**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 295-37-4 |1,4,8,11-TETRAAZACYCLOTETRADECANE | 99+% | 206-039-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use
process enclosure, local exhaust ventilation, or other engineering
controls to control airborne levels.
Exposure Limits
CAS# 295-37-4:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 186.00 - 188
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 5g/100ml (20 c)
Specific Gravity/Density:
Molecular Formula: C10H24N4
Molecular Weight: 200.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Strong oxidants.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 295-37-4: XA5254800
LD50/LC50:
Not available.
Carcinogenicity:
1,4,8,11-TETRAAZACYCLOTETRADECANE -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 295-37-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 295-37-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 295-37-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/23/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,n'-disuccinimidyl carbonate, 98%
| 74124-79-1 |
|
2,6-Dimethylthiophenol, 96%
| 118-72-9 |
|
1-Phenyl-2-thiourea
| 103-85-5 |
|
N-Acetyl-S-(2-Cyanoethyl)-L-Cysteine
| 74514-75-3 |
|
2-Bromobenzonitrile, 99%
| 2042-37-7 |
|
Ammonium-D4 Chloride, 98+ Atom % D
| 12015-14-4 |
|
(2,2-Dichloro-1-methylcyclopropyl)benzene, 95%
| 3591-42-2 |
|
4-Bromo-2-Fluorobenzylamine Hydrochloride 99% (Titr.)
| 147181-08-6 |
|
1-Isobutoxycarbonyl-2-isobutoxy-1,2-dihydroquinone, 97%
| 38428-14-7 |
|
Levulinic acid, 98+%
| 123-76-2 |
|
Sodium bismuthate(V)
| 1304-76-3 |
|
4-Fluorobenzonitrile, 99%
| 1194-02-1 |
|
Phenylacetic Acid Hydrazide, 99%
| 937-39-3 |
|
4-Amino-2-Mercaptopyrimidine, 97%
| 333-49-3 |
|
3,5-Dimethoxybenzyl Alcohol, 98%
| 705-76-0 |
|
2,2'-Biphenol, 99%
| 1806-29-7 |
|
2-Methyl-2-nitrosopropane dimer 98%
| 6841-96-9 |
|
3-[2-(2-Iodoacetamido)acetamido]-PROXYL, free radical
| 74648-17-2 |
|
Diethyl 2-ethyl-2-(p-tolyl)malonate, 99%
| 68692-80-8 |
|
3,5-bis(trifluoromethyl)aniline, 98+%
| 328-74-5 |
|
Ethyl 3-Chloropropionate, 99% (GC)
| 623-71-2 |
|
Benzo[a]pyrene, 98%
| 50-32-8 |
|
(-)-Camphene, 95%
| 5794-04-7 |
|
4-(Dimethylamino)-Benzophenone 98%
| 529-84-0 |
|
Cyclohexylacetic Acid, 99%
| 5292-21-7 |
|
Tetracosane, 99%
| 646-31-1 |
|
4-Benzyloxyaniline Hydrochloride, 98%
| 51388-20-6 |
|
Chloromethyl Butyrate, 99%
| 33657-49-7 |
|
4-Aminosulfonyl-1-Hydroxy-2-Naphthoic Acid, 97%
| 64415-15-2 |
|
N,N-Diethylethylenediamine, 98+%
| 100-36-7 |
|
Xenon difluoride, 99.5%
| 13709-36-9 |
|
Tungsten Disulfide, 99%,Particle Size 0.7- 1.1 Micrometer
| 12138-09-9 |
|
n-Benzylethylenediamine 99% (titr.)
| 4152-09-4 |
|
2,4-Dimethylbenzoic acid, 98%
| 611-01-8 |
|
L-10-Camphorsulfonic Acid Ammonium Salt
| 13867-85-1 |
|
Meso-Tetraphenylporphine, Chlorin free
| 20998-75-8 |
|
n-Propylcyclopropane methylamine hydrochloride, 99%
| 26389-60-6 |
|
1-Octanesulfonic Acid Sodium Salt Premixed Concentrate (Low UV)
| 5324-84-5 |
|
2-Benzimidazolylurea, 97%
| 24370-25-0 |
|
2-Fluoro-6-Nitrotoluene, 98%
| 769-10-8 |
|
2,8-Bis(dimethylamino)-10-dodecyl-acridinium bromide
| 41387-42-2 |
|
Isopentyl Ether, 98% (GC)
| 544-01-4 |
|
Ethyl Methyl Sulfide, 98% (GC)
| 624-89-5 |
|
1,4,8,11-Tetraazacyclotetradecane, 99+%
| 295-37-4 |
|
DL-P-Chlorophenylalanine, 98%
| 7424-00-2 |
|
1-Adamantyl Bromomethyl Ketone, 98%
| 5122-82-7 |
|
4-Amino-2-nitrophenol, 99%
| 119-34-6 |
|
2,4-Dinitroanisole
| 119-27-7 |
|
Rhodamine B Base
| 509-34-2 |
|
Glycol sulfite, 98%
| 3741-38-6 |
|
|