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MSDS 
:
 Cadmium Nitrate Tetrahydrate, 98%
CAS 
:
 10022-68-1
SYNONYMS 
:
 Nitric acid, cadmium salt, tetrahydrate.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 10022-68-1 |Cadmium nitrate, tetrahydrate | 98 | unlisted
|----------------|--------------------------------------|----------|-----------|
| 10325-94-7 |Cadmium nitrate | - | 233-710-6
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN O
Risk Phrases: 20/21/22 8

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Contact with combustible material may cause fire.

Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. Chronic inhalation may cause
pulmonary emphysema.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause unconsciousness.
Inhalation:
Effects may be delayed. Causes respiratory tract irritation. May
cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea
(labored breathing), and death. Irritation may lead to chemical
pneumonitis and pulmonary edema. May cause dyspnea (difficult or
labored breathing). May cause anemia. May cause cough, chest pain,
fever, muscular cramps, and headache.
Chronic:
May cause respiratory tract cancer. Prolonged or repeated exposure
may cause permanent bone structure abnormalities. May cause liver and
kidney damage. May cause anemia and other blood cell abnormalities.
Chronic inhalation may cause pulmonary emphysema.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Antidote:
The use of Calcium disodium EDTA as a chelating agent should be
determined by qualified medical personnel.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with combustible materials
may cause a fire. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode
when heated.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Do not use
combustible materials such as paper towels to clean up spill.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Minimize dust generation
and accumulation. Avoid contact with skin and eyes. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Avoid contact with clothing and other
combustible materials. Do not ingest or inhale. Use with adequate
ventilation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Local exhaust ventilation may be necessary to control any air
contaminants to within their TLVs during the use of this product.
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 132 deg C
Freezing/Melting Point: 59.5 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 215% (20 C)
Specific Gravity/Density: 2.455 @ 17C
Molecular Formula: Cd(NO3)2.4H2O
Molecular Weight: 308.47

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, combustible materials, organic materials,
reducing agents.
Incompatibilities with Other Materials:
Reducing agents, phosphorus, copper, copper alloys, and organic
materials.
Hazardous Decomposition Products:
Nitrogen oxides, toxic cadmium oxide fumes.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 10022-68-1: EV1850000
CAS# 10325-94-7: EV1750000
LD50/LC50:
CAS# 10022-68-1: Draize test, rabbit, eye: 20 mg/24H Moderate;
Draize test, rabbit, skin: 500 mg/24H Severe; Oral, rat: LD50 = 300
mg/kg.
CAS# 10325-94-7: Oral, mouse: LD50 = 100 mg/kg; Oral, rat: LD50 =
300 mg/kg.
Carcinogenicity:
Cadmium nitrate, tetrahydrate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Cadmium nitrate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish: Rainbow trout: 55ug/L; 48HFish: Fathead Minnow: 820ug/L; 48H

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: III
IMO
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: III
RID/ADR
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing group: III

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 10022-68-1: No information available.
CAS# 10325-94-7: 3
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10022-68-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 10325-94-7 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10022-68-1: OEL-ARAB Republic of Egypt:TWA 0.05 mg(Cd)/m3
OEL-AUSTRALIA:TWA 0.05 mg(Cd)/m3
OEL-BELGIUM:TWA 0.05 mg(Cd)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-DENMARK:TWA 0.01 mg(Cd)/m3
OEL-FINLAND:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-GERMANY;Carcinogen
OEL-INDIA:TWA 0.05 mg(Cd)/m3
OEL-JAPAN:TWA 0.05 mg(Cd)/m3
OEL-THE NETHERLANDS:TWA 0.02 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-THE PHILIPPINES:TWA 0.2 mg(Cd)/m3
OEL-RUSSIA:TWA 0.01 mg(Cd)/m3;STEL 0.05 mg(Cd)/m3
OEL-SWEDEN:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-SWITZERLAND:TWA 0.05 mg(Cd)/m3
OEL-THAILAND:TWA 0.2 mg(Cd)/m3;STEL 0.5 mg(Cd)/m3
OEL-TURKEY:TWA 0.2 mg(Cd)/m3
OEL-UNITED KINGDOM:TWA 0.01 mg(Cd)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 10325-94-7: OEL-ARAB Republic of Egypt:TWA 0.05 mg(Cd)/m3
OEL-AUSTRALIA:TWA 0.05 mg(Cd)/m3
OEL-BELGIUM:TWA 0.05 mg(Cd)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-DENMARK:TWA 0.01 mg(Cd)/m3
OEL-FINLAND:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-GERMANY;Carcinogen
OEL-INDIA:TWA 0.05 mg(Cd)/m3
OEL-JAPAN:TWA 0.05 mg(Cd)/m3
OEL-THE NETHERLANDS:TWA 0.02 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-THE PHILIPPINES:TWA 0.2 mg(Cd)/m3
OEL-RUSSIA:TWA 0.01 mg(Cd)/m3;STEL 0.05 mg(Cd)/m3
OEL-SWEDEN:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-SWITZERLAND:TWA 0.05 mg(Cd)/m3
OEL-THAILAND:TWA 0.2 mg(Cd)/m3;STEL 0.5 mg(Cd)/m3
OEL-TURKEY:TWA 0.2 mg(Cd)/m3
OEL-UNITED KINGDOM:TWA 0.01 mg(Cd)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 10022-68-1 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 10325-94-7 is not listed on the TSCA inventory.
It is for research and development use only.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 3/24/1999 Revision #4 Date: 12/03/2002

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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