**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 123-76-2 |Levulinic acid | 98+ | 204-649-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Light sensitive.Harmful.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes moderate skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do not use mouth-to-mouth
resuscitation if victim ingested or inhaled the substance; induce
artificial respiration with the aid of a pocket mask equipped with a
one-way valve or other proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Store protected from light.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 123-76-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Flakes
Color: after melting, clear yellow
Odor: none reported
pH: Not available.
Vapor Pressure: 1 mm Hg @ 102 deg C
Viscosity: Not available.
Boiling Point: 245 - 246 deg C
Freezing/Melting Point: 33 - 35 deg C
Autoignition Temperature: Not applicable.
Flash Point: 137 deg C ( 278.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Freely Soluble.
Specific Gravity/Density: 1.1340g/cm3
Molecular Formula: CH3COCH2CH2CO2H
Molecular Weight: 116.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. May decompose when exposed to light.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat, exposure
to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, bases, direct light.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 123-76-2: OI1575000
LD50/LC50:
CAS# 123-76-2: Draize test, rabbit, skin: 500 mg/24H Moderate; Oral,
rat: LD50 = 1850 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
Carcinogenicity:
Levulinic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 123-76-2: 1
Canada
CAS# 123-76-2 is listed on Canada's DSL List.
CAS# 123-76-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 123-76-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,n'-disuccinimidyl carbonate, 98%
| 74124-79-1 |
|
2,6-Dimethylthiophenol, 96%
| 118-72-9 |
|
1-Phenyl-2-thiourea
| 103-85-5 |
|
N-Acetyl-S-(2-Cyanoethyl)-L-Cysteine
| 74514-75-3 |
|
2-Bromobenzonitrile, 99%
| 2042-37-7 |
|
Ammonium-D4 Chloride, 98+ Atom % D
| 12015-14-4 |
|
(2,2-Dichloro-1-methylcyclopropyl)benzene, 95%
| 3591-42-2 |
|
4-Bromo-2-Fluorobenzylamine Hydrochloride 99% (Titr.)
| 147181-08-6 |
|
1-Isobutoxycarbonyl-2-isobutoxy-1,2-dihydroquinone, 97%
| 38428-14-7 |
|
Levulinic acid, 98+%
| 123-76-2 |
|
Sodium bismuthate(V)
| 1304-76-3 |
|
4-Fluorobenzonitrile, 99%
| 1194-02-1 |
|
Phenylacetic Acid Hydrazide, 99%
| 937-39-3 |
|
4-Amino-2-Mercaptopyrimidine, 97%
| 333-49-3 |
|
3,5-Dimethoxybenzyl Alcohol, 98%
| 705-76-0 |
|
2,2'-Biphenol, 99%
| 1806-29-7 |
|
2-Methyl-2-nitrosopropane dimer 98%
| 6841-96-9 |
|
3-[2-(2-Iodoacetamido)acetamido]-PROXYL, free radical
| 74648-17-2 |
|
Diethyl 2-ethyl-2-(p-tolyl)malonate, 99%
| 68692-80-8 |
|
3,5-bis(trifluoromethyl)aniline, 98+%
| 328-74-5 |
|
Ethyl 3-Chloropropionate, 99% (GC)
| 623-71-2 |
|
Benzo[a]pyrene, 98%
| 50-32-8 |
|
(-)-Camphene, 95%
| 5794-04-7 |
|
4-(Dimethylamino)-Benzophenone 98%
| 529-84-0 |
|
Cyclohexylacetic Acid, 99%
| 5292-21-7 |
|
Tetracosane, 99%
| 646-31-1 |
|
4-Benzyloxyaniline Hydrochloride, 98%
| 51388-20-6 |
|
Chloromethyl Butyrate, 99%
| 33657-49-7 |
|
4-Aminosulfonyl-1-Hydroxy-2-Naphthoic Acid, 97%
| 64415-15-2 |
|
N,N-Diethylethylenediamine, 98+%
| 100-36-7 |
|
Xenon difluoride, 99.5%
| 13709-36-9 |
|
Tungsten Disulfide, 99%,Particle Size 0.7- 1.1 Micrometer
| 12138-09-9 |
|
n-Benzylethylenediamine 99% (titr.)
| 4152-09-4 |
|
2,4-Dimethylbenzoic acid, 98%
| 611-01-8 |
|
L-10-Camphorsulfonic Acid Ammonium Salt
| 13867-85-1 |
|
Meso-Tetraphenylporphine, Chlorin free
| 20998-75-8 |
|
n-Propylcyclopropane methylamine hydrochloride, 99%
| 26389-60-6 |
|
1-Octanesulfonic Acid Sodium Salt Premixed Concentrate (Low UV)
| 5324-84-5 |
|
2-Benzimidazolylurea, 97%
| 24370-25-0 |
|
2-Fluoro-6-Nitrotoluene, 98%
| 769-10-8 |
|
2,8-Bis(dimethylamino)-10-dodecyl-acridinium bromide
| 41387-42-2 |
|
Isopentyl Ether, 98% (GC)
| 544-01-4 |
|
Ethyl Methyl Sulfide, 98% (GC)
| 624-89-5 |
|
1,4,8,11-Tetraazacyclotetradecane, 99+%
| 295-37-4 |
|
DL-P-Chlorophenylalanine, 98%
| 7424-00-2 |
|
1-Adamantyl Bromomethyl Ketone, 98%
| 5122-82-7 |
|
4-Amino-2-nitrophenol, 99%
| 119-34-6 |
|
2,4-Dinitroanisole
| 119-27-7 |
|
Rhodamine B Base
| 509-34-2 |
|
Glycol sulfite, 98%
| 3741-38-6 |
|
|