**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 102-70-5 |Triallylamine | 98 | 203-048-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 10 22 24 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Toxic in contact with skin. Causes
burns.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 102-70-5:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light yellow
Odor: ammonia-like
pH: Not available.
Vapor Pressure: 90 mmHg @ 80 C
Viscosity: Not available.
Boiling Point: 150.0 - 151.0 deg C
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 204 deg C ( 399.20 deg F)
Flash Point: 39 deg C ( 102.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 2G/L (20C) IN WATER
Specific Gravity/Density: .7900g/cm3
Molecular Formula: (CH2=CHCH2)3N
Molecular Weight: 137.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 102-70-5: XX5950000
LD50/LC50:
CAS# 102-70-5: Inhalation, rat: LC50 = 554 ppm/8H; Oral, mouse: LD50
= 492 mg/kg; Oral, rat: LD50 = 1030 mg/kg; Skin, rabbit: LD50 = 400
uL/kg.
Carcinogenicity:
Triallylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Discarded triallylamine is a hazardous waste. Do not discharge to
surface water or to a sewer system.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TRIALLYLAMINE
Hazard Class: 3 (8)
UN Number: 2610
Packing Group: III
IMO
Shipping Name: TRIALLYLAMINE
Hazard Class: 3 (8)
UN Number: 2610
Packing Group: III
RID/ADR
Shipping Name: TRIALLYLAMINE
Hazard Class: 3
UN Number: 2610
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 102-70-5: No information available.
Canada
CAS# 102-70-5 is listed on Canada's NDSL List.
CAS# 102-70-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-70-5 is listed on the TSCA inventory.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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