**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 1304-76-3 |Bismuth oxide (Bi2O3) | <15 | 215-134-7 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | <15 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 12232-99-4 |Sodium bismuthate(V) | 85 | 235-455-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material
have not been fully investigated.Hygroscopic (absorbs moisture from
the air).
Potential Health Effects
Eye:
Dust may cause mechanical irritation. No information regarding eye
irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
Harmful if swallowed. The toxicological properties of this substance
have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated. Inhalation of dust may cause respiratory tract
irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Decomposes at high temperatures releasing oxygen
which may cause an existing fire to burn more vigorously.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1304-76-3:
CAS# 7732-18-5:
CAS# 12232-99-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow to brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble in cold, dec by hot
Specific Gravity/Density:
Molecular Formula: BiNaO3
Molecular Weight: 279.96
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, toxic fumes of sodium oxide,
bismuth oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1304-76-3: EB2984460
CAS# 7732-18-5: ZC0110000
CAS# 12232-99-4: VZ1750000
LD50/LC50:
CAS# 1304-76-3: Oral, mouse: LD50 = 10 gm/kg; Oral, rat: LD50 = 5000
mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 12232-99-4: Oral, rat: LD50 = 420 mg/kg.
Not available.
Carcinogenicity:
Bismuth oxide (Bi2O3) -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Sodium bismuthate(V) -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1304-76-3: 1
CAS# 7732-18-5: No information available.
CAS# 12232-99-4: No information available.
Canada
CAS# 1304-76-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 12232-99-4 is listed on Canada's DSL List.
CAS# 1304-76-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 12232-99-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1304-76-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 12232-99-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 2/25/1998 Revision #3 Date: 12/04/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,n'-disuccinimidyl carbonate, 98%
| 74124-79-1 |
|
2,6-Dimethylthiophenol, 96%
| 118-72-9 |
|
1-Phenyl-2-thiourea
| 103-85-5 |
|
N-Acetyl-S-(2-Cyanoethyl)-L-Cysteine
| 74514-75-3 |
|
2-Bromobenzonitrile, 99%
| 2042-37-7 |
|
Ammonium-D4 Chloride, 98+ Atom % D
| 12015-14-4 |
|
(2,2-Dichloro-1-methylcyclopropyl)benzene, 95%
| 3591-42-2 |
|
4-Bromo-2-Fluorobenzylamine Hydrochloride 99% (Titr.)
| 147181-08-6 |
|
1-Isobutoxycarbonyl-2-isobutoxy-1,2-dihydroquinone, 97%
| 38428-14-7 |
|
Levulinic acid, 98+%
| 123-76-2 |
|
Sodium bismuthate(V)
| 1304-76-3 |
|
4-Fluorobenzonitrile, 99%
| 1194-02-1 |
|
Phenylacetic Acid Hydrazide, 99%
| 937-39-3 |
|
4-Amino-2-Mercaptopyrimidine, 97%
| 333-49-3 |
|
3,5-Dimethoxybenzyl Alcohol, 98%
| 705-76-0 |
|
2,2'-Biphenol, 99%
| 1806-29-7 |
|
2-Methyl-2-nitrosopropane dimer 98%
| 6841-96-9 |
|
3-[2-(2-Iodoacetamido)acetamido]-PROXYL, free radical
| 74648-17-2 |
|
Diethyl 2-ethyl-2-(p-tolyl)malonate, 99%
| 68692-80-8 |
|
3,5-bis(trifluoromethyl)aniline, 98+%
| 328-74-5 |
|
Ethyl 3-Chloropropionate, 99% (GC)
| 623-71-2 |
|
Benzo[a]pyrene, 98%
| 50-32-8 |
|
(-)-Camphene, 95%
| 5794-04-7 |
|
4-(Dimethylamino)-Benzophenone 98%
| 529-84-0 |
|
Cyclohexylacetic Acid, 99%
| 5292-21-7 |
|
Tetracosane, 99%
| 646-31-1 |
|
4-Benzyloxyaniline Hydrochloride, 98%
| 51388-20-6 |
|
Chloromethyl Butyrate, 99%
| 33657-49-7 |
|
4-Aminosulfonyl-1-Hydroxy-2-Naphthoic Acid, 97%
| 64415-15-2 |
|
N,N-Diethylethylenediamine, 98+%
| 100-36-7 |
|
Xenon difluoride, 99.5%
| 13709-36-9 |
|
Tungsten Disulfide, 99%,Particle Size 0.7- 1.1 Micrometer
| 12138-09-9 |
|
n-Benzylethylenediamine 99% (titr.)
| 4152-09-4 |
|
2,4-Dimethylbenzoic acid, 98%
| 611-01-8 |
|
L-10-Camphorsulfonic Acid Ammonium Salt
| 13867-85-1 |
|
Meso-Tetraphenylporphine, Chlorin free
| 20998-75-8 |
|
n-Propylcyclopropane methylamine hydrochloride, 99%
| 26389-60-6 |
|
1-Octanesulfonic Acid Sodium Salt Premixed Concentrate (Low UV)
| 5324-84-5 |
|
2-Benzimidazolylurea, 97%
| 24370-25-0 |
|
2-Fluoro-6-Nitrotoluene, 98%
| 769-10-8 |
|
2,8-Bis(dimethylamino)-10-dodecyl-acridinium bromide
| 41387-42-2 |
|
Isopentyl Ether, 98% (GC)
| 544-01-4 |
|
Ethyl Methyl Sulfide, 98% (GC)
| 624-89-5 |
|
1,4,8,11-Tetraazacyclotetradecane, 99+%
| 295-37-4 |
|
DL-P-Chlorophenylalanine, 98%
| 7424-00-2 |
|
1-Adamantyl Bromomethyl Ketone, 98%
| 5122-82-7 |
|
4-Amino-2-nitrophenol, 99%
| 119-34-6 |
|
2,4-Dinitroanisole
| 119-27-7 |
|
Rhodamine B Base
| 509-34-2 |
|
Glycol sulfite, 98%
| 3741-38-6 |
|
|