carcinogenicity:
N,N-Diethylethylenediamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: N,N-DIETHYLETHYLENEDIAMINE
Hazard Class: 8 (3)
UN Number: 2685
Packing Group: II
IMO
Shipping Name: N,N-DIETHYLETHYLENEDIAMINE
Hazard Class: 8 (3)
UN Number: 2685
Packing Group: II
RID/ADR
Shipping Name: N,N-DIETHYLETHYLENEDIAMINE
Hazard Class: 8
UN Number: 2685
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 21 Harmful in contact with skin.
R 35 Causes severe burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 100-36-7: 1
Canada
CAS# 100-36-7 is listed on Canada's DSL List.
CAS# 100-36-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-36-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/04/1998 Revision #3 Date: 6/17/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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1-Phenyl-2-thiourea
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N-Acetyl-S-(2-Cyanoethyl)-L-Cysteine
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2-Bromobenzonitrile, 99%
| 2042-37-7 |
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Ammonium-D4 Chloride, 98+ Atom % D
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4-Bromo-2-Fluorobenzylamine Hydrochloride 99% (Titr.)
| 147181-08-6 |
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1-Isobutoxycarbonyl-2-isobutoxy-1,2-dihydroquinone, 97%
| 38428-14-7 |
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Levulinic acid, 98+%
| 123-76-2 |
|
Sodium bismuthate(V)
| 1304-76-3 |
|
4-Fluorobenzonitrile, 99%
| 1194-02-1 |
|
Phenylacetic Acid Hydrazide, 99%
| 937-39-3 |
|
4-Amino-2-Mercaptopyrimidine, 97%
| 333-49-3 |
|
3,5-Dimethoxybenzyl Alcohol, 98%
| 705-76-0 |
|
2,2'-Biphenol, 99%
| 1806-29-7 |
|
2-Methyl-2-nitrosopropane dimer 98%
| 6841-96-9 |
|
3-[2-(2-Iodoacetamido)acetamido]-PROXYL, free radical
| 74648-17-2 |
|
Diethyl 2-ethyl-2-(p-tolyl)malonate, 99%
| 68692-80-8 |
|
3,5-bis(trifluoromethyl)aniline, 98+%
| 328-74-5 |
|
Ethyl 3-Chloropropionate, 99% (GC)
| 623-71-2 |
|
Benzo[a]pyrene, 98%
| 50-32-8 |
|
(-)-Camphene, 95%
| 5794-04-7 |
|
4-(Dimethylamino)-Benzophenone 98%
| 529-84-0 |
|
Cyclohexylacetic Acid, 99%
| 5292-21-7 |
|
Tetracosane, 99%
| 646-31-1 |
|
4-Benzyloxyaniline Hydrochloride, 98%
| 51388-20-6 |
|
Chloromethyl Butyrate, 99%
| 33657-49-7 |
|
4-Aminosulfonyl-1-Hydroxy-2-Naphthoic Acid, 97%
| 64415-15-2 |
|
N,N-Diethylethylenediamine, 98+%
| 100-36-7 |
|
Xenon difluoride, 99.5%
| 13709-36-9 |
|
Tungsten Disulfide, 99%,Particle Size 0.7- 1.1 Micrometer
| 12138-09-9 |
|
n-Benzylethylenediamine 99% (titr.)
| 4152-09-4 |
|
2,4-Dimethylbenzoic acid, 98%
| 611-01-8 |
|
L-10-Camphorsulfonic Acid Ammonium Salt
| 13867-85-1 |
|
Meso-Tetraphenylporphine, Chlorin free
| 20998-75-8 |
|
n-Propylcyclopropane methylamine hydrochloride, 99%
| 26389-60-6 |
|
1-Octanesulfonic Acid Sodium Salt Premixed Concentrate (Low UV)
| 5324-84-5 |
|
2-Benzimidazolylurea, 97%
| 24370-25-0 |
|
2-Fluoro-6-Nitrotoluene, 98%
| 769-10-8 |
|
2,8-Bis(dimethylamino)-10-dodecyl-acridinium bromide
| 41387-42-2 |
|
Isopentyl Ether, 98% (GC)
| 544-01-4 |
|
Ethyl Methyl Sulfide, 98% (GC)
| 624-89-5 |
|
1,4,8,11-Tetraazacyclotetradecane, 99+%
| 295-37-4 |
|
DL-P-Chlorophenylalanine, 98%
| 7424-00-2 |
|
1-Adamantyl Bromomethyl Ketone, 98%
| 5122-82-7 |
|
4-Amino-2-nitrophenol, 99%
| 119-34-6 |
|
2,4-Dinitroanisole
| 119-27-7 |
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Rhodamine B Base
| 509-34-2 |
|
Glycol sulfite, 98%
| 3741-38-6 |
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|